摘要:
A polyester polyol includes a reaction product obtained from: (i) a polyol including 3 or more hydroxyl groups; (ii) a dicarboxylic acid or an anhydride thereof that includes 3 carbon atoms or fewer between the carboxylic acid groups or the anhydride thereof; (iii) a monocarboxylic acid or an anhydride thereof; (iv) optionally a diol; and (v) optionally a dicarboxylic acid or an anhydride thereof that includes greater than 3 carbons between the carboxylic acid groups or the anhydride thereof. A molar ratio of (i)+(iv) to (ii)+(v) ranges from 1.08:1 to 1.75:1, and a molar ratio of (i)+(iv) to (iii) ranges from 1.25:1 to 4:1. The reaction product has a hydroxyl value of from 60 to 300 mg KOH/g, and an acid value of less than 15 mg KOH/g.
摘要:
Provided are a composition capable of forming a cured product with excellent hardness, scratch resistance, chemical resistance, and flexibility; and a polyisocyanate compound that can be used as a curing agent for the composition. The polyisocyanate compound is represented by Formula (1), wherein R1 to R3 are identical or different and are a group represented by Formula (1a), wherein L1 and L2 are identical or different and represent an alkylene group having from 1 to 10 carbons, m represents a number of 0 or greater, L3 represents a divalent hydrocarbon group having from 4 to 18 carbons, and X represents an isocyanate group or a blocked isocyanate group blocked with a blocking agent, where m is not simultaneously 0 for R1 to R3, and the bond with the wavy line bonds to a nitrogen atom in Formula (1). In addition, the composition contains a polyisocyanate compound and a polyacrylic polyol.
摘要:
Star polymers prepared by reacting a highly branched polymer and either a lactone or lactam are disclosed. These star polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described star polymers are also disclosed.
摘要:
Regarding the present inventions I to VII, an aqueous emulsion of ultraviolet-absorbing resin obtained by neutralizing a solution of an ultraviolet-absorbing resin (i), which is obtained by reacting a polyester polyol (A) having an ultraviolet-absorbing group, a compound (C) containing an ionic or a nonionic surface active group, an organic polyisocyanate (D), and a polyol (B) added according to need, in the presence of an organic solvent (s) if necessary, with a neutralizing agent (E), dispersing in water, and removing a solvent, has excellent compatibility with other resins such as an acrylic resin (iia) and/or an urethane resin (iiu), imparts excellent light resistance without impairing favorable properties of the other resin, can improve a compounding stability to an aqueous emulsion of the other resin, shows less bleedout of the ultraviolet-absorbing resin on a surface of a coating film obtained from the emulsion, imparts stable light resistance to the other resin over a long period of time, and can impart excellent alkali resistance and solvent resistance to other resin having poor alkali resistance or solvent resistance. Therefore, the emulsion can be used for coating artificial leather, plastics, woody material or the like. Regarding Invention VIII, an aqueous polyurethane emulsion, constituted of a polyester diol (VIIIA) containing at least one diol selected from the group consisting of 2-n-butyl-2-ethyl-1,3-propanediol, 2,2-diethyl-1,3-propanediol, and 2,4-diethyl-1,5-pentanediol, null-caprolactone, and adipic acid, as an at least one structural component unit; a chain extender (VIIIB); a compound (C) containing an ionic and/or nonionic surface active group; an organic polyisocyanate (D); and a neutralizing agent (E), is an aqueous polyurethane emulsion using a polyester diol, but in spite of this, an artificial leather obtained from the same has excellent flexibility, light resistance, hydrolysis resistance and heat resistance.