Dye containing polarizing film
    12.
    发明授权
    Dye containing polarizing film 失效
    含偏光膜的染料

    公开(公告)号:US5609796A

    公开(公告)日:1997-03-11

    申请号:US322620

    申请日:1994-10-13

    摘要: A dye-containing polarizing film which comprises at least one dye selected from:dye represented by the following formula(1):Q1--N.dbd.N--Q2--X--Q3--N.dbd.N--Q4 (1)wherein Q1 and Q4 are phenyl or naphthyl group, Q2 and Q3 are phenylen group, X is azo or azoxy, and dye represented by the following formula(2): ##STR1## wherein Me is a transition metal selected from copper, nickel, zinc and iron, Q5 and Q6 are 1-naphthol or 2-naphthol residue, Y is azo or azoxy, R1 and R2 are hydrogen, lower alkyl, lower alkoxy or sulfo. The polarizing film exhibits polarizing activities not smaller than those of a iodine containing polarizing film, has excellent durability and does not cause light to break through the film by using several types of the specific dye in combination.

    摘要翻译: 含有选自下述式(1)表示的染料的至少一种染料的染料偏振膜:Q1-N = N-Q2-X-Q3-N = N-Q4(1)其中Q1和Q4为 苯基或萘基,Q2和Q3是亚苯基,X是偶氮或偶氮基,以及由下式(2)表示的染料:其中Me是选自铜,镍,锌和铁的过渡金属 ,Q5和Q6是1-萘酚或2-萘酚残基,Y是偶氮或氮氧基,R1和R2是氢,低级烷基,低级烷氧基或磺基。 偏振膜具有不低于含碘偏光膜的偏振活性,具有优异的耐久性,并且通过组合使用几种特定染料不会使光破裂。

    Azo-stibene condensates as leather dyes
    13.
    发明授权
    Azo-stibene condensates as leather dyes 失效
    偶氮萜烯作为皮革染料冷凝

    公开(公告)号:US4742162A

    公开(公告)日:1988-05-03

    申请号:US597212

    申请日:1984-04-06

    CPC分类号: C09B43/10 C09B56/04

    摘要: Condensates of an azo compound of the formula ##STR1## wherein n is 1 or 2, with the stilbene compound of the formula ##STR2## in the molar ratio of 1:1 to 2:1, dye leather in a yellowish-brown shade, which penetrate deeply into the leather, and give fast dyeings.

    摘要翻译: 其中n为1或2的式“IMAGE”的偶氮化合物与式(IMAGE)的1,2-二苯乙烯化合物的摩尔比为1:1至2:1的浓缩物,黄棕色阴影的染料皮革, 它深入皮革,并给予快速染色。

    Azo compounds containing both sulfo groups and basic or cationic groups
which compounds are in metal-free or 1:1 metal complex form

    公开(公告)号:US4594410A

    公开(公告)日:1986-06-10

    申请号:US409111

    申请日:1982-08-18

    申请人: Reinhard Pedrazzi

    发明人: Reinhard Pedrazzi

    摘要: Azo dyes of the formula ##STR1## and external salts thereof, wherein F is the residue of a monoazo or disazo compound in 1:1 metal complex form or of a trisazo, disazoazoxy or tetrakisazo compound in metal-free or 1:1 metal complex form,each X is independently --NR.sub.2 --Q--NR.sub.3 R.sub.4 or --NR.sub.2 --Q--N.sup..sym. R.sub.5 R.sub.6 R.sub.7, whereinQ is linear or branched C.sub.2-6 alkylene or --NH--CO--CH.sub.2 --,R.sub.2 is hydrogen or C.sub.1-4 alkyl,each of R.sub.3 and R.sub.4 is independently hydrogen; C.sub.1-6 alkyl; C.sub.2-6 alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted by 1, 2 or 3 C.sub.1-4 alkyl groups or --NR.sub.3 R.sub.4 is a saturated or unsaturated 5- or 6-membered heterocyclic ring containing, in addition to the nitrogen atom, no further or one further hetero atom,each of R.sub.5 and R.sub.6 is independently C.sub.1-6 alkyl; C.sub.2-6 alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted by 1, 2 or 3 C.sub.1-4 alkyl groups, andR.sub.7 is C.sub.1-4 alkyl or benzyl or ##STR2## is a saturated or unsaturated 5- or 6-membered heterocyclic ring containing, in addition to the nitrogen atom, no further or one further hetero atom or--N.sup..sym. R.sub.5 R.sub.6 R.sub.7 is pyridinium or pyridinium substituted by 1 or 2 methyl groups,each Z.sub.1 is independently --CO--, --SO.sub.2 -- or ##STR3## wherein R.sub.1 is hydrogen or C.sub.1-4 alkyl, andY is chloro, hydroxy, amino, an aliphatic, cycloaliphatic or aromatic amino group or a saturated heterocyclic amino group in which the nitrogen atom is part of the heterocyclic ring,each Z.sub.2 is independently ##STR4## wherein R.sub.1 is hydrogen or C.sub.1-4 alkyl,m is 1, 2 or 3,n is 0, 1, 2, 3 or 4, andp is 0, 1, 2, 3 or 4,with the proviso that n+2p.gtoreq.m+1, useful for dyeing and printing cotton, paper and leather.

    Trisazo/azoxy dyestuff mixtures
    20.
    发明授权
    Trisazo/azoxy dyestuff mixtures 失效
    三唑/偶氮染料混合物

    公开(公告)号:US4591634A

    公开(公告)日:1986-05-27

    申请号:US755037

    申请日:1985-07-15

    CPC分类号: C09B43/10

    摘要: Trisazo/azoxy dyestuff mixtures which in the form of free acid correspond to the formula ##STR1## in which R denotes H or optionally substituted alkyl,X and Y denote H, alkyl, alkoxy, halogen, hydroxyl, alkylsulphonyl, optionally mono- or di-alkyl-substituted sulphamyl, carboxyl and carboxyalkoxy andK denotes the radical of a coupling component,are outstandingly suitable for dyeing fibre materials containing hydroxyl groups and fibre materials containing amide groups, such as cotton, natural and synthetic polyamide, paper and leather. They give dyeings having good build-up capacity and good combinability.

    摘要翻译: 游离酸形式的三唑烷/偶氮染料混合物对应于式(Ⅰ),其中R表示H或任选取代的烷基,X和Y表示H,烷基,烷氧基,卤素,羟基,烷基磺酰基,任选单 - 或二烷基取代的磺酰基,羧基和羧基烷氧基,K表示偶联组分的基团,非常适用于染色含有羟基的纤维材料和含有酰胺基团的纤维材料,如棉花,天然和合成聚酰胺,纸和 皮革。 它们赋予具有良好的堆积能力和良好的组合性的染色。