公开(公告)号：US06649042B2

公开(公告)日：2003-11-18

申请号：US09797448

申请日：2001-03-01

Applicant: Carlos Gustavo Dassori ,  Nancy Fernandez ,  Rosa Arteca ,  Carlos Castillo

Inventor： Carlos Gustavo Dassori ,  Nancy Fernandez ,  Rosa Arteca ,  Carlos Castillo

IPC: C10G4500

CPC classification number: C10G65/04

Abstract: A process for hydroprocessing a hydrocarbon feedstock, includes the steps of providing a hydrocarbon feed having an initial characteristic; providing a first hydrogen-containing gas; feeding the hydrocarbon feed and the first hydrogen-containing gas cocurrently to a first hydroprocessing zone so as to provide a first hydrocarbon product; providing a plurality of additional hydroprocessing zones including a final zone and an upstream zone; feeding the first hydrocarbon product cocurrently with a recycled gas to the upstream zone so as to provide an intermediate hydrocarbon product; and feeding the intermediate hydrocarbon product cocurrently with a second hydrogen-containing gas to the final zone so as to provide a final hydrocarbon product having a final characteristic which is improved as compared to the initial characteristic.

公开(公告)号：US06638419B1

公开(公告)日：2003-10-28

申请号：US09959639

申请日：2002-01-10

Applicant: Pedro Da Silva ,  Raphaël Le Gall

Inventor： Pedro Da Silva ,  Raphaël Le Gall

IPC: C10G4500

CPC classification number: C10G53/06 ,  C10G32/00 ,  C10G53/14

Abstract: A method for obtaining oil products such as diesel fuel with improved quality, from a gas oil fraction containing organosulphur compounds such as dibenzenethiophenes and/or their derivatives, with initial and final boiling points generally ranging between about 170 and 480° C. The method includes at least two steps which consist in: (a) liquid-liquid extraction wherein the diesel fuel fraction is contacted with a solvent so as to obtain a gas oil-type raffinate with low content of sulphur and aromatic compounds and an extract rich in solvent and with high content of sulphur and aromatic compounds; (b) oxidation of the extract sulphur compounds so as to obtain, after separation, a heavy gas oil-type hydrocarbon effluent with low sulphur content, and a residue comprising oxidased organosulphur compounds. The invention also concerns oil products obtained by said method which can be used either for the formation of fuel for internal combustion engine with compression ignition (of the diesel type) or as fuel.

Abstract translation: 一种从含有有机硫化合物如二苯并噻吩和/或其衍生物的粗柴油馏分获得质量提高的柴油的油品的方法，其初始和最终沸点通常在约170和480℃之间。该方法包括 至少两个步骤，其包括：（a）液 - 液萃取，其中柴油燃料馏分与溶剂接触，以获得含硫量低的芳族化合物和富含溶剂的提取物的瓦斯油型萃余液和 具有高含量的硫和芳香族化合物; （b）萃取物硫化合物的氧化，以便在分离后获得具有低硫含量的重质瓦斯油型烃流出物和包含氧化有机硫化合物的残余物。 本发明还涉及通过所述方法获得的油产品，其可用于形成具有压缩点火（柴油型）或作为燃料的内燃机的燃料。

公开(公告)号：US06638418B1

公开(公告)日：2003-10-28

申请号：US10045285

申请日：2001-11-07

Applicant: Tom N. Kalnes ,  Vasant P. Thakkar ,  Richard K. Hoehn

Inventor： Tom N. Kalnes ,  Vasant P. Thakkar ,  Richard K. Hoehn

IPC: C10G4500

CPC classification number: C10G65/12 ,  C10G2400/04

Abstract: A dual recycle catalytic hydrocracking process for the production of ultra low sulfur diesel while simultaneously processing two feedstocks. One preferred feedstock boils in the temperature range of diesel and the second preferred feedstock boils in the temperature range above that of diesel.

Abstract translation: 双重循环催化加氢裂化方法，用于生产超低硫柴油，同时处理两种原料。 一种优选的原料在柴油的温度范围内沸腾，第二种优选的原料在高于柴油的温度范围内沸腾。

公开(公告)号：US06635170B2

公开(公告)日：2003-10-21

申请号：US09957939

申请日：2001-09-21

Applicant: Alberto Ravella

Inventor： Alberto Ravella

IPC: C10G4500

CPC classification number: C10G65/02 ,  C10G49/22 ,  C10G65/12

Abstract: This invention relates to a two stage hydroprocessing process with stripping zones between the hydroprocessing zones and following the last hydroprocessing zone. The stripping occurs at high pressure and temperature with no disengagement between or following the hydroprocessing zones. There is recycle of high temperature gaseous effluent from the last stripping zone to the first stripping zone.

公开(公告)号：US06447673B1

公开(公告)日：2002-09-10

申请号：US09803781

申请日：2001-03-12

Applicant: Merry Holli Garrett Cordera ,  Charles Allen Comeaux ,  Koenraad Jacques Herrebout ,  Joe David Hunter

Inventor： Merry Holli Garrett Cordera ,  Charles Allen Comeaux ,  Koenraad Jacques Herrebout ,  Joe David Hunter

IPC: C10G4500

CPC classification number: C10G45/08 ,  C10G49/002 ,  C10G65/04 ,  C10G65/12

Abstract: A hydrofining process in which a sulfur- and hydrocarbon-containing processing stream is supplied to a multi-stage hydrotreating reactor incorporating separate stages of cobalt molybdenum catalysts. Hydrogen may be supplied concurrently or counter-currently with the hydrocarbon-containing processing stream. The processing stream is passed into contact with an initial catalyst stage comprising a cobalt molybdenum desulfurization catalyst present in a minor amount of the total composite amount of catalysts within the reactor. Thereafter the processing stream is passed through a subsequent catalyst stage comprising a major amount of cobalt molybdenum hydrocracking catalyst. The effluent stream having a reduced sulfur content is then withdrawn from the hydrotreating reactor. The initial and subsequent catalyst stages are separated by an intervening sector within the reactor containing an inert particulate refractory material, specifically silica particles generally spheroidal in shape.

Abstract translation: 一种加氢精制方法，其中将含硫和烃的处理流供应到包含单独的钴钼催化剂级的多级加氢处理反应器。 可以与含烃处理流同时或逆向提供氢。 使处理流与初始催化剂阶段接触，所述初始催化剂阶段包含在反应器内少量总复合量的催化剂中存在的钴钼脱硫催化剂。 此后，处理流通过包括大量钴钼加氢裂化催化剂的后续催化剂阶段。 然后从加氢处理反应器中取出具有降低的硫含量的流出物流。 初始催化剂阶段和随后的催化剂阶段由反应器内的中间部分分开，其中包含惰性颗粒耐火材料，特别是通常为球形的二氧化硅颗粒。

公开(公告)号：US06444118B1

公开(公告)日：2002-09-03

申请号：US09785909

申请日：2001-02-16

Applicant: Gary G. Podrebarac ,  Gary R. Gildert

Inventor： Gary G. Podrebarac ,  Gary R. Gildert

IPC: C10G4500

CPC classification number: C10G65/043 ,  C10G45/00 ,  C10G45/02 ,  C10G2300/4087 ,  Y10S203/06

Abstract: A process for concurrently fractionating and treating of a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification or selective hydrogenation and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans, dienes or mixtures may be subjected to a second thioetherification or selective hydrogenation, depending on its make-up, and then passed on to a polishing hydrodesulfurization reactor or the entire intermediate stream may be passed directly to the polishing reactor. The bottoms are subjected to concurrent hydrodesulfurization and fractional distillation and the combined overheads and bottoms are fed to the polishing reactor. The effluent from the polishing reactor may be combined with the light boiling range naphtha to produce a new full boiling range naphtha containing substantially less total sulfur than the original feed. The object being to meet higher standards for sulfur removal, by treating the components of the naphtha feed with the process that preserves the olefinic while most expediently removing the sulfur compounds.

Abstract translation: 一种用于同时分馏和处理全程石脑油流的方法。 全沸点石脑油流首先进行同时硫代醚化或选择性氢化和分解成轻沸点石脑油，中沸程石脑油和重沸点石脑油。 含有噻吩和噻吩沸点范围的硫醇，二烯或混合物的中间沸点石脑油可根据其组成进行第二次硫醚化或选择性氢化，然后转入抛光加氢脱硫反应器，或者整个中间体流可以是 直接通过抛光反应器。 将塔底物进行同时加氢脱硫和分馏，并将组合的塔顶馏出物和塔底物加入抛光反应器。 来自抛光反应器的流出物可以与轻沸点石脑油组合以产生新的全沸点石脑油，其中含有比原始进料更少的总硫。 目的是要通过用保留烯烃的方法处理石脑油进料的组分，同时最有利地除去硫化合物，以达到更高的脱硫标准。

公开(公告)号：US06340430B1

公开(公告)日：2002-01-22

申请号：US09397350

申请日：1999-09-15

Applicant: Brian Murray Wood

Inventor： Brian Murray Wood

IPC: C10G4500

CPC classification number: C10G65/08

Abstract: A hydrotreating process is presented for both dewaxing the diesel fraction and reducing the aromatic content of kerosene fraction of a distillate boiling range feed stream. The feed stream is flashed to generate vapor and liquid phase streams. The portion which comprises most of the heavy diesel is passed into a dewaxing zone. The vapor-phase stream, preferably rich in kerosene and light diesel, is used to quench the effluent of the dewaxing zone before it is passed into a downstream aromatics hydrogenation zone. Depending on the composition of the feed to the process, a second flashing step performed in the presence of added hydrogen may be employed to produce the feed to the dewaxing zone. PNA's may be hydrogenated prior to recycling to a hydrocracking zone.

Abstract translation: 提出了加氢处理方法，用于脱蜡柴油馏分和降低馏出物沸程进料流的煤油馏分的芳族含量。 进料流被闪蒸以产生蒸气和液相流。 包含大部分重柴油的部分进入脱蜡区。 优选使用富含煤油和轻柴油的气相物流，在脱蜡区的流出物进入下游芳族化合物氢化区之前，将其脱气。 取决于该方法的进料的组成，可以使用在加入的氢气存在下进行的第二闪蒸步骤以产生脱蜡区的进料。 在再循环到加氢裂化区之前，PNA可能被氢化。

公开(公告)号：US06306289B1

公开(公告)日：2001-10-23

申请号：US09423833

申请日：1999-11-16

Applicant: Fumitaka Hayashi ,  Akira Kamo ,  Hiroshi Toshima

Inventor： Fumitaka Hayashi ,  Akira Kamo ,  Hiroshi Toshima

IPC: C10G4500

CPC classification number: B01J23/88 ,  B01J21/02 ,  B01J21/10 ,  B01J21/12 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/108 ,  B01J37/0205 ,  B01J37/03 ,  C10G45/08

Abstract: A hydrotreating catalyst having both a high desulfurization activity and a denitrogenation activity and a method of hydrotreating a hydrocarbon oil using the same is provided. A hydrotreatment catalyst comprising a silica-alumina carrier loaded with at least one hydrogenation-active component; wherein (1) the silica content is in the range of 2 to 40% by weight based on the total weight of the carrier; and (2) in the spectrum obtained by nuclear magnetic resonance analysis (29Si-NMR), (i) the area of the peak at −80 ppm is 10% or more of the combined area of all the peaks; and (ii) the combined area of peaks at −80 ppm, −86 ppm and −92 ppm is 20% or more of the combined area of all peaks; a hydrotreating catalyst comprising a silica-alumina carrier containing a specific amount of a third component loaded with at lest one hydrogenation-active metal component and having a specific pore structure; and a method of hydrotreating a hydrocarbon oil comprising contacting a hydrocarbon oil with hydrogen in the presence of said hydrotreating catalyst.

Abstract translation: 提供具有高脱硫活性和脱氮活性的加氢处理催化剂，以及使用其加氢处理烃油的方法。一种加氢处理催化剂，其包含负载有至少一种氢化活性组分的二氧化硅 - 氧化铝载体; 其中（1）基于所述载体的总重量，二氧化硅含量在2-40重量％的范围内; 和（2）在通过核磁共振分析（29Si-NMR）获得的光谱中，（i）-80ppm处的峰面积为所有峰的组合面积的10％以上; 和（ii）-80ppm，-86ppm和-92ppm的峰的组合面积为所有峰的组合面积的20％或更多; 加氢处理催化剂，其包含含有特定量的第三组分的二氧化硅 - 氧化铝载体，所述第三组分装载有至少一种氢化活性金属组分并具有特定孔结构; 以及加氢处理烃油的方法，包括在所述加氢处理催化剂存在下使烃油与氢气接触。

公开(公告)号：US06203695B1

公开(公告)日：2001-03-20

申请号：US09528197

申请日：2000-03-17

Applicant: Virginie Harle ,  Slavik Kazstelan ,  Frédéric Morel ,  Stéphane Kressmann ,  Philippe Courty

Inventor： Virginie Harle ,  Slavik Kazstelan ,  Frédéric Morel ,  Stéphane Kressmann ,  Philippe Courty

IPC: C10G4500

CPC classification number: B01J37/0018 ,  B01J21/04 ,  B01J23/85 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  C10G45/04 ,  C10G45/08 ,  C10G49/02 ,  C10G49/04

Abstract: A process for hydrotreating a hydrocarbon feed, comprising subjecting said feed to hydrotreating conditions in the presence of a catalyst comprising an essentially alumina-based extruded support, essentially constituted by a plurality of juxtaposed agglomerates, optionally at least one catalytic metal or a compound of a catalytic metal from group VIB (group 6 of the new periodic table notation) and/or optionally, at least one catalytic metal or a compound of a catalytic metal from group VIII (group 8, 9 and 10 of the new periodic table notation), in which the sum S of the group VIB and VIII metals, expressed as the oxides, is 0% to 50% by weight, and wherein each of these agglomerates is partly in the form of packs of flakes and partly in the form of needles, said needles being uniformly dispersed both about the packs of flakes and between the flakes, in which the alumina agglomerates are obtained by forming a starting alumina originating from rapid dehydration of hydrargillite and in which the amount of alumina from boehmite decomposition is 5% to 70% by weight.

Abstract translation: 一种用于加氢烃化进料的方法，包括在催化剂存在下使所述进料加氢处理，所述催化剂包含基本上由氧化铝为基础的挤出载体，所述催化剂基本上由多个并置的附聚物，任选的至少一种催化金属或 来自VIB族的催化金属（新周期表符号的第6族）和/或任选的至少一种催化金属或来自第VIII族的催化金属的化合物（新的周期表符号的第8,9和10族） 其中以氧化物表示的VIB族和VIII族金属的总和S为0重量％至50重量％，并且其中这些附聚物中的每一个部分为薄片包装形式，部分为针状， 所述针均匀地分散在薄片包装片和薄片之间，其中通过形成起始氧化铝，其中氧化铝附聚物通过形成来自hydrargite的快速脱水的起始氧化铝和 其中勃姆石分解的氧化铝的量为5重量％至70重量％。

公开(公告)号：US06190540B1

公开(公告)日：2001-02-20

申请号：US09083872

申请日：1998-05-22

Applicant: Kaaeid A. Lokhandwala ,  Richard W. Baker

Inventor： Kaaeid A. Lokhandwala ,  Richard W. Baker

IPC: C10G4500

CPC classification number: C10G49/007 ,  C10G49/22

Abstract: A process for hydroprocessing a fluid stream containing at least hydrogen and hydrocarbons. The process uses a hydrocarbon-selective membrane to reduce the concentration of hydrocarbons and contaminants in the hydrogen stream recycled to the hydroprocessing reactor. The membrane can operate in the presence of hydrogen sulfide. The process also provides the opportunity for increased NGL recovery from the hydrocarbon-enriched membrane permeate stream.

Abstract translation: 用于加氢处理至少含有氢和烃的流体流的方法。 该方法使用烃选择性膜来减少再循环到加氢处理反应器的氢气流中的烃和污染物的浓度。 膜可以在硫化氢存在下操作。 该方法还提供了从富含烃的膜渗透物流中增加NGL回收的机会。