Abstract:
A system for preventing hydrate formation in a pipeline includes a heater housing. The heater housing has an outer diameter sized to travel within the pipeline. A turbine assembly is located within the heater housing. The turbine assembly has a blade that is rotatable by a flow of fluid within the pipeline. An electric heater is located within the heater housing and is electrically connected to the turbine assembly. The electric heater is selectively contacted by the flow of fluid within the pipeline.
Abstract:
A system for depressurizing a gas in a pipeline is described. The system com-prises an expander configured and arranged for generating mechanical power by expanding gas from a first pressure to a second pressure. The system further comprises a heat pump and a heat transfer circuit containing a heat transfer fluid circu-lating therein, for receiving heat from the heat pump and delivering heat to the gas through a heat exchanger. A controller is further provided, configured and arranged for modulating a flow rate of the heat transfer fluid circulating in the heat transfer circuit as a function of a heat rate to be transferred from the heat transfer fluid to the gas, particularly as a function of temperature differentials between the gas and the heat transfer fluid at a gas inlet side and a gas outlet side of the heat exchang-er.
Abstract:
A method for controlling a pipeline system is provided. The method includes powering on an electrical heating source for heating the pipeline system. The method further includes powering off the electrical heating source, powering at least a sensor along the pipeline system for measuring a physical property, and communicating the measured data to a remote communication destination.
Abstract:
A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents involves treating the fluid with an inhibitor comprising a substantially water soluble polymer having a polymer backbone .with a pendant C.sub.1 --C.sub.3 alkyl group; the polymer having an average molecular weight between about 1,000 and about 6,000,000. Preferably, the pendant alkyl group is a methyl group. The rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream Is reduced using the alkylated polymer backbone inhibitor, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. Test results are disclosed which unexpectedly show that alkylating the polymer backbone with a methyl group will produce a subcooling for the alkylated polymer that is at least about 2.degree. F. (about 1.1.degree. C.) greater than its nonalkylated counterpart. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.
Abstract:
A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is claimed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble polymers having N-vinyl amide or N-allyl amide units. Specific examples of such copolymers include, N-vinyl-N-methylacetamide (VIMA) copolymerized with acryloylpyrrolidine (APYD) or acryloylpiperidine (APID), and more preferably, VIMA copolymerized with N-substituted methacrylamides, such as N-isopropylmethacrylamide (iPMAM) and methacryloylpyrrolidine (MAPYD) to produce inhibitors for practicing the claimed method.
Abstract:
Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.
Abstract:
A method for inhibiting the formation and/or agglomeration of clathrate hydrates in a petroleum fluid stream containing water is disclosed. The disclosed method uses predetermined inhibitors having a guest group, a polymer backbone, and an anchor group positioned between the guest group and the polymer backbone. The inhibitor predetermination method comprises selection of the polymer backbone, anchor group and guest group using several types of criteria. The polymer backbone should produce a substantially water soluble polymer in combination with the anchor group and the guest group. The anchor group should be a hydrophilic moiety with between one and four hydrogen bonding atoms. The guest group should be either a hydrophobic or amphiphilic moiety with a carbon atom to heteroatom ratio greater than or equal to about two to one and an average van der Waals diameter between about 3.8 angstroms and about 8.6 angstroms. Some inhibitors selected using the disclosed predetermination method have produced a subcooling temperature of about 30.0.degree. F. Of 56 predetermined inhibitors, 18 have produced a subcooling temperature .gtoreq.24.0.degree. F., 22 have produced a subcooling temperature 10.0.degree. F.
Abstract:
A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitor used for practicing the method is selected from the family of substantially water soluble copolymers formed from N-methyl-N-vinylacetamide (VIMA) and one of three comonomers, vinylpyrrolidone (VP), vinylpiperidone (VPip), or vinylcaprolactam (VCap). VIMA/VCap is the preferred copolymer. These copolymers may be used alone or in combination with each other or other hydrate inhibitors. Preferably, a solvent, such as water, brine, alcohol, or mixtures thereof, is used to produce an inhibitor solution or mixture to facilitate treatment of the petroleum fluid stream.