公开(公告)号：US07450292B1

公开(公告)日：2008-11-11

申请号：US11526416

申请日：2006-09-22

Applicant: Anthony K. Burrell ,  Anoop Agrawal ,  John P. Cronin ,  Juan C. L. Tonazzi ,  Benjamin P. Warner ,  T. Mark McCleskey

Inventor： Anthony K. Burrell ,  Anoop Agrawal ,  John P. Cronin ,  Juan C. L. Tonazzi ,  Benjamin P. Warner ,  T. Mark McCleskey

IPC: G02F1/153 ,  G02F1/15 ,  G02F1/00

CPC classification number: C09K9/02 ,  B60R1/088 ,  B82Y20/00 ,  C09K2211/1029 ,  G02F1/1521 ,  G02F1/155 ,  G02F1/157 ,  G02F2202/022 ,  G02F2202/36

Abstract: Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3−), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N−), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N−) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C−). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

Abstract translation: 使用廉价，低导电性的导体制备电致变色器件如后视镜和低漏电流的显示器的电解液。 优选的电解质包括双功能氧化还原染料和熔融盐溶剂，对紫外线辐射具有增强的稳定性。 溶剂包括锂或季铵阳离子，和全氟磺酰亚胺阴离子，选自三氟甲基磺酸酯（CF 3 SO 3 SO 2），双（三氟甲基磺酰基）酰亚胺 （（CF 3 SO 2）2 N - ），双（全氟乙基磺酰基）酰亚胺（（CF _{3（三氟甲基磺酰基）甲基化（（3,3-二甲基-2- （CF 3 SO 2）3） - （CH 3）3）。 具有纳米结构电极的电致发光，电致变色和光电致变色装置包括具有双功能氧化还原染料的离子液体。 当使用解决方案的设备供电时，一些电解液颜色变红，导致红色或中性电光设备。}

公开(公告)号：US07129093B2

公开(公告)日：2006-10-31

申请号：US10812444

申请日：2004-03-30

Applicant: T. Mark McCleskey ,  Deborah S. Ehler ,  Kevin D. John ,  Anthony K. Burrell ,  Gavin E. Collis ,  Edel M. Minogue ,  Benjamin P. Warner

Inventor： T. Mark McCleskey ,  Deborah S. Ehler ,  Kevin D. John ,  Anthony K. Burrell ,  Gavin E. Collis ,  Edel M. Minogue ,  Benjamin P. Warner

IPC: G01N33/20

CPC classification number: G01N21/643 ,  G01N31/22 ,  G01N2021/7786 ,  Y10T436/25125 ,  Y10T436/25875

Abstract: A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.

Abstract translation: 一种测定样品中铍或其铍化合物的方法，包括提供疑似含有铍或其化合物的样品，通过溶解于溶液中，从样品中提取铍或其化合物，向溶液中加入荧光指示剂 从而将任何铍或其化合物与荧光指示剂结合，并通过测量荧光来确定样品中任何铍或其化合物的存在或量。

公开(公告)号：US06961168B2

公开(公告)日：2005-11-01

申请号：US10741903

申请日：2003-12-19

Applicant: Anoop Agrawal ,  John P. Cronin ,  Juan C. L. Tonazzi ,  Benjamin P. Warner ,  T. Mark McCleskey ,  Anthony K. Burrell

Inventor： Anoop Agrawal ,  John P. Cronin ,  Juan C. L. Tonazzi ,  Benjamin P. Warner ,  T. Mark McCleskey ,  Anthony K. Burrell

IPC: C25B1/00 ,  G02B5/23 ,  G02F20060101 ,  G02F1/00 ,  G02F1/15 ,  G02F1/153 ,  G02F1/155

CPC classification number: C09K9/02 ,  B60R1/088 ,  C09K2211/1029 ,  G02F1/1521 ,  G02F1/157 ,  G02F2202/36

Abstract: Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3−), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N−), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N−) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C−). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

公开(公告)号：US06949238B2

公开(公告)日：2005-09-27

申请号：US10360544

申请日：2003-02-05

Applicant: William Tumas ,  Kevin C. Ott ,  T. Mark McCleskey ,  Matthew Z. Yates ,  Eva R. Birnbaum

Inventor： William Tumas ,  Kevin C. Ott ,  T. Mark McCleskey ,  Matthew Z. Yates ,  Eva R. Birnbaum

IPC: C01B37/04 ,  C01B39/54

CPC classification number: C01B37/04 ,  C01B39/54 ,  Y10S423/30

Abstract: Novel zeolites are produced by combining a polar solute, a silicon or phosphorous source, and a structure directing agent. Surfactants and a hydrophobic solvent are added to the previously mixed three species and shaken to disperse the surfactants. The reverse microemulsion is stirred overnight, at about room temperature and then iced for five to ten minutes. A metal source is added vigorously shaken for about two minutes. The mixture is then aged for about two hours at about room temperature. A mineralizer is added and the resultant mixture aged for about two hours at about room temperature. The mixture is heated to about 180° C., for a suitable time period. The final novel product is then isolated.

Abstract translation: 通过组合极性溶质，硅或磷源和结构导向剂来制备新型沸石。 将表面活性剂和疏水性溶剂加入到先前混合的三种物质中并摇动以分散表面活性剂。 将反相微乳液在约室温下搅拌过夜，然后冰化5至10分钟。 将金属源剧烈振动约两分钟。 然后将混合物在约室温下老化约2小时。 加入矿化剂，所得混合物在约室温下老化约2小时。 将混合物加热至约180℃，持续合适的时间。 然后分离最终的新产品。

公开(公告)号：US06599962B2

公开(公告)日：2003-07-29

申请号：US09835256

申请日：2001-04-12

Applicant: T. Mark McCleskey ,  Matthew Z. Yates

Inventor： T. Mark McCleskey ,  Matthew Z. Yates

IPC: C08J300

CPC classification number: C08J3/21

Abstract: There has been invented a method for incorporating additives into polymers comprising: (a) forming an aqueous or alcohol-based colloidal system of the polymer; (b) emulsifying the colloidal system with a compressed fluid; and (c) contacting the colloidal polymer with the additive in the presence of the compressed fluid. The colloidal polymer can be contacted with the additive by having the additive in the compressed fluid used for emulsification or by adding the additive to the colloidal system before or after emulsification with the compressed fluid. The invention process can be carried out either as a batch process or as a continuous on-line process.

公开(公告)号：US06176895B1

公开(公告)日：2001-01-23

申请号：US09185891

申请日：1998-11-04

Applicant: Joseph M. DeSimone ,  William Tumas ,  Kimberly R. Powell ,  T. Mark McCleskey ,  Timothy J. Romack ,  James B. McClain ,  Eva R. Birnbaum

Inventor： Joseph M. DeSimone ,  William Tumas ,  Kimberly R. Powell ,  T. Mark McCleskey ,  Timothy J. Romack ,  James B. McClain ,  Eva R. Birnbaum

IPC: C22B326

CPC classification number: C22B3/0005 ,  C22B3/0097 ,  Y02P10/234

Abstract: A composition useful for the extraction of metals and metalloids comprises (a) carbon dioxide fluid (preferably liquid or supercritical carbon dioxide); and (b) a polymer in the carbon dioxide, the polymer having bound thereto a ligand that binds the metal or metalloid; with the ligand bound to the polymer at a plurality of locations along the chain length thereof (i.e., a plurality of ligands are bound at a plurality of locations along the chain length of the polymer). The polymer is preferably a copolymer, and the polymer is preferably a fluoropolymer such as a fluoroacrylate polymer. The extraction method comprises the steps of contacting a first composition containing a metal or metalloid to be extracted with a second composition, the second composition being as described above; and then extracting the metal or metalloid from the first composition into the second composition.

Abstract translation: 用于萃取金属和准金属的组合物包括（a）二氧化碳流体（优选液体或超临界二氧化碳）; 和（b）二氧化碳中的聚合物，所述聚合物结合有与金属或准金属结合的配体; 其中配体在其长度的多个位置处与聚合物结合（即，多个配体沿聚合物链长度的多个位置结合）。 聚合物优选为共聚物，聚合物优选为氟聚合物，例如氟代丙烯酸酯聚合物。 提取方法包括以下步骤：将含有待萃取的金属或准金属的第一组合物与第二组合物接触，第二组合物如上所述; 然后将金属或准金属从第一组合物提取到第二组合物中。