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1.发明授权Zeolite, process for producing the same, adsorbent comprising the zeolite, heat utilization system, adsorption heat pump, cold/heat storage system, and air-conditioning apparatus for humidity regulation 失效沸石，其制造方法，包含沸石的吸附剂，热利用系统，吸附热泵，冷/热储存系统和用于湿度调节的空调装置公开(公告)号：US07527777B2
公开(公告)日：2009-05-05
申请号：US11311562
申请日：2005-12-20
申请人： Hiromu Watanabe , Takahiko Takewaki , Masanori Yamazaki , Hiroyuki Kakiuchi , Kouji Inagaki , Atsushi Kosaka , Norikazu Hosokawa
发明人： Hiromu Watanabe , Takahiko Takewaki , Masanori Yamazaki , Hiroyuki Kakiuchi , Kouji Inagaki , Atsushi Kosaka , Norikazu Hosokawa
CPC分类号： B82Y30/00 , B01J20/0292 , B01J20/18 , B82Y10/00 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/54 , F25B17/08 , Y02P20/129 , Y10S423/30
摘要： Subjects for the invention are to provide a zeolite reduced in performance deterioration in repetitions of use or during long-term use and a process for producing the same and to provide an adsorbent comprising the zeolite and a heat utilization system or the like employing the adsorbent.The invention relates to a zeolite which has a framework density of from 10 T/nm3 to 16 T/nm3 and a carbon content of from 1% by weight to 6% by weight and satisfies the following (1) or (2): (1) the zeolite is an aluminophosphate which has a nitrogen content of from 0.5% by weight to 12% by weight and in which the aluminum may be partly replaced by Me; (2) the zeolite is a silicoaluminophosphate in which the aluminum may be partly replaced by Me and which, when burned to a carbon content lower than 0.3% by weight, retains the framework structure possessed by the silicoaluminophosphate before the burning: (provided that Me in (1) and (2) above is at least one element selected from the elements in Groups 2A, 7A, 8, 1B, and 2B of the periodic table).
摘要翻译： 本发明的目的是提供在使用重复或长期使用中降低性能劣化的沸石及其制备方法，并提供使用该吸附剂的沸石的吸附剂和热利用系统等。 本发明涉及一种沸石，其骨架密度为10T / nm 3至16T / nm 3，碳含量为1％至6％（重量），满足下列（1）或（2）：（ 1）沸石是氮含量为0.5重量％至12重量％的铝磷酸盐，其中铝可部分被Me取代; （2）沸石是硅铝磷酸盐，其中铝可以部分地被Me替代，并且当燃烧到低于0.3重量％的碳含量时，在燃烧之前保留硅铝磷酸盐所具有的骨架结构：（如果Me 在上述（1）和（2）中，是选自元素周期表第2A，7A，8，1B和2B族元素中的至少一种元素）。
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公开(公告)号：US06974889B1
公开(公告)日：2005-12-13
申请号：US09744697
申请日：1999-07-28
申请人： Jannetje Maatje van den Berge, legal representative , Machteld Maria Wilfried Mertens , Wilfried Jozef Mortier , Marcel Johannes Janssen , Cornelius Maria Wilhelmus Van Oorschot
IPC分类号： B01D53/02 , B01J20/18 , B01J29/18 , B01J29/65 , B01J29/70 , B01J29/85 , B01J35/00 , C01B37/00 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/02 , C01B39/26 , C01B39/44 , C01B39/46 , C01B39/48 , C01B39/54 , C01G3/00 , C07B61/00 , C07C1/24 , C07C11/04 , C07C11/06 , C07C11/08 , C10G3/00 , C01B25/26 , B01J27/16 , B01J27/182 , C01B33/26 , C07C1/207
CPC分类号： B01J29/7026 , B01J20/0292 , B01J20/18 , B01J29/18 , B01J29/50 , B01J29/65 , B01J29/7011 , B01J29/7023 , B01J29/85 , B01J35/0013 , B01J2229/62 , C01B37/00 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/02 , C01B39/265 , C01B39/44 , C01B39/445 , C01B39/48 , C01G3/00 , C10G3/49 , C10G25/03 , C10G2400/20 , C10G2400/22 , Y02P30/20
摘要： Colloidal crystalline molecular sieve seeds are used in phosphorus-containing crystalline molecular sieve manufacture. Certain of the products have enhanced utility in oxygenate conversions.
摘要翻译： 胶态结晶分子筛种子用于含磷结晶分子筛制造。 某些产品具有提高氧合转化率的效用。
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3.发明授权Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same 有权具有限定中孔的窄尺寸分布的微孔结晶壁的材料及其制备方法
公开(公告)号：US5902564A
公开(公告)日：1999-05-11
申请号：US178678
申请日：1998-10-26
申请人： Juan Lujano , Yilda Romero , Jose Carrazza
发明人： Juan Lujano , Yilda Romero , Jose Carrazza
IPC分类号： B01J29/08 , B01J20/18 , B01J20/28 , B01J29/04 , B01J29/83 , B01J35/10 , C01B37/00 , C01B37/04 , C01B39/00 , C01B39/02 , C01B39/04 , C01B39/22 , C01B39/54 , C01B39/24
CPC分类号： C01B39/22 , B01J20/18 , B01J29/04 , B01J35/002 , B01J35/1038 , B01J35/1057 , B01J35/1061 , B01J35/108 , C01B37/04 , C01B39/04 , Y10S423/14 , Y10S423/21
摘要： The invention relates to a synthetic crystalline material and its use in catalytic conversion of organic compounds and as a sorbent. The crystalline material contains one or more microporous crystalline phases, having a micropore volume greater than or equal to about 0.15 cc/g distributed in channels between about 3 to about 15 .ANG. in average diameter which is rendered accessible by a mesopore volume of greater than or equal to about 0.1 cc/g distributed in channels between about 20 to about 100 .ANG. in average diameter. A process is also provided for preparing the crystalline material of the present invention.
摘要翻译： 本发明涉及一种合成结晶材料及其在有机化合物的催化转化和吸附剂中的应用。 结晶材料包含一个或多个微孔结晶相，其具有大于或等于约0.15cc / g的微孔体积，其通道平均直径为约3至约15 ANGSTROM，通过介孔体积大于或等于 分布在平均直径约20至约100安培之间的通道中约0.1cc / g。 还提供了制备本发明的结晶材料的方法。
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公开(公告)号：US5879655A
公开(公告)日：1999-03-09
申请号：US970369
申请日：1992-11-02
CPC分类号： C01B37/04 , B01J29/84 , B01J29/85 , C01B37/08 , Y10S423/30
摘要： The present invention is a method for synthesizing non-zeolitic molecular sieves which have a three-dimensional microporous framework structure comprising �AlO.sub.2 ! and �PO.sub.2 ! units. In preparing the reaction mixture, a critical feature of the invention is for the molar ratio of the templating agent to phosphorus be greater than about 0.05 before the molar ratio of aluminum to phosphorus is greater than about 0.5.
摘要翻译： 本发明是一种合成非沸石分子筛的方法，其具有包含[AlO 2]和[PO 2]单元的三维微孔骨架结构。 在制备反应混合物时，本发明的关键特征是在铝与磷的摩尔比大于约0.5之前，模板剂与磷的摩尔比大于约0.05。
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公开(公告)号：US5849258A
公开(公告)日：1998-12-15
申请号：US659645
申请日：1996-06-06
申请人： Juan Lujano , Yilda Romero , Jose Carrazza
发明人： Juan Lujano , Yilda Romero , Jose Carrazza
IPC分类号： B01J29/08 , B01J20/18 , B01J20/28 , B01J29/04 , B01J29/83 , B01J35/10 , C01B37/00 , C01B37/04 , C01B39/00 , C01B39/02 , C01B39/04 , C01B39/22 , C01B39/54
CPC分类号： C01B39/22 , B01J20/18 , B01J29/04 , B01J35/002 , B01J35/1038 , B01J35/1057 , B01J35/1061 , B01J35/108 , C01B37/04 , C01B39/04 , Y10S423/14 , Y10S423/21
摘要： The invention relates to a synthetic crystalline material and its use in catalytic conversion of organic compounds and as a sorbent. The crystalline material contains one or more microporous crystalline phases, having a micropore volume greater than or equal to about 0.15 cc/g distributed in channels between about 3 to about 15 .ANG. in average diameter which is rendered accessible by a mesopore volume of greater than or equal to about 0.1 cc/g distributed in channels between about 20 to about 100 .ANG. in average diameter. A process is also provided for preparing the crystalline material of the present invention.
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公开(公告)号：US5741751A
公开(公告)日：1998-04-21
申请号：US704055
申请日：1996-08-28
申请人： Stephen J. Miller
发明人： Stephen J. Miller
IPC分类号： B01J29/82 , B01J29/85 , C01B37/04 , C01B37/06 , C01B37/08 , C10G11/05 , C10G45/64 , C10G47/16 , B01J27/18 , B01J27/182 , B01J27/188 , B01J27/198
摘要： This invention provides a method for preparing non-zeolitic molecular sieves using inexpensive reagents and at lower manufacturing cost. The method includes using a low density, small size particulate hydrated alumina, such as aluminum hydroxide, in place of aluminum alkoxides and other more costly reagents. The preferred particulate hydrated alumina has a density of less than 1.0 g/cm.sup.3, an average particle size of less than about 40 microns and an alkali content of less than 0.12 wt %.
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7.发明授权Colored crystalline aluminophosphates and/or silicoaluminophosphates of the AEL or VFI type 失效AEL或VFI型彩色结晶铝磷酸盐和/或硅铝磷酸盐
公开(公告)号：US5360474A
公开(公告)日：1994-11-01
申请号：US946406
申请日：1992-09-16
IPC分类号： B01J20/10 , B01J20/18 , B01J27/18 , B01J27/182 , B01J29/83 , B01J29/85 , C01B25/36 , C01B37/04 , C01B37/08 , C07F9/02 , C09B67/08 , B01J31/26 , C08K5/08
CPC分类号： B01J20/0292 , B01J20/18 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , Y10S423/30
摘要： Colored crystalline alumophosphates and/or silicoalumophsophates of the AEL or VFI type useful as dyes, optical elements and as adsorbents have the following X-ray diffraction diagram:______________________________________ Interplanar spacing Relative intensity d(A) I/I.sub.o .times. 100 ______________________________________ 10.91 .+-. 0.1 26 .+-. 10 9.19 .+-. 0.1 41 .+-. 10 6.79 .+-. 0.05 16 .+-. 10 5.57 .+-. 0.05 52 .+-. 10 4.39 .+-. 0.05 39 .+-. 10 4.18 .+-. 0.05 71 .+-. 10 4.09 .+-. 0.05 33 .+-. 10 3.98 .+-. 0.05 57 .+-. 10 3.86 .+-. 0.05 68 .+-. 10 3.81 .+-. 0.05 100 ______________________________________ and a composition described by the following formula:a quinizarin.b Al.sub.2 O.sub.3.c P.sub.2 O.sub.5.d SiO.sub.2where a is from 0.05 to 2, b and c are each from 8 to 12, and d is from 0 to 4.
摘要翻译： 可用作染料，光学元件和吸附剂的AEL或VFI型彩色结晶铝磷酸盐和/或硅铝酸盐具有以下X射线衍射图： - 平面间距相对强度-d（A）I / Io×100 -10.91 + / - 0.1 26 +/- 10 -9.19 +/- 0.1 41 +/- 10 -6.79 +/- 0.05 16 +/- 10 -5.57 +/- 0.05 52 +/- 10 -4.39 +/- 0.05 39 +/- 10 -4.18 +/- 0.05 71 +/- 10 -4.09 +/- 0.05 33 +/- 10 -3.98 +/- 0.05 57 +/- 10 -3.86 +/- 0.05 68 +/- 10 -3.81 +/- 0.05 100 - 和由下式描述的组合物：醌茜嗪b Al 2 O 3·c P 2 O 5·d 2 O其中a为0.05至2，b和c各自为8至12，d为0至4。
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公开(公告)号：US5326464A
公开(公告)日：1994-07-05
申请号：US397076
申请日：1989-08-22
IPC分类号： B01J20/18 , B01J23/04 , B01J29/82 , B01J29/84 , B01J29/85 , B01J39/12 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/48 , C10G11/02 , C07C4/06 , C10G47/04
CPC分类号： C01B37/08 , B01J20/18 , B01J23/04 , B01J29/82 , B01J29/84 , B01J29/85 , B01J39/12 , C01B33/28 , C01B37/04 , C01B37/06
摘要： A process for converting feedstock comprising hydrocarbon compounds to product comprising hydrocarbon compounds of lower molecular weight than said feedstock hydrocarbon compounds which comprises contacting said feedstock at conditions for said conversion with catalyst comprising crystals having a framework topology after heating at 110.degree. C. or higher giving an X-ray diffraction pattern with interplanar d-spacings at 16.4.+-.0.2 Angstroms, 8.2.+-.0.1 Angstroms, 6.21.+-.0.05 Angstroms, 6.17.+-.0.05 Angstroms, 5.48.+-.0.05 Angstroms and 4.74.+-.0.05 Angstroms, and without a significant interplanar d-spacing at 13.6-13.3 Angstroms.
摘要翻译： 将包含烃化合物的原料转化成包含比所述原料烃化合物低分子量烃化合物的产物的方法，该方法包括在所述转化条件下将所述原料与包含在110℃或更高温度下加热后具有骨架拓扑结构的催化剂接触， 具有16.4 +/- 0.2埃，8.2 +/- 0.1埃，6.21 +/- 0.05埃，6.17 +/- 0.05埃，5.48 +/- 0.05埃和4.74克/升的平面d间距的X射线衍射图， -0.05埃，并且在13.6-13.3埃处没有显着的晶面d间距。
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公开(公告)号：US5308813A
公开(公告)日：1994-05-03
申请号：US11915
申请日：1993-02-01
IPC分类号： C01B37/04 , B01J29/04 , B01J29/08 , B01J29/60 , B01J29/80 , B01J37/06 , C01B37/08 , C01B39/02 , C01B39/04 , C01B39/06 , C01B39/08 , C01B39/20 , C01B39/32 , B01J29/02
摘要： A method for demetallating crystalline molecular sieve materials by removing a transition metal in the sieve framework with a complexing agent.
摘要翻译： 一种通过用络合剂除去筛框中的过渡金属来脱金属结晶分子筛材料的方法。
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10.发明授权
公开(公告)号：US5178846A
公开(公告)日：1993-01-12
申请号：US725034
申请日：1991-07-03
申请人： Martin Buelow , Elke Jahn , Ulrich Schuelke , Karl Becker , Peter Kraak , Roland Thome , Arno Tissler
发明人： Martin Buelow , Elke Jahn , Ulrich Schuelke , Karl Becker , Peter Kraak , Roland Thome , Arno Tissler
IPC分类号： B01J20/18 , B01J29/00 , B01J29/83 , B01J29/84 , B01J29/85 , C01B25/36 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/06
CPC分类号： C01B37/08 , B01J29/84 , C01B37/04 , C01B37/065
摘要： An economical and environmentally safe method for synthesizing wide-pore aluminophosphate crystalline molecular sieves primarily involves inorganic synthesis requiring no structure-directing organic templates. In addition to aluminium and phosphate, further components selected from group IV of the periodic table of elements can be added to synthesize multi-component phosphate molecular sieves such as germano-silico-alumino-phosphate crystalline structures.
摘要翻译： 用于合成广泛磷酸铝晶体分子筛的经济且环保的方法主要涉及不需要结构导向有机模板的无机合成。 除了铝和磷酸盐之外，可以加入选自元素周期表第IV族的其它组分以合成多组分磷酸酯分子筛，例如锗 - 硅 - 铝磷酸盐晶体结构。
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