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48 条记录 (耗时 0.016 秒)

    Process for producing n-(bicyclo[2.2.1]hept-5-en-2-ylmethyl)-1,1,1-trifluoromethanesulfonamide
    21.
    发明申请
    Process for producing n-(bicyclo[2.2.1]hept-5-en-2-ylmethyl)-1,1,1-trifluoromethanesulfonamide 有权
    制备n-（双环[2.2.1]庚-5-烯-2-基甲基）-1,1,1-三氟甲磺酰胺的方法

    公开(公告)号：US20080071113A1

    公开(公告)日：2008-03-20

    申请号：US11878592

    申请日：2007-07-25

    申请人： Kei Matsunaga ,  Takeo Komata

    发明人： Kei Matsunaga ,  Takeo Komata

    IPC分类号： C07C311/01

    CPC分类号： C07C303/38 ,  C07C2602/42 ,  C07C311/09

    摘要： A process for producing N-(bicyclo[2.2.1]hept-5-en-2-ylmethyl)-1,1,1-trifluoromethanesulfonamide represented by formula [3]. The process includes the step of reacting trifluoromethanesulfonic anhydride with 1-bicyclo[2.2.1]hept-5-en-2-ylmethanamine in the presence of water and in the presence of a base selected from the group consisting of alkali metal hydroxides, alkaline-earth metal hydroxides and basic salts containing an alkali metal or an alkaline-earth metal.

    摘要翻译： 由式[3]表示的N-（双环[2.2.1]庚-5-烯-2-基甲基）-1,1,1-三氟甲磺酰胺的制备方法。 该方法包括使三氟甲磺酸酐与1-双环[2.2.1]庚-5-烯-2-基甲胺在水的存在下和在碱的存在下，选自碱金属氢氧化物，碱 - 碱金属氢氧化物和含有碱金属或碱土金属的碱性盐。

    Process for producing fluorine-containing alkylsulfonylaminoethyl α-substituted acrylate
    22.
    发明授权
    Process for producing fluorine-containing alkylsulfonylaminoethyl α-substituted acrylate 有权
    含氟烷基磺酰氨基乙基α-取代丙烯酸酯的制备方法

    公开(公告)号：US07115771B2

    公开(公告)日：2006-10-03

    申请号：US11068824

    申请日：2005-03-02

    申请人： Takeo Komata ,  Ryo Nadano ,  Makoto Matsuura

    发明人： Takeo Komata ,  Ryo Nadano ,  Makoto Matsuura

    IPC分类号： C07C69/52

    CPC分类号： C07C303/38 ,  C07C311/09

    摘要： The present invention provides a process for producing a fluorine-containing alkylsulfonylaminoethyl α-substituted acrylate represented by general formula [3]: which comprises reacting an aminoethyl α-substituted acrylate represented by general formula [1a] or a salt thereof: with a fluorine-containing alkylsulfonyl halide represented by general formula [2a] or a fluorine-containing alkylsulfonic anhydride represented by general formula [2b]:

    摘要翻译： 本发明提供由通式[3]表示的含氟烷基磺酰基氨基乙基α-取代丙烯酸酯的制备方法：其包括使通式[1a]表示的α-取代的氨基乙基α-取代的丙烯酸酯或其盐与氟 - 由通式[2a]表示的含烷基磺酰卤或由通式[2b]表示的含氟烷基磺酸酐：

    Process for producing 4-substituted benzopyran derivatives
    23.
    发明授权
    Process for producing 4-substituted benzopyran derivatives 失效
    制备4-取代苯并吡喃衍生物的方法

    公开(公告)号：US06608217B2

    公开(公告)日：2003-08-19

    申请号：US10255099

    申请日：2002-09-26

    申请人： Takeo Komata ,  Masaki Fujiwara ,  Takanao Tarui ,  Yusuke Saito ,  Hiroshi Minesaki

    发明人： Takeo Komata ,  Masaki Fujiwara ,  Takanao Tarui ,  Yusuke Saito ,  Hiroshi Minesaki

    IPC分类号： C07D31104

    CPC分类号： C07D311/58 ,  C07C45/46 ,  C07C45/673 ,  C07C49/84 ,  C07C49/825

    摘要： The present invention relates to a first process for producing a 2,2-bis(fluoromethyl)-6-(perfluoroalkyl)-2H-1-benzopyran-4-carboxylic acid. The first process includes the steps of (a) reacting a 2,2-bis(fluoromethyl)-6-(perfluoroalkyl)-2H-1-benzopyran-4-one with a perfluoroalkanesulfonic acid anhydride in the presence of a base, thereby obtaining a perfluoroalkanesulfonic 2,2-bis(fluoromethyl)-6-(perfluoroalkyl)-2H- 1-benzopyran-4-yl ester; and (b) reacting the benzopyranyl ester with carbon monoxide in the presence of a palladium complex compound and a base, thereby obtaining the carboxylic acid. The present invention further relates to a second process for producing a 2-hydroxy-5-(perfluoroalkyl) acetophenone, which can be a raw material for producing the carboxylic acid. The second process includes the steps of (c) reacting a 4-(perfluoroalkyl)alkoxybenzene with acetic anhydride or an acyl halide in the presence of a Lewis acid, thereby obtaining a 2-alkoxy-5-(perfluoroalkyl)acetophenone; and (d) dealkylating the 2-alkoxy-5-(perfluoroalkyl) acetophenone by a dealkylating agent.

    摘要翻译： 本发明涉及生产2,2-双（氟甲基）-6-（全氟烷基）-2H-1-苯并吡喃-4-羧酸的第一种方法。 第一种方法包括以下步骤：（a）在碱的存在下使2,2-双（氟甲基）-6-（全氟烷基）-2H-1-苯并吡喃-4-酮与全氟烷基磺酸酐反应，从而得到 全氟烷基磺酸2,2-双（氟甲基）-6-（全氟烷基）-2H-苯并吡喃-4-基酯; 和（b）在钯络合物和碱的存在下使苯并吡喃基酯与一氧化碳反应，由此得到羧酸。 本发明还涉及可用作生产羧酸的原料的2-羟基-5-（全氟烷基）苯乙酮的制备方法。 第二种方法包括以下步骤：（c）在路易斯酸存在下使4-（全氟烷基）烷氧基苯与乙酸酐或酰卤反应，由此得到2-烷氧基-5-（全氟烷基）苯乙酮; 和（d）通过脱烷基化剂使2-烷氧基-5-（全氟烷基）苯乙酮脱烷基化。

    Process for producing 1,1,1,5,5,5-hexafluoroacetylacetone
    24.
    发明授权
    Process for producing 1,1,1,5,5,5-hexafluoroacetylacetone 有权
    生产1,1,1,5,5,5-六氟乙酰丙酮的方法

    公开(公告)号：US06548712B2

    公开(公告)日：2003-04-15

    申请号：US09808105

    申请日：2001-03-15

    申请人： Takeo Komata ,  Nariaki II

    发明人： Takeo Komata ,  Nariaki II

    IPC分类号： C07C4500

    CPC分类号： C07C49/167 ,  C07C45/61 ,  C07C45/65 ,  C07C45/66 ,  C07C45/673 ,  C07C45/85

    摘要： The invention relates to a process for producing 1,1,1,5,5,5-hexafluoroacetylacetone. This process includes (a) hydrolyzing a metal complex of 1,1,1,5,5,5-hexafluoroacetylacetone into a 1,1,1,5,5,5-hexafluoroacetylacetone hydrate; and (b) dehydrating the hydrate into the 1,1,1,5,5,5-hexafluoroacetylacetone with high purity from a material containing a metal complex of 1,1,1,5,5,5-hexafluoroacetylacetone.

    摘要翻译： 本发明涉及一种生产1,1,1,5,5,5-六氟乙酰丙酮的方法。 该方法包括（a）将1,1,1,5,5,5-六氟乙酰丙酮的金属络合物水解成1,1,1,5,5,5-六氟乙酰丙酮水合物; 和（b）从包含1,1,1,5,5,5-六氟乙酰丙酮的金属络合物的材料中将水合物从高纯度脱水到1,1,1,5,5,5-六氟乙酰丙酮中。

    Process for Producing Alpha-Substituted Norbornanyl Acrylates
    26.
    发明申请
    Process for Producing Alpha-Substituted Norbornanyl Acrylates 有权
    生产α-取代的降冰片烷基丙烯酸酯的方法

    公开(公告)号：US20110137073A1

    公开(公告)日：2011-06-09

    申请号：US13058115

    申请日：2009-08-27

    申请人： Makoto Matsuura ,  Ryo Nadano ,  Takeo Komata

    发明人： Makoto Matsuura ,  Ryo Nadano ,  Takeo Komata

    IPC分类号： C07C67/04

    CPC分类号： C07C67/04 ,  C07C2602/42 ,  C07C69/653

    摘要： Disclosed is a process for producing α-substituted norbornanyl acrylates efficiently on an industrial scale while suppressing the formation of by-products derived from intramolecular cyclization, excessive addition to acrylic acid etc. The α-substituted norbornanyl acrylates are useful as norbornene resist monomers. In the disclosed process, an α-substituted acrylic acid is directly reacted with a substituted norbornene in the presence of at least one acid catalyst selected from methanesulfonic acid and camphorsulfonic acid. It is possible in this reaction to suppress the formation of the by-products derived from intramolecular cyclication, excessive addition of the acid to the reaction product etc.

    摘要翻译： 公开了在工业规模上有效生产α-取代的降冰片烷基丙烯酸酯的方法，同时抑制由分子内环化衍生的副产物的形成，过度添加到丙烯酸等中。α-取代的降冰片烷基丙烯酸酯可用作降冰片烯抗蚀剂单体。 在所公开的方法中，在至少一种选自甲磺酸和樟脑磺酸的酸催化剂的存在下，α-取代的丙烯酸与取代的降冰片烯直接反应。 在该反应中可以抑制由分子内环化产生的副产物的形成，向反应产物等过量加入酸。

    Process for producing 3,3,3-trifluoropropionic acid
    27.
    发明授权
    Process for producing 3,3,3-trifluoropropionic acid 有权
    制备3,3,3-三氟丙酸的方法

    公开(公告)号：US07880033B2

    公开(公告)日：2011-02-01

    申请号：US12092232

    申请日：2006-10-24

    申请人： Takeo Komata ,  Kenji Hosoi ,  Shinya Akiba

    发明人： Takeo Komata ,  Kenji Hosoi ,  Shinya Akiba

    IPC分类号： C07C51/16 ,  C07C51/235

    CPC分类号： C07C43/317 ,  C07C45/513 ,  C07C45/86 ,  C07C47/14 ,  C07C51/00 ,  C07C51/27 ,  C07C53/21

    摘要： A benzyl vinyl ether represented by the following formula is hydrolyzed in the presence of a catalyst selected among Arrhenius acids and Lewis acids to obtain 3,3,3-trifluoropropionaldehyde. Subsequently, the 3,3,3-trifluoropropionaldehyde is oxidized with an oxidizing agent. Thus, 3,3,3-trifluoropropionic acid can be more advantageously produced than in conventional techniques from an inexpensive starting material.

    摘要翻译： 由下式表示的苄基乙烯基醚在选自Arrhenius酸和路易斯酸的催化剂存在下水解，得到3,3,3-三氟丙醛。 随后，用氧化剂氧化3,3,3-三氟丙醛。 因此，与常规技术相比，从廉价的起始材料可以更有利地生产3,3,3-三氟丙酸。

    Process for Producing Fluorine-Containing Alkylsulfonylaminoethyl Alpha-Substituted Acrylate
    28.
    发明申请
    Process for Producing Fluorine-Containing Alkylsulfonylaminoethyl Alpha-Substituted Acrylate 有权
    制备含氟烷基磺酰基氨基乙基α-取代丙烯酸酯的方法

    公开(公告)号：US20090069595A1

    公开(公告)日：2009-03-12

    申请号：US12187823

    申请日：2008-08-07

    申请人： Takeo KOMATA ,  Ryo Nadano ,  Makoto Matsuura

    发明人： Takeo KOMATA ,  Ryo Nadano ,  Makoto Matsuura

    IPC分类号： C07C221/00

    CPC分类号： C07C303/38 ,  C07C311/09

    摘要： There is provided a process for producing a fluorine-containing alkylsulfonylaminoethyl α-substituted acrylate of the formula [3] by reaction of an aminoethyl α-substituted acrylate of the formula [1a] with a fluorine-containing alkylsulfonic fluoride of the formula [2], or by reaction of an aminoethyl a-substituted acrylate salt of the formula [1b] with a fluorine-containing alkylsulfonic fluoride of the formula [2] in the presence of a base, wherein a fluorine-containing compound is used as a reaction solvent: where R1 is a hydrogen atom, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tertbutyl group, fluoromethyl group, difluoromethyl group, trifluoromethyl group or perfluoroethyl group; R2 is a fluorine-containing alkyl group having a carbon number of 1 to 6; Xn− is a counter anion (n is a positive integer); and Y is a fluorine atom, chlorine atom or bromine atom.

    摘要翻译： 提供了通式[1a]的α-氨基乙基α取代丙烯酸酯与式[2]的含氟烷基磺酸氟化物反应制备式[3]的含氟烷基磺酰氨基乙基α-取代丙烯酸酯的方法， 或通过式[1b]的氨基乙基α-取代的丙烯酸盐与式[2]的含氟烷基磺酸氟化物在碱的存在下反应，其中使用含氟化合物作为反应溶剂 ：其中R1是氢原子，甲基，乙基，正丙基，异丙基，正丁基，仲丁基，叔丁基，氟甲基，二氟甲基，三氟甲基或全氟乙基; R2是碳数为1〜6的含氟烷基; Xn-为抗衡阴离子（n为正整数）; Y是氟原子，氯原子或溴原子。