公开(公告)号：US20140349093A1

公开(公告)日：2014-11-27

申请号：US14377061

申请日：2013-02-14

申请人： Thomas Hasskerl ,  Klaus Koralewski ,  Sabine Schwarz-Barac ,  Roger Recktenwald ,  Werner Hoess ,  Florian Band

发明人： Thomas Hasskerl ,  Klaus Koralewski ,  Sabine Schwarz-Barac ,  Roger Recktenwald ,  Werner Hoess ,  Florian Band

IPC分类号： B32B7/12 ,  C09J4/06 ,  B32B37/00 ,  B32B17/10

CPC分类号： B32B7/12 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B17/10899 ,  B32B37/00 ,  B32B2250/05 ,  B32B2250/40 ,  B32B2315/08 ,  C08F2220/1825 ,  C08F2220/325 ,  C09J4/06 ,  C09J133/08 ,  C09J133/10 ,  Y02E10/52 ,  Y10T428/2495 ,  Y10T428/266 ,  Y10T428/31645

摘要： The invention relates to a new adhesive composition and to sheets produced from it, for producing laminates, more particularly for bonding plastic with glass components, to a method for producing such laminates, and to the laminates produced accordingly.

摘要翻译： 本发明涉及一种新的粘合剂组合物和由其制备的片材，用于生产层压材料，更具体地说，用于将具有玻璃组分的塑料粘合到制造这种层压材料的方法中，以及相应地生产的层压材料。

公开(公告)号：US07608306B2

公开(公告)日：2009-10-27

申请号：US10548878

申请日：2004-03-02

申请人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： C08F2/46 ,  C09D4/00

CPC分类号： C09D5/24 ,  Y10T428/31511

摘要： A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and optionally a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated [sic] in a manner known per se and the lacquer cured.

摘要翻译： 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法，该漆系统由粘合剂或粘合剂混合物，任选的溶剂或溶剂混合物，任选的其它通常在漆系统中的添加剂 并且任选地是增稠剂，并且这里可以使用0-20％含量的聚合物增稠剂和0至40％含量的低聚增稠剂，在每种情况下基于干膜（组分a，c，d，e）， 5至500重量份，基于a），中值一次粒径为1至80nm，百分比聚集度为0.01至99％的导电金属氧化物粉末为5至500个 基于a），以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。

公开(公告)号：US20070098884A1

公开(公告)日：2007-05-03

申请号：US10578568

申请日：2004-08-06

申请人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： B05D3/02 ,  B05D1/12

CPC分类号： C08J7/047 ,  C09D5/24

摘要： A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated in a manner known per se and the lacquer cured.

摘要翻译： 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法，该漆系统由粘合剂或粘合剂混合物，任选的溶剂或溶剂混合物，任选的其它通常在漆系统中的添加剂 和增稠剂，并且这里可以使用0-20％含量的聚合物增稠剂和0至40％含量的低聚增稠剂，在每种情况下基于干膜（组分a，c，d，e），来自 5至500重量份，基于a），中值一次粒径为1至80nm，百分比聚集度为0.01至99％的导电金属氧化物粉末为5至500份， 重量，基于a），以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。

公开(公告)号：US20060157675A1

公开(公告)日：2006-07-20

申请号：US10548878

申请日：2004-03-02

申请人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： H01B1/12

CPC分类号： C09D5/24 ,  Y10T428/31511

摘要： A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and optionally a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated [sic] in a manner known per se and the lacquer cured.

摘要翻译： 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法，该漆系统由粘合剂或粘合剂混合物，任选的溶剂或溶剂混合物，任选的其它通常在漆系统中的添加剂 并且任选地是增稠剂，并且这里可以使用0-20％含量的聚合物增稠剂和0至40％含量的低聚增稠剂，在每种情况下基于干膜（组分a，c，d，e）， 5至500重量份，基于a），中值一次粒径为1至80nm，百分比聚集度为0.01至99％的导电金属氧化物粉末为5至500个 基于a），以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。

公开(公告)号：US20060058458A1

公开(公告)日：2006-03-16

申请号：US10539126

申请日：2003-10-18

申请人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum ,  Reiner Lingelbach

发明人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum ,  Reiner Lingelbach

IPC分类号： C08G63/60

CPC分类号： C09D4/06 ,  C08F265/06

摘要： The invention relates to coating agents for producing rigid coatings resistant to scratching and soiling which contain: A) 1-30 mass % polymer produced by free radical polymerisation of a mixture containing A1) 1-10 weight parts of at least one sulphur compound containing at least 3 thiol groups and A2) 90-99 weight parts of alkylmethacrylate; B) 0.2-10% mass of at least one fluoralkyl(meth)acrylate having from 3 to 30 carbon atoms in an alcohol radical which comprises from 6 to 61 fluorine atoms; C) 20-80 mass % multifunctional (methyl)acrylate; D) 0.01-10 mass % of at least one initiator; E) 5-75 mass % of at least one solvent and F) 0-40 mass % ordinary additives. The rigid moulded bodies resistant to scratching and soiling and comprising a plastic substrate and scratching resistant coating are also disclosed.

摘要翻译： 本发明涉及用于制造耐划伤和污染的刚性涂层的涂布剂，其包含：A）通过含有A1）的混合物的自由基聚合制备的1-30质量％的聚合物：1-10重量份的至少一种含有 至少3个硫醇基团和A2）90-99重量份的甲基丙烯酸烷基酯; B）在包含6至61个氟原子的醇基中具有3至30个碳原子的至少一种（甲基）丙烯酸氟烷基酯的0.2-10％质量; C）20-80质量％多官能（甲基）丙烯酸酯; D）0.01-10质量％的至少一种引发剂; E）5-75质量％的至少一种溶剂和F）0-40质量％的普通添加剂。 还公开了耐划伤和腐蚀并且包括塑料基材和耐刮擦涂层的刚性模制体。

公开(公告)号：US20050118434A1

公开(公告)日：2005-06-02

申请号：US10508844

申请日：2003-05-20

申请人： Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： B05D5/00 ,  B05D7/02 ,  C08J7/04 ,  B32B9/04 ,  B32B5/16

CPC分类号： C08J7/047 ,  C08J7/04 ,  C08J2483/00 ,  Y10T428/256 ,  Y10T428/265 ,  Y10T428/31663 ,  Y10T428/31667

摘要： The invention relates to self-cleaning synthetic bodies, obtained as follows: a) a siloxane coating (a) is applied to a synthetic substrate and cured, b) the polar fraction of the surface energy of the cured siloxane coating on the substrate is increased to a value of at least 10 mN/m and c) a coating (b) containing photocatalytically active TiO2 particles is applied to the synthetic substrate and cured.

摘要翻译： 本发明涉及如下获得的自清洁合成物：a）将硅氧烷涂层（a）施加到合成基底上并固化，b）基底上固化的硅氧烷涂层的表面能的极性分数增加 达到至少10mN / m的值，并且c）将含有光催化活性的TiO 2颗粒的涂层（b）施加到合成基材上并固化。

公开(公告)号：US20050016213A1

公开(公告)日：2005-01-27

申请号：US10500362

申请日：2003-02-21

申请人： Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum ,  Wolfgang Wiebel

发明人： Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum ,  Wolfgang Wiebel

IPC分类号： C03C27/12 ,  C08F230/08 ,  C08F290/14 ,  C08G59/14 ,  C08G77/20 ,  C03B8/02

CPC分类号： B32B17/10743 ,  B32B17/10036 ,  B32B17/10697 ,  B32B17/10908 ,  C08F230/08 ,  Y10T428/31504 ,  Y10T428/31623 ,  Y10T428/31663

摘要： The invention relates to polymerisable compositions obtained as follows: a) reaction of A) between 0.5 and 5 parts by weight of at least one silicon compound of formula (I): SimR1nR2oOrXs with B) between 0.01 and 2.0 parts by weight of water C) between 0 and 4.0 parts by weight of at least one acid; and b) subsequent addition of D) between 0.5 and 5 parts by weight of at least one (meth)acrylate of formula (II), E) between 98.99 and 55 parts by weight of at least one polymerisable, ethylenically unsaturated monomer, different from D) and F) between 0 and 30 parts by weight of at least one polymer and/or copolymer, which is obtained by the polymerisation or copolymerisation of at least one ethylenically unsaturated monomer E). The groups R1, R2, R3, R4 and X, in addition to the indices m, n, o, r and s are defined as cited in the description. The invention also relates to polymers and laminate glass obtained from the composition, to a method for producing laminate glass and to the use thereof.

摘要翻译： 本发明涉及如下获得的可聚合组合物：a）A）0.5至5重量份的至少一种式（I）的硅化合物：SimR1nR20OX与B）0.01至2.0重量份的水反应C） 0至4.0重量份的至少一种酸; 和b）随后加入0.5至5重量份的至少一种式（II）的（甲基）丙烯酸酯，E）98.99和55重量份的至少一种可聚合的烯键式不饱和单体，不同于 D）和F）0至30重量份的至少一种通过至少一种烯键式不饱和单体E）的聚合或共聚获得的聚合物和/或共聚物。 除了指数m，n，o，r和s之外，基团R1，R2，R3，R4和X定义如说明书中引用的那样。 本发明还涉及从组合物获得的聚合物和层压玻璃，以及层压玻璃的制造方法及其用途。