公开(公告)号：US07608306B2

公开(公告)日：2009-10-27

申请号：US10548878

申请日：2004-03-02

申请人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： C08F2/46 ,  C09D4/00

CPC分类号： C09D5/24 ,  Y10T428/31511

摘要： A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and optionally a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated [sic] in a manner known per se and the lacquer cured.

摘要翻译： 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法，该漆系统由粘合剂或粘合剂混合物，任选的溶剂或溶剂混合物，任选的其它通常在漆系统中的添加剂 并且任选地是增稠剂，并且这里可以使用0-20％含量的聚合物增稠剂和0至40％含量的低聚增稠剂，在每种情况下基于干膜（组分a，c，d，e）， 5至500重量份，基于a），中值一次粒径为1至80nm，百分比聚集度为0.01至99％的导电金属氧化物粉末为5至500个 基于a），以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。

公开(公告)号：US20060157675A1

公开(公告)日：2006-07-20

申请号：US10548878

申请日：2004-03-02

申请人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Stipan Katusic ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： H01B1/12

CPC分类号： C09D5/24 ,  Y10T428/31511

摘要： A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and optionally a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated [sic] in a manner known per se and the lacquer cured.

摘要翻译： 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法，该漆系统由粘合剂或粘合剂混合物，任选的溶剂或溶剂混合物，任选的其它通常在漆系统中的添加剂 并且任选地是增稠剂，并且这里可以使用0-20％含量的聚合物增稠剂和0至40％含量的低聚增稠剂，在每种情况下基于干膜（组分a，c，d，e）， 5至500重量份，基于a），中值一次粒径为1至80nm，百分比聚集度为0.01至99％的导电金属氧化物粉末为5至500个 基于a），以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。

公开(公告)号：US20060068197A1

公开(公告)日：2006-03-30

申请号：US10538887

申请日：2003-10-18

申请人： Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum ,  Patrick Becker

发明人： Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum ,  Patrick Becker

IPC分类号： B32B27/36 ,  B32B27/30 ,  B32B27/32 ,  B32B9/04

CPC分类号： C08J7/045 ,  C09K3/18 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31786 ,  Y10T428/31935 ,  Y10T428/31938

摘要： The invention relates to water-dispersing plastic bodies made of a plastic substrate, at least one water-dispersing, inorganic coating (a) and an adhesive promoting intermediate layer (b) which is arranged between the plastic substrate and the inorganic coating. The invention is characterised in that the intermediate layer comprises two polymers (A) and (B), whereby water on one layer of the polymer (A) forms and edge angle which is smaller than or equal to 73° at 20° C. and water on one layer of the polymer (B) forms an edge angle greater than or equal to 75° at 20° C.

摘要翻译： 本发明涉及由塑料基材，至少一种水分散无机涂层（a）和粘合剂促进中间层（b）制成的水分散塑料体，其布置在塑料基材和无机涂层之间。 本发明的特征在于，中间层包含两种聚合物（A）和（B），其中一层聚合物（A）上的水形成和在20℃下小于或等于73°的边角， 在一层聚合物（B）上的水在20℃下形成大于或等于75°的边缘角。

公开(公告)号：US20070172673A1

公开(公告)日：2007-07-26

申请号：US10555772

申请日：2004-03-25

申请人： Patrick Becker ,  Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum ,  Reiner Lingelbach

发明人： Patrick Becker ,  Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum ,  Reiner Lingelbach

IPC分类号： B32B9/04 ,  C09D5/00

CPC分类号： C08G77/24 ,  C08J7/047 ,  C08J2483/00 ,  Y10T428/31663

摘要： The invention relates to coating agents having an antigraffiti effect. Said coating agents can be obtained according to a method consisting in condensing the organic silicon compounds of general formula (I): R1nSIX4-n, wherein R1 represents a group comprising 1-20 carbon atoms, X represents an alkoxy radical having 1-20 carbon atoms or halogen and n represents an even number between 0-3. The different radicals X or R1 can be identical or different and/or the precondensates can be obtained from said components. At least 50 wt. % of the silicon compounds, in relation to the total weight of the used silicon compounds, is represented by the formula R1SiX3, wherein R1 and X have the above-cited meaning, in order to form polysiloxanes until the ratio of signals R1SiO(OH) and signals R1SiO1,5 measured by NMR-spectroscopy ranges from 0.6-4, and by adding compounds of formula (II) (R″)uSi(R′)t(OR)(4-t-u) to said polysiloxane mixture, wherein R represents a group comprising 1-20 carbon atoms having at least 3 fluoro atoms. U is 1 or 2 and t is 0 or 1, R and R′ are identical or different and represent a group comprising 1-20 carbon atoms. The also relates to plastic bodies which have coating which can be obtained by means of the coating agents.

摘要翻译： 本发明涉及具有防刮涂作用的包衣剂。 所述包衣剂可以根据通式（I）的有机硅化合物缩合的方法获得：R 1，N 2，S 4，N 4， 其中R 1表示包含1-20个碳原子的基团，X表示具有1-20个碳原子的烷氧基或卤素，n表示0-3之间的偶数。 不同的基团X或R 1可以相同或不同，和/或可以从所述组分获得预缩合物。 至少50wt。 相对于所使用的硅化合物的总重量，硅化合物的百分比由式R 1 SiX 3 N表示，其中R 1， SUP>和X具有上述含义，为了形成聚硅氧烷，直到信号R 1 SiO（OH）和信号R 1 SiO 2的比例 ，通过NMR光谱测量的5 范围为0.6-4，并且通过加入式（II）（R“）的化合物（R”）Si（R'） （OR）（4-tu））与所述聚硅氧烷混合物，其中R表示含有至少3个氟原子的1-20个碳原子的基团。 U为1或2，t为0或1，R和R'相同或不同，表示1-20个碳原子的基团。 也涉及具有可以通过涂布剂获得的涂层的塑料体。

公开(公告)号：US20060063011A1

公开(公告)日：2006-03-23

申请号：US10539057

申请日：2003-10-18

申请人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： B32B27/06 ,  B05D1/38 ,  B32B9/04

CPC分类号： C08J7/045 ,  C09K3/18 ,  Y10T428/31663

摘要： The invention relates to water-dispersing plastic bodies made of a plastic substrate, at least one water-dispersing, inorganic coating (a) and an adhesive promoting intermediate layer (b) arranged between the plastic substrate and the inorganic coating. Said coating can be obtained in such a manner that the intermediate layer applied is (b) made of a mixture with a compound which has an evaporating number smaller than or equal to 20. The sum of the layer thicknesses of the inorganic coating (a) and the intermediate layer (b) is 07 μm at the most.

摘要翻译： 本发明涉及由塑料基材，至少一种水分散无机涂层（a）和布置在塑料基材和无机涂层之间的粘合促进中间层（b）制成的分散塑料体。 所述涂层可以以如下方式获得：所施加的中间层是（b）由具有小于或等于20的蒸发数的化合物的混合物制成。无机涂层（a）的层厚度之和 中间层（b）最多为07μm。

公开(公告)号：US20070003756A1

公开(公告)日：2007-01-04

申请号：US10573075

申请日：2004-07-02

申请人： Patrick Becker ,  Norbert Brand ,  Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Patrick Becker ,  Norbert Brand ,  Thomas Hasskerl ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： B32B27/06 ,  B05D3/12 ,  B05D1/18 ,  B05D3/02

CPC分类号： B29D11/00865 ,  B29C37/0032 ,  B29C39/025 ,  B29C41/08 ,  B29K2105/0002 ,  B29K2995/0005 ,  B29K2995/0026 ,  B29K2995/0087 ,  B29L2007/002 ,  B29L2009/00 ,  B29L2011/00 ,  B29L2011/0016 ,  B29L2031/3061 ,  Y10T428/265

摘要： The invention relates to a method for production of a plastic body, made from a plastic obtained by means of a radical polymerisation with single- or multi-sided, inorganic coating containing silicon. The coating of a substrate is firstly achieved with a paint composition, containing inorganic particles in a solvent which can optionally contain additional flow improvers. One or more of such coated substrates can be used for the construction of a polymerisation chamber, in which the coated sides lie within the chamber. After radical polymerisation of a monomer mixture in the presence of a polymerisation initiator, the internal inorganic coating of the substrate transfers into or onto the surfaces of the radically polymerised plastic or of the plastic body. The invention further relates to the corresponding plastic body and the uses thereof.

摘要翻译： 本发明涉及一种用于生产塑料体的方法，该塑料体由通过具有含硅单体或多面无机涂层的自由基聚合获得的塑料制成。 首先通过涂料组合物实现基材的涂层，所述涂料组合物在溶剂中含有无机颗粒，其可以任选地含有另外的流动改进剂。 一个或多个这样的涂覆的基底可用于构建聚合室，其中涂覆的侧面位于室内。 在聚合引发剂存在下，单体混合物自由基聚合之后，基材的内部无机涂层转移到自由基聚合的塑料或塑料体的表面中或表面上。 本发明还涉及相应的塑料体及其用途。

公开(公告)号：US20070098884A1

公开(公告)日：2007-05-03

申请号：US10578568

申请日：2004-08-06

申请人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： B05D3/02 ,  B05D1/12

CPC分类号： C08J7/047 ,  C09D5/24

摘要： A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated in a manner known per se and the lacquer cured.

摘要翻译： 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法，该漆系统由粘合剂或粘合剂混合物，任选的溶剂或溶剂混合物，任选的其它通常在漆系统中的添加剂 和增稠剂，并且这里可以使用0-20％含量的聚合物增稠剂和0至40％含量的低聚增稠剂，在每种情况下基于干膜（组分a，c，d，e），来自 5至500重量份，基于a），中值一次粒径为1至80nm，百分比聚集度为0.01至99％的导电金属氧化物粉末为5至500份， 重量，基于a），以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。

公开(公告)号：US20060058458A1

公开(公告)日：2006-03-16

申请号：US10539126

申请日：2003-10-18

申请人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum ,  Reiner Lingelbach

发明人： Thomas Hasskerl ,  Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum ,  Reiner Lingelbach

IPC分类号： C08G63/60

CPC分类号： C09D4/06 ,  C08F265/06

摘要： The invention relates to coating agents for producing rigid coatings resistant to scratching and soiling which contain: A) 1-30 mass % polymer produced by free radical polymerisation of a mixture containing A1) 1-10 weight parts of at least one sulphur compound containing at least 3 thiol groups and A2) 90-99 weight parts of alkylmethacrylate; B) 0.2-10% mass of at least one fluoralkyl(meth)acrylate having from 3 to 30 carbon atoms in an alcohol radical which comprises from 6 to 61 fluorine atoms; C) 20-80 mass % multifunctional (methyl)acrylate; D) 0.01-10 mass % of at least one initiator; E) 5-75 mass % of at least one solvent and F) 0-40 mass % ordinary additives. The rigid moulded bodies resistant to scratching and soiling and comprising a plastic substrate and scratching resistant coating are also disclosed.

摘要翻译： 本发明涉及用于制造耐划伤和污染的刚性涂层的涂布剂，其包含：A）通过含有A1）的混合物的自由基聚合制备的1-30质量％的聚合物：1-10重量份的至少一种含有 至少3个硫醇基团和A2）90-99重量份的甲基丙烯酸烷基酯; B）在包含6至61个氟原子的醇基中具有3至30个碳原子的至少一种（甲基）丙烯酸氟烷基酯的0.2-10％质量; C）20-80质量％多官能（甲基）丙烯酸酯; D）0.01-10质量％的至少一种引发剂; E）5-75质量％的至少一种溶剂和F）0-40质量％的普通添加剂。 还公开了耐划伤和腐蚀并且包括塑料基材和耐刮擦涂层的刚性模制体。

公开(公告)号：US20080032124A1

公开(公告)日：2008-02-07

申请号：US11572716

申请日：2005-07-09

申请人： Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： C08J5/00 ,  B29C37/00 ,  C08J7/06 ,  C09D1/00

CPC分类号： B29C37/0032 ,  C08J5/00 ,  C09D1/00 ,  C09D5/24 ,  Y10T428/265 ,  Y10T428/31667

摘要： The invention relates to a method for producing a synthetic body from a synthetic material obtained by radical polymerization, which is coated on one or several sides with an Si-containing or inorganic substance. According to the inventive method, a substrate is coated with a lacquer composition which contains inorganic particles dissolved in a solvent which may optionally also contain a flow-control agent. One or more substrates that are coated in this manner can be used to construct a polymerization chamber, the coated sides facing the interior of the chamber. After radical polymerization of a monomer mixture in the presence of a polymerization initiator and a separating agent mixture the inward inorganic coating is transferred from the substrate to or onto the surfaces of the radically polymerized synthetic material or the corresponding synthetic body. The invention also relates to the corresponding synthetic bodies and their uses and to the use of the separating agent mixture in the polymerization casting method.

摘要翻译： 本发明涉及一种通过自由基聚合得到的合成材料的制造方法，该合成材料用含Si或无机物质涂覆在一面或几面上。 根据本发明的方法，用含有溶解在可任选还含有流动控制剂的溶剂中的无机颗粒的漆组合物涂覆基材。 以这种方式涂覆的一个或多个基材可用于构建聚合室，涂覆的侧面朝向室的内部。 在聚合引发剂和分离剂混合物存在下，单体混合物自由基聚合后，向内的无机涂层从基材转移到基体聚合的合成材料或相应合成物的表面上或表面上。 本发明还涉及相应的合成物及其用途以及在聚合浇铸法中使用分离剂混合物。

公开(公告)号：US20080139690A1

公开(公告)日：2008-06-12

申请号：US11814082

申请日：2005-12-10

申请人： Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

发明人： Patrick Becker ,  Rolf Neeb ,  Ghirmay Seyoum

IPC分类号： C08K5/101 ,  C08F2/46

CPC分类号： C09D133/14

摘要： The present invention relates to coating compositions for producing formable scratchproof coatings with dirt repellency effect, comprising A) from 1% by weight to 30% by weight of a prepolymer obtainable by free-radically polymerizing a mixture comprising A1) from 1 to 10 parts by weight of at least one sulphur compound containing at least 3 thiol groups and A2) from 90 to 99 parts by weight of alkyl (meth)acrylates, B) from 0.2% by weight to 10% by weight of at least one fluoroalkyl (meth)acrylate having 6 to 60 carbon atoms in the alcohol residue and including 13 to 121 fluorine atoms, C) from 20% by weight to 80% by weight of polyfunctional (meth)acrylates, D) from 0.01% by weight to 10% by weight of at least one initiator E) from 2% by weight to 75% by weight of at least one diluent and F) from 0% by weight to 40% by weight of customary additives G) from 0.01% by weight to 10% by weight of 2,2,3,3-tetrafluoropropyl methacrylate. Additionally disclosed are scratchproof/formable and dirt-repellent mouldings comprising a polymeric substrate and a scratchproof coating.

摘要翻译： 本发明涉及用于生产具有防污效果的可成形防刮涂层的涂料组合物，其包含A）1重量％至30重量％的预聚物，所述预聚物可通过将包含A1）1至10份的混合物自由基聚合 至少一种含至少3个硫醇基的硫化合物的重量，和A2）90-99重量份的（甲基）丙烯酸烷基酯，B）0.2重量％-10重量％的至少一种（甲基） 丙烯酸酯在醇残基中含有6〜60个碳原子，含有13〜121个氟原子，C）20重量％〜80重量％的多官能（甲基）丙烯酸酯，D）0.01重量％〜10重量％ 的至少一种引发剂E）2重量％至75重量％的至少一种稀释剂和F）0重量％至40重量％的常规添加剂G），0.01重量％至10重量％ 的2,2,3,3-四氟丙基甲基丙烯酸酯。 另外公开了包括聚合物基材和防刮涂层的防刮/可成形和防污模制品。