公开(公告)号：US20140255679A1

公开(公告)日：2014-09-11

申请号：US14349912

申请日：2012-10-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Siegfried R. Goeb ,  Silke D. Mechernich ,  Steffen Traser ,  Claudia Torre ,  Jan D. Forster

IPC: C09J7/02

CPC classification number: C09J7/0217 ,  B32B7/12 ,  B32B15/046 ,  B32B17/06 ,  B32B2457/12 ,  C03C27/048 ,  C08F220/18 ,  C09J7/00 ,  C09J7/10 ,  C09J7/385 ,  C09J133/062 ,  C09J143/04 ,  C09J151/003 ,  C09J2201/36 ,  C09J2203/322 ,  C09J2205/114 ,  C09J2433/00 ,  C09J2451/00 ,  C09J2483/00 ,  Y10T428/249954 ,  Y10T428/249978 ,  Y10T428/287 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F220/06 ,  C08F222/1006

Abstract: A multilayer pressure sensitive adhesive (PSA) film having a first pressure sensitive adhesive layer for bonding glass substrates and at least a second opposing layer, the first pressure sensitive adhesive layer being a polymerization reaction product of a precursor comprising a monomer or a partially prepolymerized monomer, in particular a (meth)acrylate based monomer, having a curable ethylenically unsaturated group, whereas the precursor further comprises an oligomeric organofunctional silane having at least 2 Si atoms, in particular 2 to 10 Si atoms, wherein the monomer having a curable ethylenically unsaturated further has a coupling group with a Zerewitinow-active H-atom and wherein the oligomeric organofunctional silane has at least one coupling group which is reactive to the coupling group of the monomer having a curable ethylenically unsaturated group, or wherein the oligomeric organofunctional silane has at least one coupling group with a Zerewitinow-active H-atom and wherein the monomer having a curable ethylenically unstaurated further has a coupling group which is reactive to the coupling group of the oligomeric organofunctional silane; with the proviso that if the monomer having a curable ethylenically unsaturated group further has a coupling group with a Zerewitinow-active H-atom which is selected to be —OH, then the coupling group of the oligomeric organofunctional silane which is reactive to the coupling group of the monomer having a curable ethylene group cannot be selected to be an amino group.

Abstract translation: 一种多层压敏粘合剂（PSA）膜，其具有用于粘合玻璃基板的第一压敏粘合剂层和至少第二相对层，所述第一压敏粘合剂层是包含单体或部分预聚单体的前体的聚合反应产物 ，特别是具有可固化的烯属不饱和基团的（甲基）丙烯酸酯基单体，而前体还包含具有至少2个Si原子，特别是2至10个Si原子的低聚有机官能硅烷，其中具有可固化烯属不饱和基团的单体 还具有具有齐维诺诺活性H原子的偶联基团，并且其中所述低聚有机官能硅烷具有至少一个与具有可固化烯键式不饱和基团的单体的偶联基团反应的偶联基团，或其中所述低聚有机官能硅烷具有 至少一个具有Zerewitinow活性H原子的偶联基团，其中 具有非饱和可固化烯键式的单体还具有与低聚有机官能硅烷的偶联基团反应的偶联基团; 条件是如果具有可固化烯键式不饱和基团的单体还具有与选择为-OH的齐维诺诺活性H原子的偶联基团，则与偶联基团反应的低聚有机官能硅烷的偶联基团 的具有可固化的亚乙基的单体不能选择为氨基。