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29 条记录 (耗时 0.032 秒)

    Trifluorovinyloxy monomers and polymers
    22.
    发明申请
    Trifluorovinyloxy monomers and polymers 失效
    三氟乙烯基氧基单体和聚合物

    公开(公告)号：US20070238856A1

    公开(公告)日：2007-10-11

    申请号：US11397109

    申请日：2006-04-05

    申请人： David Moore ,  Hongyi Zhou ,  Christoph Erben ,  Marianne Harmon ,  Joyce Hung ,  Hongwei Liu ,  Daniel Steiger ,  Daniel Brunelle

    发明人： David Moore ,  Hongyi Zhou ,  Christoph Erben ,  Marianne Harmon ,  Joyce Hung ,  Hongwei Liu ,  Daniel Steiger ,  Daniel Brunelle

    IPC分类号： C08G75/14

    CPC分类号： C08G75/23

    摘要： Reactive monomers containing the trifluorovinyloxy group may be copolymerized to form polymers useful as membranes, especially polymer electrolyte membranes for fuel cells. The monomers have the formula ((CF2CFO(R1)p)nArX2 wherein Ar is a trivalent, tetravalent or pentavalent, substituted or unsubstituted, aromatic or heteroaromatic, monocyclic or polycyclic group having from 5 to 50 carbon atoms; X is OH, SH, NR2aR2b, F or Br; p is 0 or 1; n is 1, 2 or 3; R1 is substituted or unsubstituted phenyl and R2a and R2b are independently H, C1-C8 alkyl or C1-C8 perfluoroalkyl.

    摘要翻译： 含有三氟乙烯基氧基的反应性单体可以共聚以形成可用作膜的聚合物，特别是用于燃料电池的聚合物电解质膜。 这些单体具有式（（CF 2）CFO（R 1））N 2 Ar 2 其中Ar是具有5至50个碳原子的三价，四价或五价，取代或未取代的芳族或杂芳族单环或多环基团; X是OH，SH，NR 2a R F或Br; p为0或1; n为1,2或3; R 1为取代或未取代的苯基且R 2a为H 2 O >和R 2b独立地为H，C 1 -C 8烷基或C 1 -C 3 - 8 全氟烷基。

    Polyester oligomers, methods of making, and thermosetting compositions formed therefrom
    23.
    发明申请
    Polyester oligomers, methods of making, and thermosetting compositions formed therefrom 审中-公开
    聚酯低聚物，制备方法和由其形成的热固性组合物

    公开(公告)号：US20070155946A1

    公开(公告)日：2007-07-05

    申请号：US11326208

    申请日：2006-01-04

    申请人： Corrado Berti ,  Enrico Binassi ,  Daniel Brunelle ,  Martino Colonna ,  Maurizio Fiorini ,  Tommaso Zuccheri

    发明人： Corrado Berti ,  Enrico Binassi ,  Daniel Brunelle ,  Martino Colonna ,  Maurizio Fiorini ,  Tommaso Zuccheri

    IPC分类号： C08G63/02

    CPC分类号： C08G63/6856 ,  C08G63/64 ,  C08G63/672 ,  C08G63/6956 ,  C08G63/85 ,  C08G63/916 ,  C08G2261/126 ,  C08L101/08

    摘要： The above deficiencies in the art are alleviated by, in an embodiment, a method of preparing a carboxylic acid end-capped oligomer comprising melt reacting a dicarboxylic acid, a dihydroxy compound, a hydroxy end-capped soft block compound, a diaryl carbonate, and a catalyst, wherein the molar ratio of dihydroxy end-capped soft block compound to dihydroxy compound is 1:4 to 1:40, the molar ratio of dicarboxylic acid to the combined molar amounts of dihydroxy compound and hydroxy end-capped soft block compound is 1.01:1 to 2:1, and the molar ratio of diaryl carbonate to the combined molar amounts of dihydroxy compound and hydroxy end-capped soft block compound is 1.5:1 to 3:1. A carboxylic acid end-capped oligomer prepared by the above method is also disclosed. A thermosetting composition comprising the carboxylic acid end-capped oligomer, and an article comprising the thermosetting composition, are also disclosed.

    摘要翻译： 在一个实施方案中，本领域的上述缺点通过制备羧酸封端的低聚物的方法得到缓解，所述低聚物包括使二羧酸，二羟基化合物，羟基封端的嵌段软嵌段化合物，碳酸二芳基酯和 一种催化剂，其中二羟基封端的软嵌段化合物与二羟基化合物的摩尔比为1:4至1:40，二羧酸与二羟基封端的软嵌段化合物的摩尔数的摩尔比为 1.01:1-2:1，二芳基碳酸酯与二羟基封端软嵌段化合物的摩尔量的摩尔比为1.5:1〜3:1。 还公开了通过上述方法制备的羧酸封端的低聚物。 还公开了包含羧酸封端的低聚物的热固性组合物和包含该热固性组合物的制品。

    Mixed-sulfonation block copolymers
    24.
    发明申请
    Mixed-sulfonation block copolymers 失效
    混合磺化嵌段共聚物

    公开(公告)号：US20070142613A1

    公开(公告)日：2007-06-21

    申请号：US11314337

    申请日：2005-12-20

    申请人： Joyce Hung ,  Hongyi Zhou ,  David Moore ,  Marianne Harmon ,  Daniel Brunelle ,  Hongwei Liu

    发明人： Joyce Hung ,  Hongyi Zhou ,  David Moore ,  Marianne Harmon ,  Daniel Brunelle ,  Hongwei Liu

    IPC分类号： C08G16/00 ,  C08G75/00

    CPC分类号： C08G65/4012 ,  C08G65/48 ,  C08G75/23

    摘要： Sulfonated block copolymers that may be used as membranes for fuel cells include sulfonated polyaryletherketone blocks and lightly sulfonated polyethersulfone blocks. The sulfonated polyaryletherketone blocks include structural units of formula and the lightly sulfonated polyethersulfone blocks include structural units of formula wherein R1, R2, R3, R4, R5 and R6 are independently C1-C10 alkyl, C3-C12 cycloalkyl, C6-C14 aryl, allyl, alkenyl, alkoxy, halo, or cyano; Z, Z1 and Z2 are independently a direct bond or O, S, (CH2)r, (CF2)r, C(CH3)2, C(CF3)2, or a combination thereof; M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof; a and e are independently 0 or an integer from 1 to 3; b, c, d, and f are independently 0 or an integer from 1 to 4; m, n and p are independently 0 or 1; and r is an integer from 1 to 5.

    摘要翻译： 可用作燃料电池膜的磺化嵌段共聚物包括磺化聚芳醚酮嵌段和轻质磺化聚醚砜嵌段。 磺化聚芳醚酮嵌段包括式的结构单元，轻度磺化的聚醚砜嵌段包括下式的结构单元：其中R 1，R 2，R 3， R 4，R 5和R 6独立地是C 1 -C 10 C 1 -C 6烷基，C 3 -C 12环烷基，C 6 -C 14芳基，烯丙基，烯基，烷氧基 ，卤素或氰基; Z，Z 1和Z 2独立地是直接键或O，S，（CH 2） ，（CF 3）2，C（CH 3）2，C（CH 3）2，C（CH 3） / SUB> 2 ，或其组合; M是H，金属阳离子，非金属无机阳离子，有机阳离子或其混合物; a和e独立地为0或1〜3的整数; b，c，d和f独立地为0或1〜4的整数; m，n和p独立地为0或1; r为1〜5的整数。

    Copolyetherimides
    25.
    发明申请
    Copolyetherimides 有权
    共聚酰亚胺

    公开(公告)号：US20070043203A1

    公开(公告)日：2007-02-22

    申请号：US11210164

    申请日：2005-08-22

    申请人： Qing Ye ,  David Hall ,  William Richards ,  Daniel Brunelle ,  Havva Acar

    发明人： Qing Ye ,  David Hall ,  William Richards ,  Daniel Brunelle ,  Havva Acar

    IPC分类号： C08G69/08

    CPC分类号： C08G73/1046 ,  C08G73/124

    摘要： Copolyetherimides compositions having high glass transition temperatures and outstanding ductility are presented. The copolyetherimides having Mw of at least 40,000 comprising isomeric bis(phthalimide) structural units within a relatively narrow range of isomer proportions exhibited Tgs of at least 240° C. and outstanding Notched Izod values. The copolyetherimides comprise oxydianiline residues and structural units of the formulas (I) and (II) (III). The copolyetherimides are characterized by a mole percentage of structural units derived from 4,4′-biphenol in a range from about 55% to about 85% of all bisphenol-derived structural units present in the copolyetherimide composition; a mole percentage of structural units derived from bisphenol A in a range from about 45% to about 15% of all bisphenol-derived structural units present in the copolyetherimide composition; and a total mole percentage of structural units derived from bisphenol A or 4,4′-biphenol of at least 95% of all bisphenol-derived structural units present in the copolyetherimide composition.

    摘要翻译： 提出了具有高玻璃化转变温度和优异延展性的共聚酰亚胺组合物。 具有至少40,000的含有异构双（邻苯二甲酰亚胺）结构单元的异构体双组分（邻苯二甲酰亚胺）结构单元的共聚醚酰亚胺具有至少240℃的Tg和优异的缺口伊佐德值。 共聚醚酰亚胺包括氧化二苯胺残基和式（I）和（II）（III）的结构单元。 共聚醚酰亚胺的特征在于衍生自4,4'-联苯酚的结构单元的百分比在共聚醚酰亚胺组合物中存在的所有双酚衍生的结构单元的约55％至约85％的范围内; 来自双酚A的结构单元的摩尔百分比在存在于共聚醚酰亚胺组合物中的所有双酚衍生的结构单元的约45％至约15％的范围内; 并且衍生自双酚A或4,4'-联苯酚的结构单元的总摩尔百分比为存在于共聚醚酰亚胺组合物中的所有双酚衍生的结构单元的至少95％。

    Carboxy-terminated oligomeric polyester compositions and method for making
    26.
    发明申请
    Carboxy-terminated oligomeric polyester compositions and method for making 审中-公开
    羧基封端的低聚聚酯组合物及其制备方法

    公开(公告)号：US20060116487A1

    公开(公告)日：2006-06-01

    申请号：US10999025

    申请日：2004-11-29

    申请人： Daniel Brunelle ,  Martino Colonna ,  Corrado Berti ,  Maurizio Fiorini ,  Enrico Binassi

    发明人： Daniel Brunelle ,  Martino Colonna ,  Corrado Berti ,  Maurizio Fiorini ,  Enrico Binassi

    IPC分类号： C08G63/00 ,  C08F20/00 ,  C08G63/87

    CPC分类号： C08G63/85 ,  C08G63/191 ,  C08G63/64

    摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of atleast some phenoxy end groups.

    摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。

    Polyethersulfone compositions
    28.
    发明申请
    Polyethersulfone compositions 失效
    聚醚砜组合物

    公开(公告)号：US20060030683A1

    公开(公告)日：2006-02-09

    申请号：US11193552

    申请日：2005-07-29

    申请人： David Moore ,  Hongyi Zhou ,  Daniel Steiger ,  Joyce Hung ,  Daniel Brunelle ,  Hongwei Liu ,  Marianne Harmon

    发明人： David Moore ,  Hongyi Zhou ,  Daniel Steiger ,  Joyce Hung ,  Daniel Brunelle ,  Hongwei Liu ,  Marianne Harmon

    IPC分类号： C08L81/06 ,  C08L81/00

    CPC分类号： G11B7/22 ,  G11B7/1356 ,  G11B7/1362 ,  G11B2007/0006

    摘要： Novel polyethersulfone compositions have been discovered which incorporate structural subunits derived from sulfonated bis(halophenyl)sulfones, dihydroxy terphenyls, and/or bis(hydroxyphenyl)pyridines. The sulfonated polyethersulfones show promise as materials for use in polymer electrolyte membranes (PEMs) in fuel cells owing to their high proton conductivities (0.02-0.07 S/cm at 20° C. and 100 percent humidity). In addition, a novel unsulfonated thermoplastic polyethersulfone comprising structural subunits derived from a non-sulfonated bis(halophenyl)sulfone bis4-fluorophenyl)sulfone and 4,4′-dihydroxyphenyl-2,6-pyridine (CAS No. 171820-16-9) is disclosed.

    摘要翻译： 已经发现新的聚醚砜组合物掺入衍生自磺化双（卤代苯基）砜，二羟基三联苯和/或双（羟基苯基）吡啶的结构亚单位。 磺化聚醚砜由于其高质子电导率（在20℃和100％湿度下为0.02-0.07S / cm），在燃料电池中用作聚合物电解质膜（PEM）的材料显示出希望。 另外，包含衍生自非磺化双（卤代苯基）砜双-4-氟苯基）砜和4,4'-二羟基苯基-2,6-吡啶（CAS号171820-16-9）的结构亚单位的新型未磺化热塑性聚醚砜， 被披露。