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1.发明申请Polyester oligomers, methods of making, and thermosetting compositions formed therefrom 审中-公开聚酯低聚物，制备方法和由其形成的热固性组合物公开(公告)号：US20070155946A1
公开(公告)日：2007-07-05
申请号：US11326208
申请日：2006-01-04
申请人： Corrado Berti , Enrico Binassi , Daniel Brunelle , Martino Colonna , Maurizio Fiorini , Tommaso Zuccheri
发明人： Corrado Berti , Enrico Binassi , Daniel Brunelle , Martino Colonna , Maurizio Fiorini , Tommaso Zuccheri
IPC分类号： C08G63/02
CPC分类号： C08G63/6856 , C08G63/64 , C08G63/672 , C08G63/6956 , C08G63/85 , C08G63/916 , C08G2261/126 , C08L101/08
摘要： The above deficiencies in the art are alleviated by, in an embodiment, a method of preparing a carboxylic acid end-capped oligomer comprising melt reacting a dicarboxylic acid, a dihydroxy compound, a hydroxy end-capped soft block compound, a diaryl carbonate, and a catalyst, wherein the molar ratio of dihydroxy end-capped soft block compound to dihydroxy compound is 1:4 to 1:40, the molar ratio of dicarboxylic acid to the combined molar amounts of dihydroxy compound and hydroxy end-capped soft block compound is 1.01:1 to 2:1, and the molar ratio of diaryl carbonate to the combined molar amounts of dihydroxy compound and hydroxy end-capped soft block compound is 1.5:1 to 3:1. A carboxylic acid end-capped oligomer prepared by the above method is also disclosed. A thermosetting composition comprising the carboxylic acid end-capped oligomer, and an article comprising the thermosetting composition, are also disclosed.
摘要翻译： 在一个实施方案中，本领域的上述缺点通过制备羧酸封端的低聚物的方法得到缓解，所述低聚物包括使二羧酸，二羟基化合物，羟基封端的嵌段软嵌段化合物，碳酸二芳基酯和 一种催化剂，其中二羟基封端的软嵌段化合物与二羟基化合物的摩尔比为1:4至1:40，二羧酸与二羟基封端的软嵌段化合物的摩尔数的摩尔比为 1.01:1-2:1，二芳基碳酸酯与二羟基封端软嵌段化合物的摩尔量的摩尔比为1.5:1〜3:1。 还公开了通过上述方法制备的羧酸封端的低聚物。 还公开了包含羧酸封端的低聚物的热固性组合物和包含该热固性组合物的制品。
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2.发明申请公开(公告)号：US20060116487A1
公开(公告)日：2006-06-01
申请号：US10999025
申请日：2004-11-29
CPC分类号： C08G63/85 , C08G63/191 , C08G63/64
摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of atleast some phenoxy end groups.
摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。
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3.发明申请公开(公告)号：US20070027290A1
公开(公告)日：2007-02-01
申请号：US11528206
申请日：2006-09-27
IPC分类号： C08G63/00
CPC分类号： C08G63/85 , C08G63/191 , C08G63/64
摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of at least some phenoxy end groups.
摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。
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公开(公告)号：US07687595B2
公开(公告)日：2010-03-30
申请号：US11834417
申请日：2007-08-06
CPC分类号： C08G64/14 , C08G64/081 , C08G64/307
摘要： A sulfonated telechelic polycarbonate is described which is produced by melt synthesis. A dihydroxy compound is reacted with a sulfobenzoic acid salt, then with an activated carbonate. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
摘要翻译： 描述了通过熔融合成制备的磺化遥爪聚碳酸酯。 二羟基化合物与磺基苯甲酸盐反应，然后与活性碳酸酯反应。 该方法产生磺化的遥爪聚碳酸酯，其具有高百分比的磺化端基，是可溶的并且是透明的。
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公开(公告)号：US08975360B2
公开(公告)日：2015-03-10
申请号：US13941709
申请日：2013-07-15
CPC分类号： C08K9/04 , B82Y30/00 , C08J5/005 , C08J2369/00 , C08K3/346 , Y10T428/139 , C08L69/00
摘要： Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
摘要翻译： 公开了包含磺化遥爪聚碳酸酯和有机改性粘土的纳米复合材料。 聚碳酸酯纳米复合材料具有改善的物理和机械性能。
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公开(公告)号：US08487066B2
公开(公告)日：2013-07-16
申请号：US13351102
申请日：2012-01-16
CPC分类号： C08K9/04 , B82Y30/00 , C08J5/005 , C08J2369/00 , C08K3/346 , Y10T428/139 , C08L69/00
摘要： Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
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公开(公告)号：US20120238665A1
公开(公告)日：2012-09-20
申请号：US13351102
申请日：2012-01-16
CPC分类号： C08K9/04 , B82Y30/00 , C08J5/005 , C08J2369/00 , C08K3/346 , Y10T428/139 , C08L69/00
摘要： Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
摘要翻译： 公开了包含磺化遥爪聚碳酸酯和有机改性粘土的纳米复合材料。 聚碳酸酯纳米复合材料具有改善的物理和机械性能。
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8.发明授权公开(公告)号：US07557174B2
公开(公告)日：2009-07-07
申请号：US11528206
申请日：2006-09-27
CPC分类号： C08G63/85 , C08G63/191 , C08G63/64
摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of at least some phenoxy end groups.
摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。
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公开(公告)号：US20090043071A1
公开(公告)日：2009-02-12
申请号：US11834417
申请日：2007-08-06
CPC分类号： C08G64/14 , C08G64/081 , C08G64/307
摘要： A sulfonated telechelic polycarbonate is described which is produced by melt synthesis. A dihydroxy compound is reacted with a sulfobenzoic acid salt, then with an activated carbonate. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
摘要翻译： 描述了通过熔融合成制备的磺化遥爪聚碳酸酯。 二羟基化合物与磺基苯甲酸盐反应，然后与活性碳酸酯反应。 该方法产生具有高百分比的磺化端基的磺化遥爪聚碳酸酯，是可溶的并且是透明的。
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公开(公告)号：US20100168461A1
公开(公告)日：2010-07-01
申请号：US12347221
申请日：2008-12-31
申请人： Corrado Berti , Enrico Binassi , Martino Colonna , Maurizio Fiorini , Ganesh Kannan , Sreepadaraj Karanam , Marzia Mazzacurati , Ihab Odeh
发明人： Corrado Berti , Enrico Binassi , Martino Colonna , Maurizio Fiorini , Ganesh Kannan , Sreepadaraj Karanam , Marzia Mazzacurati , Ihab Odeh
摘要： Bio-based terephthalic acid (bio-TPA), bio-based dimethyl terephthalate (bio-DMT), and bio-based polyesters, which are produced from a biomass containing a terpene or terpenoid, such as limonene are described, as well as the process of making these products. The bio-based polyesters include poly(alkylene terephthalate)s such as bio-based poly(ethylene terephthalate) (bio-PET), bio-based poly(trimethylene terephthalate) (bio-PTT), bio-based poly(butylene terephthalate) (bio-PBT), and bio-based poly(cyclohexylene dimethyl terephthalate) (bio-PCT).
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