Abstract:
A method of operating an iron redox flow battery system may comprise fluidly coupling a plating electrode of an iron redox flow battery cell to a plating electrolyte; fluidly coupling a redox electrode of the iron redox flow battery cell to a redox electrolyte; fluidly coupling a ductile plating additive to one or both of the plating electrolyte and the redox electrolyte; and increasing an amount of the ductile plating additive to the plating electrolyte in response to an increase in the plating stress at the plating electrode. In this way, ductile Fe can be plated on the negative electrode, and the performance, reliability and efficiency of the iron redox flow battery can be maintained. In addition, iron can be more rapidly produced and plated at the plating electrode, thereby achieving a higher charging rate for all iron flow batteries.
Abstract:
An iron redox flow battery system, comprising a redox electrode, a plating electrolyte tank, a plating electrode, a redox electrolyte tank with additional acid additives that may be introduced into the electrolytes in response to electrolyte pH. The acid additives may act to suppress undesired chemical reactions that create losses within the battery and may be added in response to sensor indications of these reactions.
Abstract:
A redox flow battery may include: a membrane interposed between a first electrode positioned at a first side of the membrane and a second electrode positioned at a second side of the membrane opposite to the first side; a first flow field plate comprising a plurality of positive flow field ribs, each of the plurality of positive flow field ribs contacting the first electrode at first supporting regions on the first side; and the second electrode, including an electrode spacer positioned between the membrane and a second flow field plate, the electrode spacer comprising a plurality of main ribs, each of the plurality of main ribs contacting the second flow field plate at second supporting regions on the second side, each of the second supporting regions aligned opposite to one of the plurality of first supporting regions. As such, a current density distribution at a plating surface may be reduced.
Abstract:
A redox flow battery system is provided. The system includes a positive electrode in fluid communication with a positive electrolyte comprising a first metal ion and a negative electrode in fluid communication with a negative electrolyte comprising a second metal ion. An electrically insulating ion conducting surface is provided separating the positive electrode from the negative electrode. Further, the system includes a catalyst surface in fluid communication with the first metal ion, the second metal ion, or a combination thereof, and hydrogen gas, wherein the hydrogen gas and the first metal ion, the second metal ion, or a combination thereof are fluidly contacted at the catalyst surface.
Abstract:
A method of rebalancing electrolytes in a redox flow battery system comprises directing hydrogen gas generated on the negative side of the redox flow battery system to a catalyst surface, and fluidly contacting the hydrogen gas with an electrolyte comprising a metal ion at the catalyst surface, wherein the metal ion is chemically reduced by the hydrogen gas at the catalyst surface, and a state of charge of the electrolyte and pH of the electrolyte remain substantially balanced.
Abstract:
A method of cleansing a redox flow battery system may include operating the redox flow battery system in a charge, discharge, or idle mode, and responsive to a redox flow battery capacity being less than a threshold battery capacity, mixing the positive electrolyte with the negative electrolyte. In this way, battery capacity degradation following cyclic charging and discharging of the redox flow battery system can be substantially reduced.
Abstract:
A method of rebalancing electrolytes in a redox flow battery system comprises directing hydrogen gas generated on the negative side of the redox flow battery system to a catalyst surface, and fluidly contacting the hydrogen gas with an electrolyte comprising a metal ion at the catalyst surface, wherein the metal ion is chemically reduced by the hydrogen gas at the catalyst surface, and a state of charge of the electrolyte and pH of the electrolyte remain substantially balanced.
Abstract:
A hybrid redox fuel cell system includes a hybrid redox fuel cell and an electrochemical cell. The hybrid redox fuel cell includes an anode side through which hydrogen is flowed and a cathode side through which liquid electrolyte is flowed, the liquid electrolyte including a metal ion at a higher oxidation state and the metal ion at a lower oxidation state. An anode side of the electrochemical cell is fluidly connected to the cathode side of the hybrid redox fuel cell. At the hybrid redox fuel cell, power is generated by reducing the metal ion at the higher oxidation state to the lower oxidation state at the cathode side while oxidizing the reductant at the anode side. At the anode side of the electrochemical cell, the metal ion at the lower oxidation state is oxidized to the higher oxidation state while the power is generated.
Abstract:
A hybrid redox fuel cell system includes a hybrid redox fuel cell including an anode side through which a reductant is flowed and a cathode side through which liquid electrolyte is flowed, and a catalyst bed fluidly connected to the cathode side of the hybrid redox fuel cell, the catalyst bed including a substrate layer and a catalyst layer spiral wound into a jelly roll structure. Furthermore, the liquid electrolyte includes a metal ion at a higher oxidation state and the metal ion at a lower oxidation state, and power is generated at the hybrid redox fuel cell by way of reducing the metal ion from the higher oxidation state to the lower oxidation state at the cathode side while oxidizing the reductant at the anode side.
Abstract:
A method of rebalancing electrolytes in a redox flow battery system comprises directing hydrogen gas generated on the negative side of the redox flow battery system to a catalyst surface, and fluidly contacting the hydrogen gas with an electrolyte comprising a metal ion at the catalyst surface, wherein the metal ion is chemically reduced by the hydrogen gas at the catalyst surface, and a state of charge of the electrolyte and pH of the electrolyte remain substantially balanced.