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公开(公告)号：US20220403254A1
公开(公告)日：2022-12-22
申请号：US17755344
申请日：2020-10-29
发明人： Michael Gary Polasek , Daryl Bitting , David Eugene Slivensky , Xianchun Wu , Carey Dan Ashcroft , Jerome Leonard Stavinoha, Jr.
摘要： Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). The r-olefin may then be further separated into product streams in a separation zone downstream of the cracker furnace. In some cases, presence of recycle content hydrocarbons may facilitate more efficient operation of one or more distillation columns in the separation zone, including the debutanizer.
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公开(公告)号：US20220396735A1
公开(公告)日：2022-12-15
申请号：US17755322
申请日：2020-10-29
发明人： Xianchun Wu , Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , Damon Ray Billodeaux
摘要： A pyrolysis method and system are provided that utilizes a multistage dehalogenation method to effectively remove halogen-containing compounds that are present in an initial recycled plastic feedstock. More particularly, the multistage dehalogenation system and process may involve physical sorting the plastic feedstock, melting and separating the feedstock, and subjecting the feedstock a two-stage pyrolysis with intermediate HCl removal.
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公开(公告)号：US20220380685A1
公开(公告)日：2022-12-01
申请号：US17755346
申请日：2020-10-29
发明人： Xianchun Wu , Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , William Lewis Trapp
摘要： Processes and systems for making recycle content hydrocarbons, including olefins, are provided that integrate a cracker unit with one or more other processing units. For example, in some cases, a pyrolysis unit and cracking unit may share a common energy exchange zone so that energy from one unit may be transferred to the other. The energy exchange may be direct or indirect and may be present at one or more locations between the units.
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公开(公告)号：US20220380683A1
公开(公告)日：2022-12-01
申请号：US17755627
申请日：2020-11-06
发明人： David Eugene Slivensky , Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , William Lewis Trapp , Xianchun Wu
摘要： A composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content alpha olefin or by deducting from a recycle inventory a recycle content value applied to an alpha olefin composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by an alpha olefin manufacturer has its origin in recycled waste and/or pyrolysis of recycled waste and/or in thermal steam cracking of recycle content pyoil.
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公开(公告)号：US20220340821A9
公开(公告)日：2022-10-27
申请号：US17593383
申请日：2020-05-22
发明人： Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , Xianchun Wu , Jerome Leonard Stavinoha, Jr.
摘要： A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.
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公开(公告)号：US20220281793A1
公开(公告)日：2022-09-08
申请号：US17597822
申请日：2020-07-29
发明人： David Eugene Slivensky , Kenny Randolph Parker , William Lewis Trapp , Daryl Bitting , Michael Gary Polasek , Xianchun Wu
IPC分类号： C07C45/50
摘要： A recycle content ethylene is fed to a reactor to make propionaldehyde having recycle content. The recycle ethylene feedstock is derived directly or indirectly from the cracking of recycle content pyrolysis oil. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.
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公开(公告)号：US20220228071A1
公开(公告)日：2022-07-21
申请号：US17595511
申请日：2020-05-22
发明人： Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , Xianchun Wu , Jerome Leonard Stavinoha, Jr.
IPC分类号： C10G9/00
摘要： A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly C4-C7 fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.
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公开(公告)号：US11365357B2
公开(公告)日：2022-06-21
申请号：US16881035
申请日：2020-05-22
发明人： Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , Xianchun Wu , Jerome Leonard Stavinoha, Jr.
摘要： A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.
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公开(公告)号：US20220154082A1
公开(公告)日：2022-05-19
申请号：US17593383
申请日：2020-05-22
发明人： Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , Xianchun Wu , Jerome Leonard Stavinoha, Jr.
摘要： A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.
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公开(公告)号：US20220154077A1
公开(公告)日：2022-05-19
申请号：US17594308
申请日：2020-05-22
发明人： Daryl Bitting , Kenny Randolph Parker , Michael Gary Polasek , David Eugene Slivensky , Xianchun Wu , Jerome Leonard Stavinoha, Jr.
IPC分类号： C10G1/10
摘要： A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More particularly cracker feedstock comprises a recycle content pyrolysis oil composition (r-pyoil), wherein the cracker feedstock has a boiling point curve defined the following characteristics (i) through (iii): (i) a 90% boiling point at least 350° C.; (ii) a 10% boiling point of at least 60° C.; and (iii) a 50% boiling point in the range of from 95° C. to 200° C.
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