公开(公告)号：US4711679A

公开(公告)日：1987-12-08

申请号：US923447

申请日：1985-10-22

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C06B25/22 ,  C06B25/34 ,  C06B45/10 ,  C07D251/54

CPC classification number: C06B25/34 ,  C06B25/22 ,  C06B45/105

Abstract: Hexakis (2-nitroxyethyl) melamine which is useful as an energetic plasticr.

Abstract translation: 六甲基（2-硝基乙基）三聚氰胺，可用作高能增塑剂。

公开(公告)号：US4661179A

公开(公告)日：1987-04-28

申请号：US891802

申请日：1986-07-24

Applicant: Benjamin A. Hunter ,  Everett E. Gilbert

Inventor： Benjamin A. Hunter ,  Everett E. Gilbert

IPC: A62D3/00 ,  A62D3/37 ,  A62D101/06 ,  A62D101/26 ,  A62D101/28 ,  B09B3/00 ,  C06B21/00 ,  C06B25/34 ,  D03D23/00

CPC classification number: A62D3/37 ,  B09B3/00 ,  C06B21/0091 ,  C06B25/34 ,  A62D2101/06 ,  A62D2101/26 ,  A62D2101/28 ,  Y10S149/124

Abstract: A method for destroying organic explosives, such as RDX and HMX, by hydroolysis comprises contacting liquors containing waste explosive, produced in the manufacture and processing of the explosives, with hydrogen in the presence of a heterogeneous hydrogenation catalyst, such as nickel-on-kieselguhr, for a sufficient period to destroy the explosives. The method is simple and economic and destroys the explosives, which are considered to be toxic, hazardous and non-biodegradable in soil and hence are not amenable to landfill or discharge into rivers etc., thereby eliminating or reducing the attendant pollution problems to acceptable levels.

Abstract translation: 通过氢解来破坏有机爆炸物如RDX和HMX的方法包括将非常多种氢化催化剂（例如镍 - 硅藻土）存在下将含有在爆炸物的制造和加工中生产的废爆炸物的液体与氢气接触 有足够的时间来摧毁爆炸物。 该方法简单经济，破坏了土壤中有毒，有害，不可生物降解的爆炸物，因此不适合填埋或排入河流等，从而消除或减少伴随的污染问题达到可接受的水平 。

公开(公告)号：USH103H

公开(公告)日：1986-08-05

申请号：US711892

申请日：1985-03-14

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C06B45/10 ,  C08F8/30

CPC classification number: C06B45/105 ,  C08F8/30 ,  C08F114/06

Abstract: Poly(vinylazide) having less then 1.5 percent chlorine. The product, i.e.,oly(vinylazide) being the reaction product of poly(vinylchloride) and sodium or lithium azide by heating the gel product for an extended period of time in the presence of the azide reactant.

公开(公告)号：US4476060A

公开(公告)日：1984-10-09

申请号：US535481

申请日：1983-09-26

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C06B25/00 ,  C07C203/08 ,  C07C77/00

CPC classification number: C06B25/00 ,  C07C203/08

Abstract: 1,3,5,7-Tetranitroxyadamantane is a novel propellant having desirably low pact sensitivity. It can be prepared by reacting 1,3,5,7-tetrahydroxyadamantane or 1,3,5,7-tetraacetoxyadamantane with mixed conc. nitric and sulfuric acids.

Abstract translation: 1,3,5,7-四硝基金刚烷是具有理想的低冲击敏感性的新型推进剂。 它可以通过使1,3,5,7-四羟基金刚烷或1,3,5,7-四乙酰氧基金刚烷与混合的浓缩物 硝酸和硫酸。

公开(公告)号：US4329522A

公开(公告)日：1982-05-11

申请号：US196956

申请日：1980-10-14

Applicant: Everett E. Gilbert ,  Gilbert P. Sollott

Inventor： Everett E. Gilbert ,  Gilbert P. Sollott

IPC: C07C205/05 ,  C07C79/08 ,  C07C76/02

CPC classification number: C07C205/05 ,  C07C2103/74

Abstract: The invention provides a novel explosive compound 1,3,5,7-tetranitroadamane, which possesses high explosive energy combined with excellent impact and thermal stability. The novel compound can be prepared by oxidation of 1,3,5,7-tetraaminoadamantane with permanganate.

Abstract translation: 本发明提供了一种新型的爆炸性化合物1,3,5,7-四硝基金刚烷，其具有高爆炸能量，具有优异的冲击和热稳定性。 该新型化合物可以通过用高锰酸盐氧化1,3,5,7-四氨基金刚烷来制备。

公开(公告)号：US4268696A

公开(公告)日：1981-05-19

申请号：US111754

申请日：1980-01-14

Applicant: Gilbert P. Sollott ,  Everett E. Gilbert ,  Maurice Warman

Inventor： Gilbert P. Sollott ,  Everett E. Gilbert ,  Maurice Warman

IPC: C07C205/06 ,  C07C79/10

CPC classification number: C07C201/12

Abstract: 2,2',4,4',6,6'-hexanitrostilbene, a thermally stable explosive material, isrepared by reacting 2,2',4,4',6,6'-hexanitrobibenzyl with a quinone in a suitable reaction solvent such as hexamethyl phosphoric triamide, dimethyl sulfoxide and N-methyl-pyrrolidinone. The use of organic bases to promote the reaction and to allow the use of normally inoperative reaction solvents is also disclosed.

Abstract translation: 通过使2,2'，4,4'，6,6'-六硝基苄基与醌在合适的反应中反应制备2,2'，4,4'，6,6'-己rost二烯，一种热稳定的爆炸物质 溶剂如六甲基磷酸三酰胺，二甲基亚砜和N-甲基 - 吡咯烷酮。 还公开了使用有机碱促进反应并允许使用通常不操作的反应溶剂。

公开(公告)号：US4243614A

公开(公告)日：1981-01-06

申请号：US69216

申请日：1979-08-23

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C205/06 ,  C07C79/10

CPC classification number: C07C201/12

Abstract: 2,2',4,4',6,6'-Hexanitrostilbene is produced by reacting 2,2',4,4',6,6'-hnitrobibenzyl with copper sulfate in hexamethylphosphoric triamide as a reaction solvent. The HNS product can be thus produced in greater than 80% yields.

Abstract translation: 通过使2,2'，4,4'，6,6'-六硝基苄基与硫酸铜在六甲基磷酰三胺中作为反应溶剂反应制备2,2'，4,4'，6,6'-己腈二萜烯。 因此，HNS产品可以以大于80％的产率生产。

公开(公告)号：US4221746A

公开(公告)日：1980-09-09

申请号：US20889

申请日：1979-03-15

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C205/06 ,  C07C79/10

CPC classification number: C07C201/12

Abstract: There is disclosed a process for converting 2,2', 4,4', 6,6'-hexanitrobibyl (HNBB) to 2,2', 4,4', 6,6'-hexanitrostilbene (HNS) in high yields by reacting HNBB with a halogenating agent in the presence of a base in an organic solvent or a liquid suspending agent. A preferred halogenating agent is bromine; a preferred base is pyridine; a preferred solvent is dimethylformamide; and a preferred liquid suspending agent is toluene or chlorobenzene.

Abstract translation: 公开了通过以高产率将2,2'，4,4'，6,6'-六硝基苄（HNBB）转化为2,2'，4,4'，6,6'-己二芪（HNS）的方法， 在碱存在下在有机溶剂或液体悬浮剂中使HNBB与卤化剂反应。 优选的卤化剂是溴; 优选的碱是吡啶; 优选的溶剂是二甲基甲酰胺; 优选的液体悬浮剂是甲苯或氯苯。

公开(公告)号：US4003953A

公开(公告)日：1977-01-18

申请号：US660073

申请日：1976-02-23

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C201/16 ,  C07C79/10

CPC classification number: C07C201/16 ,  C06B21/0091

Abstract: Crude TNT is purified by heating with an aqueous mixture of magnesium sulfite and magnesium bisulfite, whereby TNT is recovered in high yield and purity. The spent aqueous solution can be furnaced to recover magnesium oxide, which can be recycled to the process.

Abstract translation: 通过用亚硫酸镁和亚硫酸氢镁的水性混合物加热来纯化粗TNT，由此以高产率和纯度回收TNT。 可以将废水溶液加热回收氧化镁，这可以循环使用。

公开(公告)号：US3956409A

公开(公告)日：1976-05-11

申请号：US585735

申请日：1975-06-10

Applicant: Everett E. Gilbert

Inventor： Everett E. Gilbert

IPC: C07C201/16 ,  C07C79/10

CPC classification number: C07C201/16 ,  C06B21/0091

Abstract: Unsymmetrical TNT isomers are removed from solid or molten crude TNT by treatment with aqueous ammonium sulfite. The yield of purified TNT is significantly greater by treatment with aqueous ammonium sulfite than with conventional sodium sulfite ("sellite") at acceptable levels of isomer removal. By use of ammonium bisulfite together with ammonium sulfite or operation in a closed system to avoid loss of ammonia, high yields of TNT with essentially complete removal of TNT isomers can be obtained at low sulfite levels.

Abstract translation: 通过用亚硫酸铵水溶液处理，从固体或熔融粗TNT中除去不对称的TNT异构体。 通过用亚硫酸铵水溶液处理，纯化的TNT的产率比常规亚硫酸钠（“卫星”）处于可接受的异构体去除水平下显着更大。 通过使用亚硫酸氢铵与亚硫酸铵一起使用或在封闭系统中操作以避免氨的损失，可以在低亚硫酸盐水平下获得基本上完全去除TNT异构体的高产率的TNT。