公开(公告)号：US20200270524A1

公开(公告)日：2020-08-27

申请号：US16871311

申请日：2020-05-11

Applicant: FUJIFILM Corporation

Inventor： Takahiro OHNO ,  Makoto ISHIGURO ,  Yoshiaki HISAKADO ,  Hiroshi SATO ,  Keita TAKAHASHI ,  Naozumi SHIRAIWA ,  Taiji KATSUMATA ,  Hiroshi MATSUYAMA

IPC: C09K19/38 ,  G02F1/13363 ,  C09K19/54 ,  C09K19/34 ,  G02B5/30 ,  C08F236/20

Abstract: The present invention is to provide an optical film having optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention is an optical film having at least an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound and a polymerization initiator, and an extrapolated glass transition starting temperature of the optically anisotropic layer is 70° C. or higher.

公开(公告)号：US20190023986A1

公开(公告)日：2019-01-24

申请号：US16142538

申请日：2018-09-26

Applicant: FUJIFILM Corporation

Inventor： Shinichi YOSHINARI ,  Hiroshi SATO ,  Shinnosuke SAKAI ,  Keita TAKAHASHI ,  Naozumi SHIRAIWA ,  Hiroshi MATSUYAMA

IPC: C09K19/34 ,  G02B5/30 ,  C09K19/54

Abstract: An object of the present invention is to provide an optical film having an optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. This optical film of the present invention is an optical film at least having an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound, a predetermined mesogen compound, and a polymerization initiator, an I/O value of the liquid crystal compound is more than 0.56, and an I/O value of the mesogen compound is 0.56 or less.

公开(公告)号：US20160108315A1

公开(公告)日：2016-04-21

申请号：US14887858

申请日：2015-10-20

Applicant: FUJIFILM Corporation

Inventor： Hiroshi MATSUYAMA ,  Ryoji GOTO ,  Hiroyuki ISHIKAWA ,  Keita TAKAHASHI ,  Taiji KATSUMATA

IPC: C09K19/34 ,  G02B5/30 ,  B32B27/08 ,  C09K19/38 ,  B32B27/30

CPC classification number: C09K19/3491 ,  B32B23/04 ,  B32B23/08 ,  B32B23/20 ,  B32B27/08 ,  B32B27/308 ,  B32B33/00 ,  B32B2250/24 ,  B32B2255/00 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2305/55 ,  B32B2307/40 ,  B32B2307/4026 ,  B32B2307/42 ,  B32B2307/514 ,  B32B2307/706 ,  B32B2307/7246 ,  B32B2457/20 ,  C09K19/3001 ,  C09K19/3068 ,  C09K19/3477 ,  C09K19/348 ,  C09K19/3486 ,  C09K19/3494 ,  C09K19/3497 ,  C09K19/38 ,  C09K19/3823 ,  C09K19/3861 ,  C09K2019/0448 ,  C09K2019/3408 ,  G02B5/3016 ,  G02B5/305

Abstract: An optically anisotropic layer is formed by a liquid crystal compound represented by General Formula 1, in which the long axes of the molecules are oriented. wherein L1 and L2 independently represent a linking group having a carbonyl group; F1 and F2 independently represent an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a halogen atom; n and m independently represent an integer from 0 to 4; a and b independently represent an integer from 1 to 4; T1 and T2 independently represent a spacer portion including a straight chain or branched alkylene or alkylene oxide group having 2 to 20 carbon atoms; and Ar represents a divalent group having at least one aromatic ring selected from a group consisting of aromatic hydrocarbon rings and aromatic heterocycles, the number of Π electrons in the Ar group being 8 or greater.

Abstract translation: 光学各向异性层由通式1表示的液晶化合物形成，其中分子的长轴取向。 其中L1和L2独立地表示具有羰基的连接基团; F1和F2独立地表示碳原子数1〜4的烷基，碳原子数1〜4的烷氧基或卤原子。 n和m独立地表示0〜4的整数。 a和b独立地表示1〜4的整数， T1和T2独立地表示包括具有2至20个碳原子的直链或支链亚烷基或烯化氧基团的间隔部分; Ar表示具有至少一个选自芳香族烃环和芳香族杂环的芳香族环的二价基团， Ar组中的电子为8或更大。

公开(公告)号：US20150344782A1

公开(公告)日：2015-12-03

申请号：US14822213

申请日：2015-08-10

Applicant: FUJIFILM CORPORATION

Inventor： Hiroshi MATSUYAMA ,  Shunya KATOH ,  Masaru YOSHIKAWA

IPC: C09K19/38

CPC classification number: C09K19/3838 ,  C08F220/30 ,  C08K5/107 ,  C08L33/14 ,  C09K19/2014 ,  C09K19/54 ,  C09K2019/0448 ,  C09K2019/2078 ,  C09K2019/548 ,  C09K2219/03 ,  G02B5/3016 ,  G02F1/13363

Abstract: Provided is a liquid crystal composition which is easily synthesized and highly suppress crystallization thereof. The liquid crystal composition includes at least one compound represented by formula (1), wherein Z1 represents —CO—, —O—CO— or single bond, and Z2 represents —CO— or —CO—CH═CH—, at least one compound represented by formula (2) not having (meth)acrylate group, wherein Z3 represents —CO— or —CH═CH—CO—, and Z4 represents —CO— or —CO—CH═CH—, and at least one compound represented by formula (3), wherein Z5 represents —CO—, —O—CO— or single bond, and Z6 represents —CO—, —CO—O— or single bond.

Abstract translation: 提供一种易于合成并高度抑制其结晶的液晶组合物。 液晶组合物包含至少一种式（1）表示的化合物，其中Z 1表示-CO-，-O-CO-或单键，Z 2表示-CO-或-CO-CH = CH-，至少一个 不具有（甲基）丙烯酸酯基团的式（2）表示的化合物，其中Z 3表示-CO-或-CH = CH-CO-，Z 4表示-CO-或-CO-CH = CH-，以及至少一种化合物 由式（3）表示，其中Z5表示-CO-，-O-CO-或单键，Z6表示-CO-，-CO-O-或单键。

公开(公告)号：US20150277007A1

公开(公告)日：2015-10-01

申请号：US14672888

申请日：2015-03-30

Applicant: FUJIFILM Corporation

Inventor： Hiroshi MATSUYAMA ,  Shinichi MORISHIMA ,  Yuki NAKAZAWA

IPC: G02B5/30 ,  C08F122/26 ,  C07D277/82 ,  C07D277/64

CPC classification number: G02B5/3016 ,  C07D277/64 ,  C07D277/82 ,  C08F122/26 ,  C08F222/1006 ,  C08F222/24 ,  G02B5/3083 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/31931

Abstract: An optical film of the present invention includes an optically anisotropic layer containing a compound represented by the following general formula (1) or an optically anisotropic layer formed by the curing of a polymerizable composition containing a compound represented by the following general formula (1):

Abstract translation: 本发明的光学膜包括含有由以下通式（1）表示的化合物的光学各向异性层或通过固化含有下述通式（1）表示的化合物的聚合性组合物形成的光学各向异性层：

公开(公告)号：US20150277006A1

公开(公告)日：2015-10-01

申请号：US14672852

申请日：2015-03-30

Applicant: FUJIFILM Corporation

Inventor： Rie TAKASAGO ,  Hiroshi MATSUYAMA ,  Makoto ISHIGURO ,  Shinichi MORISHIMA

IPC: G02B5/30 ,  C09K19/54 ,  C09K19/34 ,  C09K19/20 ,  G02B1/11 ,  G02B1/12

CPC classification number: G02B5/3016 ,  C09K19/2007 ,  C09K19/2014 ,  C09K19/348 ,  C09K19/3486 ,  C09K19/3491 ,  C09K19/3494 ,  C09K19/3497 ,  C09K19/542 ,  C09K19/601 ,  C09K2019/0448 ,  C09K2019/3077 ,  C09K2019/548 ,  G02B1/11 ,  G02B1/12 ,  G02B5/3083

Abstract: An optical film of the present invention includes a positive A-plate and a positive C-plate, in which the Re(450), Re(550), and Re(650) of the positive A-plate satisfy the relationship of Re(450)≦Re(550)≦Re(650), the positive A-plate is formed of a cured product of a composition including the liquid crystal compound A, and the positive C-plate is formed of a cured product of a composition including the liquid crystal compound C.

Abstract translation: 本发明的光学膜包括正A板和正C板，其中正A板的Re（450），Re（550）和Re（650）满足Re（ 450）＆nlE; Re（550）＆nlE; Re（650）中，正A板由包含液晶化合物A的组合物的固化产物形成，正极板由固化产物形成 包含液晶化合物C的组合物

公开(公告)号：US20150002789A1

公开(公告)日：2015-01-01

申请号：US14315975

申请日：2014-06-26

Applicant: FUJIFILM Corporation

Inventor： Hiroyuki KAIHOKO ,  Yuki MATSUDA ,  Tatsuya IWASAKI ,  Shunya KATOH ,  Hiroshi MATSUYAMA ,  Toshiyuki SAIKI

IPC: G02F1/13363 ,  G02F1/1337 ,  G02F1/1335 ,  G02B5/30 ,  G02F1/1347

CPC classification number: G02B5/3016 ,  G02F2001/133633

Abstract: To provide an optically-compensatory film that can improve the contrast, to provide a polarizing plate and a liquid crystal display including the optically-compensatory film and a method of producing the optically-compensatory film. An optically-compensatory film including a transparent support; and at least one optically anisotropic layer including a liquid crystal composition containing liquid crystal compounds, in the transparent support; wherein when the optically-compensatory film is disposed between two polarizing plates in a cross nicol state, degree of depolarization as seen from the front face is 0.000022 or less, and degree of depolarization as seen from a polar angle of 50° from an absorption axis direction of one of the polarizing plates is 0.00077 or less.

Abstract translation: 为了提供可以提高对比度的光学补偿膜，提供一种偏光板和包括光学补偿膜的液晶显示器和一种制造光学补偿膜的方法。 一种光学补偿膜，包括透明支撑体; 和至少一个包含含有液晶化合物的液晶组合物的光学各向异性层; 其中当光学补偿膜设置在交叉尼科尔状态的两个偏振片之间时，从前表面看去极化程度为0.000022或更小，从与吸收轴的极角50°角度看去极化程度 一个偏振片的方向为0.00077以下。

公开(公告)号：US20230265346A1

公开(公告)日：2023-08-24

申请号：US18151893

申请日：2023-01-09

Applicant: FUJIFILM Corporation

Inventor： Wataru HOSHINO ,  Hiroshi MATSUYAMA ,  Keigo SHIGA

IPC: C09K19/52 ,  C09K19/60

CPC classification number: C09K19/52 ,  C09K19/60 ,  C09K2019/528

Abstract: An object of the present invention is to provide a liquid crystal composition capable of forming an optically anisotropic layer with suppressed alignment defects and an excellent alignment degree, an optically anisotropic layer, a laminate, and an image display device. The liquid crystal composition of the present invention includes a rod-like liquid crystal compound, and an interface improver having a repeating unit B1 represented by Formula (N-1) and a repeating unit B2 having a fluorine atom. In Formula (N-1), RB11 and RB12 each independently represent a hydrogen atom or a substituent, and RB13 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, a halogen atom, or a cyano group. Here, in a case where RB11 and RB12 represent a substituent, RB11 and RB12 may be linked to each other to form a ring.

公开(公告)号：US20230213823A1

公开(公告)日：2023-07-06

申请号：US18060873

申请日：2022-12-01

Applicant: FUJIFILM Corporation

Inventor： Yumi KATO ,  Naoki KOITO ,  Hiroshi MATSUYAMA ,  Akihiro SUGITA ,  Takehiro KASAHARA ,  Naoyoshi YAMADA

IPC: G02F1/135 ,  G02F1/1333 ,  G02F1/1335 ,  H01J49/40 ,  G02F1/13363

CPC classification number: G02F1/1351 ,  G02F1/133354 ,  G02F1/133509 ,  H01J49/40 ,  G02F1/13363

Abstract: Provided is a light absorption anisotropic film capable of preparing an image display device having excellent display performance and excellent durability, and a laminate and an image display device formed of the light absorption anisotropic film. The light absorption anisotropic film is used for an image display device, which is formed of a liquid crystal composition containing a liquid crystal compound and a dichroic substance, in which in a signal derived from the dichroic substance detected by time-of-flight secondary ion mass spectrometry, a relationship between a maximum intensity Imax of the light absorption anisotropic film in a thickness direction and an intensity Isur1 in a surface of the light absorption anisotropic film on a viewing side of the image display device satisfies Expression (I-1) 2.0≤Imax/Isur1.

公开(公告)号：US20230159827A1

公开(公告)日：2023-05-25

申请号：US18151908

申请日：2023-01-09

Applicant: FUJIFILM Corporation

Inventor： Keigo SHIGA ,  Hiroshi MATSUYAMA ,  Wataru HOSHINO ,  Yumi KATO

IPC: C09K19/54 ,  C08F222/38 ,  C08F222/20 ,  C09K19/38

CPC classification number: C09K19/542 ,  C08F222/38 ,  C08F222/20 ,  C09K19/3838 ,  G02B5/3016

Abstract: An object of the present invention is to provide a liquid crystal composition capable of forming an optically anisotropic layer with suppressed cissing during formation of an optically anisotropic layer and an excellent alignment degree, a fluorine-containing polymer, an optically anisotropic layer, a laminate, and an image display device. The liquid crystal composition of the present invention is a liquid crystal composition including a liquid crystal compound and an interface improver, in which the interface improver is a fluorine-containing polymer having a repeating unit B1 represented by Formula (B-1) and a repeating unit B2 having a fluorine atom.