公开(公告)号：US4710198A

公开(公告)日：1987-12-01

申请号：US806871

申请日：1985-12-09

Applicant: Fabio Beffa ,  Hans U. Schutz

Inventor： Fabio Beffa ,  Hans U. Schutz

IPC: C09B45/04 ,  C09B45/14 ,  C09B29/30 ,  D06P1/10 ,  D06P3/24

CPC classification number: C09B45/14 ,  Y10S8/917 ,  Y10S8/924

Abstract: A process of dyeing polyamide-containing material is disclosed using dyes of the following formula: ##STR1## wherein Me is cobalt or chromium,Ka.sup..sym. is a cation,p is 0 or 1,R and R' are each independently of the other hydrogen or a group of the formula --CO--(O).sub.n --Y, wheren is 0 or 1, andY is C.sub.1 -C.sub.5 alkyl, or phenyl which may be substituted by nitro, halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, with the proviso that R and R' may not both be hydrogen if p is 1.Novel dyes within this class are also disclosed. The process is especially useful for dyeing leather.

Abstract translation: 公开了使用以下化学式的染料的染色方法：其中Me是钴或铬，Ka（+）是阳离子，p是0或1，R和R'各自独立地为 其它氢或式-CO-（O）nY的基团，其中n为0或1，Y为C 1 -C 5烷基，或可被硝基，卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基， 条件是如果p为1，则R和R'不能都是氢。此类别中的新型染料也被公开。 该方法对于染色皮革特别有用。

公开(公告)号：US4650859A

公开(公告)日：1987-03-17

申请号：US688087

申请日：1984-12-31

Applicant: Fabio Beffa

Inventor： Fabio Beffa

IPC: C09B45/16 ,  C09B55/00 ,  C09B56/02 ,  C09B45/06 ,  D06P1/10 ,  D06P3/32

CPC classification number: C09B55/001

Abstract: Chrome azo-azomethine dyes are disclosed which contain a benzthiazolylphenyl or stilbenyl radical bound via an aldehyde group to the aldehyde moiety of the azomethine dyes. The dyes are particularly useful for dyeing wool, polyamide and leather.

Abstract translation: 公开了偶氮偶氮甲锌染料，其含有通过醛基与偶氮甲碱染料的醛部分键合的苯并噻唑基苯基或茋基。 这些染料特别适用于染色羊毛，聚酰胺和皮革。

公开(公告)号：US4563193A

公开(公告)日：1986-01-07

申请号：US549037

申请日：1983-11-07

Applicant: Fabio Beffa

Inventor： Fabio Beffa

IPC: C09B45/26 ,  C09B45/16 ,  C09B55/00

CPC classification number: C09B55/001 ,  C09B45/16 ,  Y10S8/917 ,  Y10S8/924 ,  Y10S8/926

Abstract: The novel asymmetric 1:2 chrome complex dyes of the formula I given in claim 1 are suitable in particular for dyeing wool or polyamide and especially leather.

Abstract translation: 权利要求1中给出的式I的新型不对称1：2铬复合染料特别适用于染色羊毛或聚酰胺，特别是皮革。

公开(公告)号：US4364864A

公开(公告)日：1982-12-21

申请号：US18089

申请日：1979-03-06

Applicant: Fabio Beffa ,  Gerhard Back ,  Hans U. Schutz

Inventor： Fabio Beffa ,  Gerhard Back ,  Hans U. Schutz

IPC: C09B45/14 ,  C09B45/16 ,  D06P1/10 ,  C09B45/20 ,  D06P3/24

CPC classification number: C09B45/14 ,  D06P1/10

Abstract: Cobalt and chromium complex dyes which contain, bonded to a metal atom, one molecule of each of the azo compounds of the formula ##STR1## wherein R is methyl or ethyl and the phenyl ring a is unsubstituted or substituted by 1 to 2 chlorine atoms, nd mixtures thereof with the symmetrical 1:2 cobalt or chromium complex dyes of the azo compounds of the formulae (1) and (2), said dyes being useful in the dyeing and printing of a variety of materials, especially nitrogen containing materials such as silk, leather, polyamides, polyurethanes and especially wool to obtain level dyes having good fastness to light, washing, water, hot water, fulling, decatizing and carbonizing.

Abstract translation: 含有与金属原子结合的钴和铬络合物染料，每个分子式为具有式（1）和（VI）的偶氮化合物，其中R是甲基或乙基，苯环a是 未被取代或被1至2个氯原子取代，以及与式（1）和（2）的偶氮化合物的对称1:2钴或铬络合物染料的混合物，所述染料可用于染色和印刷 各种材料，特别是含氮材料如丝绸，皮革，聚酰胺，聚氨酯，特别是羊毛，以获得具有良好的耐光牢度，洗涤，水，热水，充满，脱脂和碳化的水平染料。

公开(公告)号：US4331596A

公开(公告)日：1982-05-25

申请号：US102498

申请日：1979-12-11

Applicant: Fabio Beffa ,  Gerhard Back

Inventor： Fabio Beffa ,  Gerhard Back

IPC: C09B45/16 ,  C09B45/06 ,  C09B45/48 ,  C09B55/00 ,  C09B56/02 ,  C09B45/26 ,  D06P3/32

CPC classification number: C09B55/001 ,  C09B45/06

Abstract: 1:2 Chromium complex dyes of the formula ##STR1## wherein A is the radical of a diazo component of the benzene or naphthalene class which carries the complex forming group X in ortho-position to the azo group, B is the radical of a coupling component which couples in ortho-position to the oxy group, D is the radical of an amine of the benzene or naphthalene class which carries the complex-forming group in ortho-position to the azo group, X is an oxygen atom or a --CO--O-- group, Ar is an aromatic carbocyclic radical. Ar' and A" are aromatic carbocyclic or heterocyclic radicals, q is an integer from 0 to 5, n is an integer from 1 to 3, m is an integer from 0 to 2 and p is 0 or 1, but the sum of n+m may be at most 3, and wherein the benzene ring can carry a further fused benzene ring or can be substituted by halogen, nitro, alkyl or alkoxy, and K.sup.+ is a cation. The water-insoluble dyes are useful in dyeing polyamide textile material and for coloring leather, oil vanishes, and paper as well as viscose, polyamide, cellulose ether and cellulose ester spinning compositions, and the water-soluble dyes are useful in dyeing leather, wool, silk, casein, polyamide and polyurethane fibers and furs; and the dyes possess good covering power and fastness properties.

Abstract translation: 1：2式（1）的铬络合物染料其中A是在偶氮基团的邻位携带络合物形成基团X的苯或萘类的重氮组分的基团，B是基团 的偶联组分，其在邻位偶联到氧基，D是苯或萘类的胺基，其带有与偶氮基邻位的络合物形成基团，X是氧原子或 -CO-O-基团，Ar是芳族碳环基团。 Ar'和A“是芳族碳环或杂环基，q是0至5的整数，n是1至3的整数，m是0至2的整数，p是0或1，但是 n + m可以至多为3，其中苯环可以携带另外的稠合苯环，或者可以被卤素，硝基，烷基或烷氧基取代，并且K +是阳离子。 水不溶性染料可用于染色聚酰胺纺织材料和用于着色皮革，油漆和纸以及粘胶，聚酰胺，纤维素醚和纤维素酯纺丝组合物，水溶性染料可用于染色皮革，羊毛 ，丝，酪蛋白，聚酰胺和聚氨酯纤维和毛皮; 染料具有良好的覆盖力和牢度。

公开(公告)号：US4086223A

公开(公告)日：1978-04-25

申请号：US767131

申请日：1977-02-09

Applicant: Eginhard Steiner ,  Fabio Beffa

Inventor： Eginhard Steiner ,  Fabio Beffa

IPC: C09B45/00 ,  C09B45/16 ,  C09B45/26 ,  C09B62/08 ,  C09B62/24

CPC classification number: C09B45/00

Abstract: Asymmetrical 1:2-chromium complex dyestuffs having excellent fastness to light, rubbing, washing, alkali, milling sea water, decatizing and perspiration and having the formula ##STR1## WHEREIN A.sub.1 represents o-phenylene unsubstituted or substituted by halogen, nitro, lower alkyl, lower alkylsulphonyl, phenylsulphonyl, --SO.sub.3.sup.- M.sup.+ or ##STR2## wherein R.sub.1 represents hydrogen, lower alkyl and R.sub.2 represents hydrogen, lower alkyl or phenyl, or by a cellulosic fiber-reactive group, or o-naphthylene unsubstituted or substituted by --SO.sub.3.sup.- M.sup.+,A.sub.2 represents unsubstituted o-phenylene or o-naphthylene unsubstituted or substituted by hydroxyl or --SO.sub.3.sup.- M.sup.+, andA.sub.3 represents o-phenylene unsubstituted or substituted by halogen, nitro, lower alkyl, lower alkoxy, lower alkylsulphonyl, phenylsulphonyl, --SO.sub.3.sup.- M.sup.+ --or ##STR3## wherein R.sub.3 and R.sub.4 independently of each other represent hydrogen or lower alkyl, or o-naphthylene unsubstituted or substituted by nitro, --SO.sub.3.sup.- M.sup.+ or bothB represents 1,2-naphthylene unsubstituted or substituted by halogen, phenylamino, --COO.sup.- M.sup.+, --SO.sub.3.sup.- M.sup.+, N-lower-alkyl-sulphamoyl or N,N-di-lower-alkylsulphamoyl; 4-(1-phenyl-3-methyl-pyrazol-5-onyl), 4-(halogenphenyl-, 1-lower-alkylsulphonylphenyl- or 1-SO.sub.3.sup.- M.sup.+ -phenyl-3-methyl-pyrazol-5-onyl) or 4-(1-SO.sub.3.sup.- M.sup.+ -phenyl-3-methyl-5-amino-pyrazolyl),M.sup.+ represents a colorless cation, andn represents an integer from 1 to 3,And wherein ring G is unsubstituted or substituted by halogen, --SO.sub.3.sup.- M.sup.+ - or sulphamoyl,X.sub.1 represents --O--,X.sub.2 represents --O-- or --COO--,X.sub.3 represents --O--, --COO-- or ##STR4## wherein R denotes lower alkyl or phenyl X.sub.4 represents --O--, --NH-- or ##STR5## wherein R has the meaning given in the definition of X.sub.3, and ##STR6## being linked to A.sub.1, A.sub.3 or both and the dyestuff molecule having, in all, from 0 to 3 --SO.sub.3.sup.- M.sup.+ groups, andwherein more than one ##STR7## group is present it is not bound to the same ring A.sub.1, A.sub.3 or B and when A.sub.1, A.sub.3 or B are unsubstituted or substituted o-phenylene, the ##STR8## group is bound thereto in the para position with respect to the substituent participating in the chromium complex.

公开(公告)号：US4085097A

公开(公告)日：1978-04-18

申请号：US647268

申请日：1976-01-07

Applicant: Fabio Beffa ,  Arthur Buhler ,  Peter Donath ,  Hans Ulrich Schutz ,  Gerhard Back

Inventor： Fabio Beffa ,  Arthur Buhler ,  Peter Donath ,  Hans Ulrich Schutz ,  Gerhard Back

IPC: C09B45/01 ,  C09B45/16 ,  C09B45/06 ,  C09B45/34 ,  C09B45/48 ,  C09B55/00

CPC classification number: C09B45/01

Abstract: A process is described for the manufacture of chromium complexes of metallizable dyes in the form of solid dyestuff powders of low salt to salt-free content, or of concentrated solutions of low salt or salt-free content in which a metallizable dye, or a mixture of metallizable dyes, in an organic solvent which is immiscible or sparingly miscible with water, or reacted with a chromium compound, in the course of which any water which is liberated is removed by azeotropic distillation, and the resulting chromium complex, provided it is a 1:1 complex, is then optionally reacted in the presence of a base with a further mol of a metallizable dye, or of a colorless, complexforming compound, then isolated from undissolved constituents, and the resulting dye solution of low salt or salt-free content is optionally concentrated or evaporated to dryness, whereby it is possible the manufacture of 1:1 or 1:2 chromium complexes without the handicap of effluent pollution, and to isolate the dyes without using salt. The dyes obtained are especially suitable for the manufacture of concentrated solutions without the necessity of having to increase the solubility by means of extenders.

Abstract translation: 描述了一种制备以低盐至无盐含量的固体染料粉末形式的可镀金属染料的铬络合物的方法，或其中可镀金属染料或混合物的低浓度或无盐含量的浓缩溶液 的可镀金属染料，在与水不混溶或微量混溶的有机溶剂中或与铬化合物反应，在此过程中，通过共沸蒸馏除去任何释放的水，以及所得的铬络合物，只要它是 然后任选地在碱的存在下与另外的摩尔的可镀金属染料或无色的复合形成化合物反应，然后从未溶解的组分中分离出所得到的低盐或无盐的染料溶液 含量可选地浓缩或蒸发至干，由此可能制造1：1或1：2铬配合物，而不会造成污染物的污染，并将染料与 使用盐。 所得到的染料特别适用于制备浓缩溶液，而不需要通过增量剂增加溶解度。

公开(公告)号：US3978037A

公开(公告)日：1976-08-31

申请号：US529670

申请日：1974-12-04

Applicant: Fabio Beffa ,  Alfred Fasciati

Inventor： Fabio Beffa ,  Alfred Fasciati

IPC: C09B45/48 ,  C09B45/16 ,  C09B55/00 ,  C09B56/02 ,  C09B45/26 ,  D06P3/24

CPC classification number: C09B55/001 ,  C09B45/16

Abstract: 1:2 Chromium complex dyes of the formula ##SPC1##Wherein A represents the radical of a diazo component, B represents the radical of a coupling component, --X-- is --O--, --NH--, ##EQU1## --Y-- is --O-- or --COO--, R.sub.1 is hydrogen or alkyl and R.sub.2 is a radical of the benzene or naphthalene class which is substituted by a carboxy or a sulpho group, K.sup.+ represents a cation, and wherein the benzene ring b can carry a further fused benzene ring or can be substituted by halogen, nitro, low molecular alkyl or alkoxy as well as arylazo groups, and the radicals A and B are devoid of --SO.sub.3 H and --COOH groups. These dyes are useful for dyeing and printing natural and synthetic polyamides to produce level dyeings of good fastness, especially fastness to pulling, water and perspiration.

Abstract translation: 1：2结构式的铬络合物染料，其中A表示重氮组分的基团，B表示偶合组分的基团，-X-是-O - ， - NH - ， - N-烷基，-N-芳烷基或 N-芳基，-OR-是-O-或-COO-，R1是氢或烷基，R2是被羧基或磺基取代的苯或萘类的基团，K + >表示阳离子，其中苯环b可以携带另外的稠合苯环或可以被卤素，硝基，低分子烷基或烷氧基以及芳基偶氮基取代，基团A和B不含-SO 3 H， -COOH基团。 这些染料可用于染色和印刷天然和合成聚酰胺以产生良好牢度的水平染色，特别是拉伸，水和汗水的牢度。

公开(公告)号：US3970615A

公开(公告)日：1976-07-20

申请号：US536059

申请日：1974-12-24

Applicant: Hans Ulrich Schutz ,  Gerhard Back ,  Fabio Beffa

Inventor： Hans Ulrich Schutz ,  Gerhard Back ,  Fabio Beffa

IPC: C09B45/16 ,  C09B45/06 ,  C09B45/48 ,  D06P3/24

CPC classification number: C09B45/16

Abstract: Chromium complex dyes of the formula ##SPC1##Wherein one of the symbols X.sub.1, X.sub.2 and X.sub.3 is hydrogen and each of the others is hydrogen, a halogen atom, a nitro group, a methyl or a methoxy group, R is a phenyl radical which is optionally substituted by halogen, low molecular alkoxy, alkyl or nitro and Me.sup.+ is a cation are disclosed; said dyes being useful in dyeing synthetic and natural polyamides to produce dyeings which are level and have good fastness to light, washing, fulling, decatizing and carbonizing.

Abstract translation: 符号为X1，X2和X3的式的铬络合物染料是氢，并且其中每一个都是氢，卤素原子，硝基，甲基或甲氧基，R是任选被取代的苯基 通过卤素，低分子量烷氧基，烷基或硝基和Me +是阳离子; 所述染料可用于染色合成和天然聚酰胺以产生水平且具有良好的耐光牢度，洗涤，充满，脱脂和碳化的染色。

公开(公告)号：US4502865A

公开(公告)日：1985-03-05

申请号：US557715

申请日：1983-12-02

Applicant: Gerhard Back ,  Fabio Beffa ,  Hans-Ulrich Sch/u/ tz

Inventor： Gerhard Back ,  Fabio Beffa ,  Hans-Ulrich Sch/u/ tz

IPC: C09B62/032 ,  C09B62/477 ,  D06P1/38 ,  D06P5/28 ,  C09B45/16 ,  D06P3/14

CPC classification number: D06P5/006 ,  C09B62/032 ,  C09B62/477 ,  D06P1/38 ,  Y10S8/917

Abstract: Novel chromium complex dyes are disclosed which have the formula ##STR1## wherein S.sub.1 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical, an acylamino or arylazo group,S.sub.2 represents a hydrogen or halogen atom, a nitro group, a sulpho group, an alkyl or alkoxy radical,S.sub.3 represents a hydrogen atom, a nitro group or a halogen atom,P is 1 or 2,R represents a fluorochloropyrimidyl or fluorotriazinyl radical, a chloroacetyl, bromoacetyl, .alpha.-chloro- or .alpha.-bromoacryloyl radical or an .alpha.,.beta.-dichloro- or .alpha.,.beta.-dibromopropionyl radical, andK.sup..sym. represents a cation.

Abstract translation: 公开了新型的铬络合物染料，其具有式“IMAGE”，其中S1表示氢或卤素原子，硝基，磺基，烷基或烷氧基，酰氨基或芳基偶氮基，S2表示氢或卤素原子， 硝基，磺基，烷基或烷氧基，S3表示氢原子，硝基或卤原子，P为1或2，R表示氟氯嘧啶基或氟三嗪基，氯乙酰基，溴乙酰基，α-氯代 - 或α-溴丙烯酰基或α，β-二氯或α，β-二溴丙酰基，K（+）表示阳离子。