Thermally stable polycarbonates, thermoplastic compositions thereof, and articles formed therefrom
    22.
    发明授权
    Thermally stable polycarbonates, thermoplastic compositions thereof, and articles formed therefrom 有权
    热稳定的聚碳酸酯,其热塑性组合物和由其形成的制品

    公开(公告)号:US07531615B2

    公开(公告)日:2009-05-12

    申请号:US11324949

    申请日:2006-01-04

    Abstract: A polycarbonate such as aliphatic/aromatic polycarbonate comprises repeating structural carbonate units of the formula (H-1): in which Rh is a radical having the formula (H-2): wherein each of R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23, R24, R25, R26, R27, and R28 is independently a hydrogen, a C1-C6 alkyl group, or a halogen substituted C1-C6 alkyl group. The polycarbonate, and a thermoplastic composition thereof, have improved thermal stability, cost-effectiveness, and exhibit improved manufacturability such as, for example, minimum cyclic carbonate formation and minimum amine acceptor requirement.

    Abstract translation: 聚碳酸酯如脂肪族/芳香族聚碳酸酯包括重复式(H-1)的结构碳酸酯单元:其中Rh是具有式(H-2)的基团:其中R11,R12,R13,R14,R15, R16,R17,R18,R19,R20,R21,R22,R23,R24,R25,R26,R27和R28独立地为氢,C1-C6烷基或卤素取代的C1-C6烷基。 聚碳酸酯及其热塑性组合物具有改进的热稳定性,成本效益,并且显示出改进的可制造性,例如最小的环状碳酸酯形成和最小的胺受体要求。

    Method for purifying 1,1-bis(4′-hydroxy-3′-methylphenyl)cyclohexane and methods of producing polycarbonates therefrom
    23.
    发明授权
    Method for purifying 1,1-bis(4′-hydroxy-3′-methylphenyl)cyclohexane and methods of producing polycarbonates therefrom 失效
    纯化1,1-双(4'-羟基-3'-甲基苯基)环己烷的方法及其制备聚碳酸酯的方法

    公开(公告)号:US06646097B1

    公开(公告)日:2003-11-11

    申请号:US10065573

    申请日:2002-10-31

    Abstract: A method for purifying 1,1-bis(4′-hydroxy-3′-methylphenyl)cyclohexane comprises dissolving said 1,1-bis(4′-hydroxy-3′-methylphenyl)cyclohexane in a first solvent consisting essentially of an alcohol to form a first solution; filtering said first solution; adding a second solvent consisting essentially of water to the filtered first solution to form a second solution, wherein said second solution comprises about 40 parts to about 95 parts of the first solvent per 100 parts of the combined weight of the first and second solvents; crystallizing said 1,1-bis(4′-hydroxy-3′-methylphenyl) cyclohexane from said second solution to form a first crystalline product; dissolving said first crystalline product in a third solvent to form a third solution, wherein the third solvent comprises an aromatic compound; and crystallizing said 1,1-bis(4′-hydroxy-3′-methylphenyl)cyclohexane from said third solution to produce a second crystalline product.

    Abstract translation: 纯化1,1-双(4'-羟基-3'-甲基苯基)环己烷的方法包括将所述1,1-双(4'-羟基-3'-甲基苯基)环己烷溶解在基本上由醇组成的第一溶剂中 形成第一个解决方案; 过滤所述第一溶液; 将基本上由水组成的第二溶剂加入到过滤的第一溶液中以形成第二溶液,其中所述第二溶液每100份第一和第二溶剂的组合重量包含约40份至约95份的第一溶剂; 从所述第二溶液中结晶所述1,1-双(4'-羟基-3'-甲基苯基)环己烷以形成第一结晶产物; 将所述第一结晶产物溶解在第三溶剂中以形成第三溶液,其中所述第三溶剂包含芳族化合物; 并从所述第三溶液中结晶出所述1,1-双(4'-羟基-3'-甲基苯基)环己烷以产生第二结晶产物。

    Bisphosphine oxide monomers
    24.
    发明授权
    Bisphosphine oxide monomers 失效
    二氧化膦氧化物单体

    公开(公告)号:US5414134A

    公开(公告)日:1995-05-09

    申请号:US170143

    申请日:1993-12-20

    Applicant: Gary C. Davis

    Inventor: Gary C. Davis

    CPC classification number: C07F9/5329 C08G64/083

    Abstract: Bisphosphine oxide monomers and homologs thereof may be incorporated into polycarbonates in order to obtain a flame retardant polymer. More particularly, bis[2,5-(diphenylphosphine oxide)]-1,4-hydroquinone and homologs thereof may be used to prepare flame retardant polycarbonates that retain high glass transition temperature and high impact resistances.

    Abstract translation: 可将双氧化膦单体及其同系物引入聚碳酸酯中以获得阻燃聚合物。 更具体地,双[2,5-(二苯基氧化膦)] -1,4-氢醌及其同系物可用于制备保持高玻璃化转变温度和高耐冲击性的阻燃聚碳酸酯。

    Phosphine oxide substituted polycarbonate
    25.
    发明授权
    Phosphine oxide substituted polycarbonate 失效
    氧化膦取代聚碳酸酯

    公开(公告)号:US5194564A

    公开(公告)日:1993-03-16

    申请号:US900355

    申请日:1992-06-18

    CPC classification number: C08G64/083

    Abstract: Novel flame retardant polycarbonates are prepared that maintain a T.sub.g and an impact strength similar to that of non-modified polycarbonates. More particular, phosphine oxide containing polycarbonates are prepared that demonstrate improved flame retardancy and the retention of impact strength and glass transition temperature.

    Abstract translation: 制备新型阻燃聚碳酸酯,其保持与未改性聚碳酸酯类似的Tg和冲击强度。 更具体地,制备含氧化膦的聚碳酸酯,其显示出改进的阻燃性和冲击强度和玻璃化转变温度的保持。

    Storage stable aryl nitrone compositions
    28.
    发明授权
    Storage stable aryl nitrone compositions 失效
    储存稳定的芳基硝酮组合物

    公开(公告)号:US4661433A

    公开(公告)日:1987-04-28

    申请号:US687681

    申请日:1984-12-31

    Applicant: Gary C. Davis

    Inventor: Gary C. Davis

    CPC classification number: C07C291/02 G03F7/091

    Abstract: Aryl nitrones, of the type used in contrast enhancement photolithography techniques, are stabilized by adding thereto a drying agent such as molecular sieve, silica gel or an alkylalkoxysilane. The resulting compositions are substantially storage stable.

    Abstract translation: 用于对比度增强光刻技术的类型的芳基硝酮通过向其中加入干燥剂如分子筛,硅胶或烷基烷氧基硅烷来稳定化。 所得组合物基本上储存稳定。

    Photopatternable dielectric compositions, method for making and use
    30.
    发明授权
    Photopatternable dielectric compositions, method for making and use 失效
    光电图案介电组合物,制造和使用方法

    公开(公告)号:US4587204A

    公开(公告)日:1986-05-06

    申请号:US695601

    申请日:1985-01-28

    Applicant: Gary C. Davis

    Inventor: Gary C. Davis

    CPC classification number: C08L79/08 C08G73/106 G03F7/0757

    Abstract: There is provided a photosensitive modified silicone-aromatic polyamide acid convertible to a patterned silicone-polyimide. A silicone-polyamide acid is modified with an isocyanatoalkylacrylate to produce a silicone-aromatic polyamide acid having acrylate alkylamide groups attached to the silicone-aromatic polyamide acid backbone by nitrogen-nuclear bound carbon linkages.

    Abstract translation: 提供了可转变成图案化的硅氧烷聚酰亚胺的感光改性的有机硅 - 芳族聚酰胺酸。 用异氰酸酯基烷基丙烯酸酯改性硅氧烷聚酰胺酸,以通过氮 - 核结合碳键制备具有连接到硅氧烷 - 芳族聚酰胺酸骨架上的丙烯酸酯烷基酰胺基团的硅氧烷 - 芳族聚酰胺酸。

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