Process for separating acid gases from gaseous mixtures utilizing composite membranes formed from salt-polymer blends
    24.
    发明授权
    Process for separating acid gases from gaseous mixtures utilizing composite membranes formed from salt-polymer blends 失效
    使用由盐 - 聚合物共混物形成的复合膜分离酸性气体与气体混合物的方法

    公开(公告)号:US06315968B1

    公开(公告)日:2001-11-13

    申请号:US08374462

    申请日:1995-01-18

    IPC分类号: B01J800

    摘要: The present invention is a process for separating acid gas from gaseous mixtures containing acid gas and at least one non-acid gas. The process comprises bringing the gas stream into contact with a multilayer composite membrane comprising a non-selective polymeric support layer and a separating layer comprising a blend of a water soluble polymer and one-half equivalent or more of an acid gas reactive salt based upon the repeating unit of the water soluble polymer, the acid gas reactive salt which is formed from a monovalent cation and an anion for which the pKa of the conjugate acid is greater than 3, wherein the multilayer composite membrane separates the acid gas from the gaseous mixture by selectively permeating the acid gas.

    摘要翻译: 本发明是从含有酸性气体和至少一种非酸性气体的气态混合物中分离酸性气体的方法。 该方法包括使气流与包含非选择性聚合物支持层的多层复合膜接触,以及包含水溶性聚合物和半反式酸反应性盐的一半等于或者更多的基于 水溶性聚合物的重复单元,由单价阳离子形成的酸性气体反应性盐和共轭酸的pKa大于3的阴离子,其中多层复合膜通过以下方式将酸性气体与气体混合物分离: 选择性渗透酸性气体。