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公开(公告)号：US6130178A
公开(公告)日：2000-10-10
申请号：US286158
申请日：1999-04-05
IPC分类号： C03C10/16
CPC分类号： C03C10/16
摘要： The present invention is directed at a glass-ceramic having high strength and toughness and containing miserite as a predominant crystal phase. The glass-ceramic has a composition calculated in terms of a weight percent on the oxide basis comprising 40-68% SiO.sub.2, 12-35% CaO, 8-20% CaF.sub.2, 4-10.5% K.sub.2 O, 0-5% Al.sub.2 O.sub.3, 0-5% B.sub.2 O.sub.3, 0-15% P.sub.2 O.sub.5, 0-4% R.sub.2 O.sub.3, wherein R represents Y.sup.3+ and rare earth metals in the lanthanide series, and 0-5% of optional constituents selected from the group consisting of MgO, SrO, BaO, Na.sub.2 O, Nb.sub.2 O.sub.5, ZrO.sub.2, and ZnO, and 0-10% of optional constituents selected from the group consisting of Nb.sub.2 O.sub.5 and TiO.sub.2 and 0-2% Li.sub.2 O as an optional constituent. The glass-ceramic may contain secondary phases of cristobalite (SiO.sub.2), fluorite (CaF.sub.2), xonotlite (Ca.sub.6 Si.sub.6 O.sub.17 F.sub.2), and fluorapatite (Ca.sub.5 (PO.sub.4).sub.3 F), and small amounts of other calcium silicate phases such as wollastonite (CaSiO.sub.3).
摘要翻译： 本发明涉及具有高强度和韧性的玻璃陶瓷，并且含有苦ite石作为主要结晶相。 玻璃陶瓷具有以氧化物为基准的重量百分比计算的组成，包括40-68％SiO 2，12-35％CaO，8-20％CaF 2，4-10.5％K 2 O，0-5％Al 2 O 3，0 -5％B2O3,0-15％P2O5,0-4％R2O3，其中R代表Y3 +，镧系中的稀土金属和0-5％选自MgO，SrO，BaO， Na 2 O，Nb 2 O 5，ZrO 2和ZnO，以及选自Nb 2 O 5和TiO 2以及0-2％Li 2 O作为任选成分的0-10％的任选成分。 玻璃陶瓷可以含有方英石（SiO 2），萤石（CaF 2），黑云母（Ca 6 Si 6 O 17 F 2）和氟磷灰石（Ca 5（PO 4）3 F））和少量其它硅酸钙相如硅灰石（CaSiO 3）的次相。
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公开(公告)号：US6087280A
公开(公告)日：2000-07-11
申请号：US785336
申请日：1997-01-16
IPC分类号： C03B32/02 , C03C10/00 , C03C10/12 , G02B6/00 , G02B6/02 , G02B6/10 , G02B6/12 , G02B6/122 , G02B6/28
CPC分类号： G02B6/0218 , C03C10/0027 , G02B6/10 , G02B6/2835
摘要： An athermal optical device and a method for producing the device, such as an athermal optical fiber reflective grating, are described. The athermal optical fiber reflective grating device comprises a negative expansion substrate, an optical fiber mounted on the substrate surface, and a grating defined in the optical fiber. The method for producing the athermal optical fiber reflective grating device comprises providing a negative expansion substrate, mounting an optical fiber with at least one reflective grating defined therein onto the substrate upper surface, and affixing the optical fiber to the substrate at at least two spaced apart locations.
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公开(公告)号：US5910459A
公开(公告)日：1999-06-08
申请号：US742611
申请日：1996-10-28
CPC分类号： C03C10/0045 , Y10S977/811
摘要： The glass-ceramic material of the present invention has the hexagonal sheet structure of hexacelsian as its primary crystal phase and exhibits x-ray diffraction patterns indicative of hexacelsian, said glass-ceramic material has a stabilized thermal expansion and an overall weight percent composition comprising: 35-55% SiO.sub.2, 5-25% Al.sub.2 O.sub.3, 5-25% MgO, 5-35% BaO, 6-14% TiO.sub.2, 0-10% ZnO, and 0-8% ZrO.sub.2.
摘要翻译： 本发明的玻璃 - 陶瓷材料具有六面体结构的六面体作为其主要结晶相，并且表现出表示六面体的x射线衍射图案，所述玻璃 - 陶瓷材料具有稳定的热膨胀和总体重量百分比组成，包括： 35-55％SiO 2，5-25％Al 2 O 3，5-25％MgO，5-35％BaO，6-14％TiO 2，0-10％ZnO和0-8％ZrO 2。
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公开(公告)号：US5744208A
公开(公告)日：1998-04-28
申请号：US265192
申请日：1994-06-24
申请人： George H. Beall , Jeffrey T. Kohli
发明人： George H. Beall , Jeffrey T. Kohli
CPC分类号： C03C10/00 , C03C10/0009 , C03C3/087 , C03C3/097 , G11B5/7315 , Y10S428/90 , Y10T428/21
摘要： This invention is directed at the makings of glass-ceramic which is uniquely suited for use as a disc substrate for utilization in a magnetic memory storage device. The glass ceramic material exhibits a crystal phase assemblage comprised predominately of a mixture of lithium disilicate and tridymite which are uniformly interspersed with a residual glass phase and form an interlocked microstructure with the glass. The composition consists essentially, expressed in terms of weight percent on the oxide basis, of 75-95% SiO.sub.2, 3-15% Li.sub.2 O, 0-6% Al.sub.2 O.sub.3, and 0-6% K.sub.2 O. The nucleating agent for this glass-ceramic is selected from the group consisting of 0-0.1% Pd and 0-5% P.sub.2 O.sub.5 ; however if Pd is absent the P.sub.2 O.sub.5 amount is at least 0.5% and if P.sub.2 O.sub.5 is absent then the Pd amount is at least 0.005%. Additionally, up to 15% of optional ingredients may be added, including, B.sub.2 O.sub.3, Na.sub.2 O, ZnO, MgO, CaO, SrO, ZrO.sub.2, TiO.sub.2, F, Sb.sub.2 O.sub.3, As.sub.2 O.sub.3, PbO and BaO.
摘要翻译： 本发明涉及玻璃陶瓷的特征，其特别适用于磁盘存储装置中的盘基片。 玻璃陶瓷材料表现出主要由二硅酸锂和鳞石英的混合物组成的晶相组合物，其均匀地散布有残留的玻璃相并与玻璃形成互锁的微观结构。 该组合物基本上以75-95％SiO 2，3-15％Li 2 O，0-6％Al 2 O 3和0-6％K 2 O为基础，以氧化物为基准以重量百分比表示。 该玻璃陶瓷的成核剂选自0-0.1％Pd和0-5％P 2 O 5; 然而，如果Pd不存在，则P 2 O 5量为至少0.5％，如果不存在P 2 O 5，则Pd量为至少0.005％。 另外，可添加高达15％的任选成分，包括B2O3，Na2O，ZnO，MgO，CaO，SrO，ZrO2，TiO2，F，Sb2O3，As2O3，PbO和BaO。
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公开(公告)号：US5492869A
公开(公告)日：1996-02-20
申请号：US387954
申请日：1995-02-13
CPC分类号： C03C4/02 , C03C10/0027
摘要： An opaque glass-ceramic having a beta-spodumene solid solution as its primary crystal phase, and a method of controlling color in the glass-ceramic. The glass-ceramic is produced from a Li.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 precursor glass containing 3-6% TiO.sub.2 +ZrO.sub.2 as a nucleating agent and having colorants controlled at levels of 1500-4,000 ppm Fe.sub.2 O.sub.3, 1500-4000 ppm CeO.sub.2 and 50-500 ppm V.sub.2 O.sub.5.
摘要翻译： 具有β-锂辉石固溶体作为其主晶相的不透明玻璃陶瓷以及控制玻璃陶瓷中颜色的方法。 玻璃陶瓷由含有3-6％TiO 2 + ZrO 2作为成核剂的Li2O-Al2O3-SiO2前体玻璃制备，并具有控制在1500-4,000ppm Fe 2 O 3，1500-4000ppm CeO 2和50-500ppm的着色剂 V2O5。
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公开(公告)号：US5173453A
公开(公告)日：1992-12-22
申请号：US773455
申请日：1991-10-09
申请人： George H. Beall , Linda R. Pinckney
发明人： George H. Beall , Linda R. Pinckney
CPC分类号： C03C10/0027 , C03C10/0036
摘要： This invention is directed toward of a glass-ceramic article consisting essentially, expressed in terms of weight percent on the oxide basis, of about 64-70% SiO.sub.2, 18-22% Al.sub.2 O.sub.3, 3.3-4% Li.sub.2 O, 2-5% ZnO, 0-2% MgO, 1.5-3.5% ZrO.sub.2, 0.5-2.5% TiO.sub.2, 3.5-4.5% ZrO.sub.2 +TiO.sub.2, 0.5-1.5% As.sub.2 O.sub.5 and 0-0.5% SnO.sub.2. The glass-ceramic article disclosed herein, is comprised of adjacent areas which exhibit visible transmissions ranging from transparent-to-opaque. The transparent areas are clear, transparent and essentially colorless and contain stuffed .beta.-quartz as essentially the sole crystal phase. On the other hand, the translucent-to-opaque areas contain .beta.-spodumene as the predominant crystal phase with a minor amounts of gahnite crystals resulting from the thermal transformation of said stuffed .beta.-quartz. This gahnite phase is present in an amount sufficient to compensate for the transformation of said stuffed .beta.-quartz to .beta.-spodumene, resulting in a dimensional change, expressed in terms of density change, of essentially zero.
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公开(公告)号：US4874724A
公开(公告)日：1989-10-17
申请号：US258673
申请日：1988-10-17
CPC分类号： C03C10/00
摘要： This invention is directed to the production of glass-ceramic articles exhibiting an apparent annealing point in excess of 400.degree. C. and excellent resistance to moisture attack, the articles consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-25 ZnO 35-50 Na.sub.2 O 0-15 Al.sub.2 O.sub.3 0.75-6 K.sub.2 O 0-10 P.sub.2 O.sub.5 29-37. Li.sub.2 O + Na.sub.2 O + K.sub.2 O 5-25 ______________________________________
摘要翻译： 本发明涉及玻璃陶瓷制品的制造，该玻璃陶瓷制品具有超过400℃的表观退火点和优异的耐水分侵蚀性，该制品基本上以摩尔百分比计：-Li2O 5-25 ZnO 35- 50 -Na2O 0-15 Al2O3 0.75-6-K2O 0-10 P2O5 29-37。 -Li2O + Na2O + K2O 5-25 -
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公开(公告)号：US4666867A
公开(公告)日：1987-05-19
申请号：US897514
申请日：1986-08-18
申请人： George H. Beall , John F. MacDowell
发明人： George H. Beall , John F. MacDowell
IPC分类号： C03C3/062 , C03C3/064 , C03C3/066 , C03C3/089 , C03C3/091 , C03C3/093 , C03C3/097 , C03C4/02 , C03C4/16 , C03C10/00 , C03C10/02 , C03C11/00 , C03C10/04
CPC分类号： C03C3/064 , C03C10/0054 , C03C11/007 , C03C3/066 , C03C3/091 , C03C3/093 , C03C4/16
摘要： The present invention is concerned with the preparation of glass microfoams and gas-ceramics having compositions selected from the systems of SiO.sub.2 --Al.sub.2 O.sub.3 --B.sub.2 O.sub.3 --RO--R.sub.2 O, SiO.sub.2 --Al.sub.2 O.sub.3 (B.sub.2 O.sub.3)--P.sub.2 O.sub.5 --Li.sub.2 O--[ZrO.sub.2 (TiO.sub.2)], and SiO.sub.2 --P.sub.2 O.sub.5 --B.sub.2 O.sub.3 --[RO], wherein RO is selected from the group of MgO, CaO, SrO, BaO, and ZnO, and R.sub.2 O is selected from the group of alkali metal oxides. The foams comprise hydrogen-containing cells produced through the inclusion in the batch of a hydrogen-generating agent selected from the group of ammonium salts and/or a combination of amines and/or carbohydrates and/or hydrocarbons with phosphates.
摘要翻译： 本发明涉及具有选自SiO 2 -Al 2 O 3 -BO 2 -R 2 O 2，SiO 2 -Al 2 O 3（B 2 O 3）-P 2 O 5 -LiO 2 - [ZrO 2（TiO 2）]的体系的组成的玻璃微泡和气体陶瓷的制备， 和SiO 2 -P 2 O 5 -B 2 O 3 - [RO]，其中RO选自MgO，CaO，SrO，BaO和ZnO，R2O选自碱金属氧化物。 泡沫包括通过在批次中包含选自铵盐和/或胺和/或碳水化合物和/或与磷酸盐的烃的组合的氢气发生剂而产生的含氢电池。
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公开(公告)号：US4582760A
公开(公告)日：1986-04-15
申请号：US735660
申请日：1985-05-20
CPC分类号： C03C8/12
摘要： The present invention is concerned with the preparation of glazes which are especially suitable for application to glass-ceramic articles containing potassium fluorrichterite as substantially the sole crystal phase. The glazes consist essentially, expressed in terms of weight percent on the oxide basis, ofSiO.sub.2 :46-50Al.sub.2 O.sub.3 :5-8ZrO.sub.2 :0.3-1Li.sub.2 O:1-2Na.sub.2 O:2-3.5K.sub.2 O:1-2CaO:1-4ZnO:2-6SrO:2-6B.sub.2 O.sub.3 :9-11PbO:20-25.
摘要翻译： 本发明涉及特别适用于玻璃陶瓷制品的釉料的制备，所述玻璃陶瓷制品含有基本上唯一的结晶相的氟化钾。 釉料基本上以氧化物的重量百分数表示，SiO 2：46-50 Al 2 O 3：5-8 ZrO 2：0.3-1 Li 2 O：1-2Na 2 O：2-3.5K 2 O：1-2 CaO：1 -4 ZnO：2-6 SrO：2-6 B2O3：9-11 PbO：20-25。
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公开(公告)号：US4519828A
公开(公告)日：1985-05-28
申请号：US479681
申请日：1983-03-28
CPC分类号： C03C10/0054 , C03C3/093 , C03C3/108
摘要： This invention is concerned with the production of substantially transparent glass-ceramic articles containing mullite as the predominant crystal phase which can be prepared by crystallizing in situ precursor glasses capable of being melted at temperatures no higher than 1650.degree. C. The inventive articles consist essentially, in weight percent, of 10-70% SiO.sub.2, 7-40% B.sub.2 O.sub.3, 14-50% Al.sub.2 O.sub.3, 0-35% RO, wherein RO consists of at least one member of the group in the indicated proportions of 0-15% MgO, 0-20% CaO, 0-30% SrO, 0-30% BaO, and 0-30% PbO, and 0-30% R.sub.2 O, wherein R.sub.2 O consists of at least one member of the group in the indicated proportions of 0-10% Li.sub.2 O, 0-15% Na.sub.2 O, 0-25% K.sub.2 O, 0-25% Rb.sub.2 O, and 0-25% Cs.sub.2 O, the mole ratio Al.sub.2 O.sub.3 :RO+R.sub.2 O>1.3. Where 0.01-1% Cr.sub.2 O.sub.3 is included in the composition, the glass-ceramic will exhibit broad absorption over the visible region of the radiation spectrum, strong fluorescence in the red and near infrared portions of the spectrum where exposed to ultraviolet and/or visible radiation, and relatively little overlap of the absorption and fluorescent spectra.
摘要翻译： 本发明涉及生产基本上透明的含有莫来石作为主要结晶相的玻璃陶瓷制品，其可以通过使能够在不高于1650℃的温度下熔化的原位前体玻璃结晶来制备。本发明的制品基本上包括， 重量百分比为10-70％SiO 2，7-40％B 2 O 3，14-50％Al 2 O 3，0-35％RO，其中RO由至少一种所述比例的0-15％MgO ，0-20％CaO，0-30％SrO，0-30％BaO和0-30％PbO和0-30％R2O，其中R2O由指定比例为0的至少一种成员组成 -10％Li2O，0-15％Na2O，0-25％K2O，0-25％Rb2O和0-25％Cs2O，摩尔比Al2O3：RO + R2O> 1.3。 在组合物中包含0.01-1％的Cr2O3的情况下，玻璃陶瓷将在辐射光谱的可见区域表现出广泛的吸收，在暴露于紫外线和/或可见光辐射的光谱的红色和近红外部分的强荧光 ，并且吸收和荧光光谱的重叠相对较少。
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