公开(公告)号：US20110226009A1

公开(公告)日：2011-09-22

申请号：US13122765

申请日：2009-10-02

Applicant: Henri Paradowski ,  Sylvain Vovard

Inventor： Henri Paradowski ,  Sylvain Vovard

IPC: F25J1/02

CPC classification number: F25J3/0233 ,  F25J1/0022 ,  F25J1/004 ,  F25J1/0042 ,  F25J1/0045 ,  F25J1/005 ,  F25J1/0072 ,  F25J1/0208 ,  F25J1/0219 ,  F25J1/0265 ,  F25J1/0267 ,  F25J3/0209 ,  F25J3/0257 ,  F25J3/029 ,  F25J2200/02 ,  F25J2200/76 ,  F25J2215/04 ,  F25J2215/30 ,  F25J2220/64 ,  F25J2235/60 ,  F25J2240/30 ,  F25J2270/02 ,  F25J2270/04 ,  F25J2270/14 ,  F25J2270/42

Abstract: This process includes the cooling of an introduction stream (72) inside an upstream heat exchanger (28). It includes the introduction of the cooled introduction stream (76) into a fractionating column (50) and the tapping at the bottom portion of the column (50) of the denitrided stream of hydrocarbons. It also includes the introduction of a stream (106) rich in nitrogen obtained from the head portion of the column (50) into a separation container (60) and the recovery of the head gaseous stream from the separation container (60) in order to form the stream (20) which is rich in helium. The liquid stream (110) is obtained from the bottom of the first separation container (60) is separated into a liquid nitrogen stream (18) and a first reflux stream (114) which is introduced as reflux into the head of the fractionating column (50).

Abstract translation: 该过程包括在上游热交换器（28）内冷却引入流（72）。 其包括将冷却的引入物流（76）引入分馏塔（50）中并且在脱氮烃流的塔（50）的底部排出。 还包括将从塔（50）的头部获得的富含氮气的物流（106）引入分离容器（60）并从分离容器（60）回收头部气流，以便 形成富含氦气的流（20）。 从第一分离容器（60）的底部获得的液体流（110）被分离成液氮流（18）和第一回流流（114），其作为回流引入到分馏塔的头部 50）。

公开(公告)号：US07552598B2

公开(公告)日：2009-06-30

申请号：US11399768

申请日：2006-04-07

Applicant: Henri Paradowski

Inventor： Henri Paradowski

IPC: F25J1/00

CPC classification number: F25J1/0218 ,  F25J1/0022 ,  F25J1/005 ,  F25J1/0052 ,  F25J1/0057 ,  F25J1/0087 ,  F25J1/0092 ,  F25J1/0097 ,  F25J1/0214 ,  F25J1/0217 ,  F25J1/0268 ,  F25J1/0283 ,  F25J1/0288 ,  F25J1/029 ,  F25J2270/16 ,  F25J2290/10

Abstract: In this process, the LNG stream is sub-cooled with a refrigerating fluid in a first heat exchanger. This refrigerating fluid undergoes a closed second refrigeration cycle which is independent of the first cycle. The closed cycle comprises a phase of heating the refrigerating fluid in a second heat exchanger, and a phase of compressing the refrigerating fluid in a compression apparatus to a pressure greater than its critical pressure. It further comprises a phase of cooling the refrigerating fluid originating from the compression apparatus in the second heat exchanger and a phase of dynamically expanding of a proportion of the refrigerating fluid issuing from the second heat exchanger in a turbine. The refrigerating fluid is formed by a mixture of nitrogen-containing fluids.

Abstract translation: 在该过程中，LNG流在第一热交换器中用冷冻流体进行二次冷却。 这种制冷流体经历了与第一循环无关的封闭的第二制冷循环。 闭合循环包括在第二热交换器中加热制冷流体的阶段以及将压缩装置中的冷冻流体压缩至大于其临界压力的压力的相。 其还包括冷却来自第二热交换器中的压缩装置的冷冻流体的相，以及在涡轮机中从第二热交换器发出的一部分冷冻流体动态膨胀的阶段。 制冷流体由含氮流体的混合物形成。

公开(公告)号：US07185514B2

公开(公告)日：2007-03-06

申请号：US10487655

申请日：2002-08-28

Applicant: Henri Paradowski

Inventor： Henri Paradowski

IPC: F25J3/00

CPC classification number: F25J3/0252 ,  F25J3/0219 ,  F25J3/0233 ,  F25J3/0238 ,  F25J2200/70 ,  F25J2205/04 ,  F25J2210/02 ,  F25J2210/04 ,  F25J2210/12 ,  F25J2210/62 ,  F25J2235/60 ,  F25J2245/02 ,  F25J2245/90 ,  F25J2270/02 ,  F25J2270/04 ,  F25J2270/60 ,  F25J2270/904

Abstract: The invention relates to a method for fractionating a gas produced by the pyrolysis of hydrocarbons (1) for the recovery of C2 and higher hydrocarbons, in particular ethylene and ethane, comprising an operation (70) for compressing and drying gas (1) as a result of it passing into a series of compressors (3, 10, 17, 24, 36), an operation (80) for progressively cooling and partially liquefying the gas produced by compression and drying operation (70) as a result of it successively passing into a cryogenic exchanger (62), and a distillation operation (90) in a column (64), and the corresponding installation.According to the invention, cryogenic exchanger (62) is cooled by at least one cooling liquid (400) which is liquid natural gas (LNG).

Abstract translation: 本发明涉及一种用于分馏烃（1）的热分解产生的用于回收C 2 O 3和更高级烃，特别是乙烯和乙烷的气体的方法，其包括用于压缩的操作（70） 和干燥气体（1），其由于其进入一系列压缩机（3,10,17,24,36），用于逐渐冷却和部分液化由压缩和干燥操作产生的气体的操作（80）（70 ），其结果是它连续地进入低温交换器（62）和在列（64）中的蒸馏操作（90）和相应的装置。 根据本发明，低温交换器（62）由至少一种液体天然气（LNG）的冷却液（400）冷却。

公开(公告)号：US06449984B1

公开(公告)日：2002-09-17

申请号：US09968610

申请日：2001-10-02

Applicant: Henri Paradowski

Inventor： Henri Paradowski

IPC: F25J100

CPC classification number: F25J3/029 ,  F25J1/0022 ,  F25J1/004 ,  F25J1/0042 ,  F25J1/0052 ,  F25J1/0057 ,  F25J1/0217 ,  F25J1/0284 ,  F25J1/0292 ,  F25J1/0295 ,  F25J3/0209 ,  F25J3/0233 ,  F25J3/0257 ,  F25J2200/02 ,  F25J2200/06 ,  F25J2200/50 ,  F25J2200/74 ,  F25J2200/78 ,  F25J2215/04 ,  F25J2240/30 ,  F25J2240/40 ,  F25J2260/30 ,  F25J2270/12 ,  F25J2270/66 ,  F25J2280/02 ,  Y02C10/12 ,  Y10S62/927

Abstract: A process for liquefaction of and nitrogen extraction from natural gas, an installation for implementation of the process, and gases obtained by this process. In the process, a first top fraction is cooled and liquefied, separated into a second top fraction which is relatively volatile and which provides gaseous nitrogen, and into a second bottom fraction which is withdrawn. The first bottom fraction is cooled in order to provide liquefied natural gas essentially free nitrogen.

Abstract translation: 从天然气液化和氮气提取的过程，用于实施该方法的装置以及通过该方法获得的气体。 在该方法中，将第一顶部馏分冷却并液化，分离成相对挥发性的第二顶部馏分，并提供气态氮，并进入被抽出的第二塔底馏分。 第一底部馏分被冷却以提供液化天然气基本上是游离氮。

公开(公告)号：US5114450A

公开(公告)日：1992-05-19

申请号：US513558

申请日：1990-04-24

Applicant: Henri Paradowski ,  Michel Leroy

Inventor： Henri Paradowski ,  Michel Leroy

IPC: C10L3/00 ,  C10G5/06 ,  C10G7/00 ,  C10G7/06 ,  C10L3/06 ,  C10L3/12 ,  F25J3/02

CPC classification number: F25J3/0219 ,  C10G5/06 ,  F25J3/0233 ,  F25J3/0242 ,  F25J2200/04 ,  F25J2200/74 ,  F25J2200/78 ,  F25J2205/50 ,  F25J2210/12 ,  F25J2220/64 ,  F25J2270/12 ,  F25J2270/66 ,  F25J2280/30 ,  F25J2290/62

Abstract: A method of and a plant for recovering liquid hydrocarbons in a gaseous batch, the plant comprising a compressor for the gaseous batch, a column for absorbing C5 and heavier hydrocarbons associated with a debutanization column; a column for absorbing C3 and heavier hydrocarbons associated with a de-ethanization column and with a heat exchange system connected to a refrigeration cycle, the plant providing from a gaseous batch issuing from a catalytic cracking unit a debutanized gasoline, a liquefied gas cut (C3 and C4-hydrocarbons) and a gaseous cut (C2 and lighter hydrocarbons) wherein the losses of C3 and higher C-hydrocarbons are much smaller than that occurring with existing plants.

Abstract translation: 一种用于回收气态批料液体烃的方法和装置，该装置包括用于气态批料的压缩机，用于吸收C5和与脱丁烷塔相关的较重烃的塔; 用于吸收与脱乙烷塔相关的C3和较重烃的塔和与制冷循环连接的热交换系统的塔，该设备由气化批料从催化裂化装置发出脱丁烷基化的汽油，液化气馏分（C3 和C 4烃）和气态馏分（C 2和较轻的烃），其中C3和更高级碳氢化合物的损失远小于现有设备发生的损失。

公开(公告)号：US4690702A

公开(公告)日：1987-09-01

申请号：US779811

申请日：1985-09-25

Applicant: Henri Paradowski ,  Joelle H. Castel ,  Herve B. Parfait

Inventor： Henri Paradowski ,  Joelle H. Castel ,  Herve B. Parfait

IPC: C07C7/09 ,  F25J3/02 ,  F23J3/06

CPC classification number: C07C7/09 ,  F25J3/0209 ,  F25J3/0219 ,  F25J3/0233 ,  F25J3/0242 ,  F25J2200/02 ,  F25J2200/74 ,  F25J2200/78 ,  F25J2205/04 ,  F25J2210/12 ,  F25J2240/02 ,  F25J2270/12 ,  F25J2270/60 ,  F25J2270/902 ,  F25J2290/40

Abstract: The invention relates to a method and an apparatus for cryogenic fractionation of a gaseous feed comprising a contact purifying-refrigerating column into the bottom of which is injected a partially condensed gaseous feed, the said column producing in its head portion a residual gas and in its bottom portion a liquid which is injected into a fractionating column producing in its head portion a distillate which is at least partially condensed and injected into the head portion of the column to thus recover in the bottom liquid of this column the heavy compounds contained in the vaporized fraction of the gaseous feed.

Abstract translation: 本发明涉及一种用于气态进料的低温分馏的方法和装置，其包括接触净化 - 制冷塔，其底部注入部分冷凝的气态进料，所述塔在其头部产生残余气体，并在其中 底部是一种液体，其被注入分馏塔中，在其头部产生至少部分冷凝并注入塔的头部的馏出物，从而在该塔的底部液体中回收包含在蒸发的 部分气态进料。

公开(公告)号：US4339253A

公开(公告)日：1982-07-13

申请号：US214698

申请日：1980-12-09

Applicant: Enzo Caetani ,  Henri Paradowski

Inventor： Enzo Caetani ,  Henri Paradowski

IPC: F25J1/00 ,  F25J1/02

CPC classification number: F25J1/0265 ,  F25J1/0022 ,  F25J1/0052 ,  F25J1/0055 ,  F25J1/0214 ,  F25J1/0263 ,  F25J1/0291 ,  F25J1/0292 ,  F25J1/0295 ,  F25J1/0296 ,  F25J2205/90 ,  F25J2220/64

Abstract: A process of and apparatus for liquefying a dry gas with low boiling point in a first circuit through heat exchange with a main refrigerating fluid in a second circuit itself pre-cooled to its at least partial liquefaction through heat exchange with an auxiliary refrigerating fluid in a third circuit, wherein, for a same amount of treated products, the required total compression input power for the refrigerating fluids is reduced by performing in said third circuit an intermediate condensation between the two last compression stages followed by a phase separation, the gaseous phase being compressed to a high pressure in the last compression stage whereas the liquid phase is compressed to a high pressure by a pump and recycled to a cryogenic heat exchanger for cooling the gas initially in the moist state thereby at least partially drying same.

Abstract translation: 一种用于在第一回路中液化低沸点的干燥气体的方法和装置，其通过与第二回路中的主冷冻流体进行热交换，其本身通过与辅助冷冻流体的热交换进行热交换而预冷却至其部分液化 其中，对于相同量的处理产品，通过在所述第三回路中执行两个最后压缩级之间的相位分离之后的中间冷凝，然后进行相分离，所述冷却流体的所需总压缩输入功率被减小 在最后压缩阶段被压缩至高压，而液相通过泵压缩至高压，并再循环至低温热交换器，以最初在潮湿状态下冷却气体，从而至少部分干燥。

公开(公告)号：US4072485A

公开(公告)日：1978-02-07

申请号：US729182

申请日：1976-10-04

Applicant: Charles Becdelievre ,  Victor Kaiser ,  Henri Paradowski

Inventor： Charles Becdelievre ,  Victor Kaiser ,  Henri Paradowski

IPC: F25J3/06

CPC classification number: F25J3/0209 ,  F25J1/0052 ,  F25J1/0092 ,  F25J1/0267 ,  F25J3/0219 ,  F25J3/0233 ,  F25J3/0238 ,  F25J3/061 ,  F25J3/062 ,  F25J3/0635 ,  F25J3/064 ,  F25J2210/12 ,  F25J2215/62 ,  F25J2270/12 ,  F25J2270/60 ,  F25J2270/66 ,  F25J2270/902

Abstract: A method of processing through low temperature heat exchanges natural gases and cracked gases consisting in using a cooling cycle including compressing and then cooling a cycle mixture of gases consisting of C1 hydrocarbons, C2 hydrocarbons and C3 hydrocarbons through outer coolers with attendant total liquefaction of the cycle mixture under pressure; subsequently effecting a sub-cooling of the mixture within heat exchanges in counter-current relation to one expanded part thereof and/or cold returns and rejects of products processed in the cycle and finally expanding said sub-cooled mixture in at least one exchanger where various cooling processes of the treated products are carried out at successive temperature levels.

Abstract translation: 一种通过低温热交换的天然气和裂解气体的处理方法，包括使用冷却循环，包括通过外部冷却器压缩然后冷却由C1烃，C2烃和C3烃组成的气体的循环混合物，伴随着循环的总液化 混合物在压力下; 随后在与其一个扩展部分相反的热交换中进行热交换和/或冷循环中加工的产品的冷回收和排出，并且最终在至少一个交换器中膨胀所述次冷却的混合物，其中各种 处理产物的冷却过程在连续的温度水平下进行。

公开(公告)号：US09506690B2

公开(公告)日：2016-11-29

申请号：US12624587

申请日：2009-11-24

Applicant: Henri Paradowski ,  Sylvain Vovard

Inventor： Henri Paradowski ,  Sylvain Vovard

IPC: F25J1/02 ,  F25J1/00

CPC classification number: F25J1/0092 ,  F25J1/0022 ,  F25J1/0035 ,  F25J1/005 ,  F25J1/0057 ,  F25J1/0072 ,  F25J1/0082 ,  F25J1/0097 ,  F25J1/0204 ,  F25J1/0207 ,  F25J1/0215 ,  F25J1/0217 ,  F25J1/0218 ,  F25J1/025 ,  F25J1/0262 ,  F25J1/0263 ,  F25J1/0265 ,  F25J1/0278 ,  F25J1/0288 ,  F25J1/0294 ,  F25J2210/06 ,  F25J2240/40 ,  F25J2240/70 ,  F25J2270/16 ,  F25J2290/44

Abstract: A process for the production of a subcooled liquefied natural gas stream from a natural gas feed stream. Passing a first natural gas feed stream through a first heat exchanger for precooling by heat exchange with a first stream of gaseous refrigerant produced in a first refrigeration cycle comprising a first dynamic expansion turbine. Passing the precooled feed stream through a second heat exchanger for liquefying by heat exchange with a second stream of gaseous refrigerant produced in a second refrigeration cycle comprising a second dynamic expansion turbine. Passing the liquefied natural gas stream through a third heat exchanger for subcooling the liquefied gas by heat exchange with a third refrigerant stream produced in a third refrigeration cycle comprising a third dynamic expansion turbine separate from the first turbine and the second turbine. An installation includes devices for conveying the natural gas stream, the heat exchangers and the turbines and compression devices cooling the refrigerants for the heat exchangers.

Abstract translation: 一种从天然气进料流生产过冷液化天然气流的方法。 将第一天然气进料流通过第一热交换器进行预冷，通过与包括第一动态膨胀涡轮的第一制冷循环中产生的第一气态制冷剂流进行热交换。 使预冷的进料流通过第二热交换器以通过与在包括第二动态膨胀涡轮机的第二制冷循环中产生的第二气态制冷剂流进行热交换来液化。 使液化的天然气流通过第三热交换器，以通过与在第三制冷循环中产生的第三制冷剂流进行热交换来使液化气体过冷，所述第三制冷剂流包括与第一涡轮机和第二涡轮分离的第三动态膨胀涡轮机。 安装包括用于输送天然气流的装置，热交换器和涡轮机以及冷却用于热交换器的制冷剂的压缩装置。

公开(公告)号：US6105389A

公开(公告)日：2000-08-22

申请号：US113517

申请日：1998-07-10

Applicant: Henri Paradowski ,  Alexandre Rojey

Inventor： Henri Paradowski ,  Alexandre Rojey

IPC: F25J1/00 ,  F25J1/02

CPC classification number: F25J1/0022 ,  F25J1/0052 ,  F25J1/0057 ,  F25J1/0214 ,  F25J1/0262 ,  F25J1/0272 ,  F25J1/0283 ,  F25J1/0292 ,  F25J1/0295 ,  F25J2290/12

Abstract: A method allowing a gaseous mixture such as a natural gas to be liquefied by using a first compressed coolant mixture M.sub.1, at least partially condensed by cooling with the aid of an external coolant fluid, then subcooled, expanded, and vaporized, and a second compressed coolant mixture, cooled with the aid of an external coolant fluid, then cooled by heat exchange with the first coolant mixture M.sub.1 during the first cooling stage (I), after which it is in an at least partially condensed state. The second partially condensed coolant mixture is sent without phase separation to a second cooling stage (II) where it is fully condensed, expanded, and vaporized at at least two pressure levels. The subcooled natural gas is expanded to form the LNG produced.

Abstract translation: 通过使用第一压缩冷却剂混合物M1使气态混合物（例如天然气）液化的方法通过外部冷却剂流体的冷却至少部分冷凝，然后被过冷，膨胀和蒸发，并且第二压缩 冷却剂混合物，借助于外部冷却剂流体冷却，然后在第一冷却阶段（I）期间通过与第一冷却剂混合物M1的热交换而冷却，之后其处于至少部分冷凝状态。 将第二部分冷凝的冷却剂混合物不经相分离送入第二冷却段（II），在第二冷却段（II）中，其在至少两个压力水平下完全冷凝，膨胀和蒸发。 过冷的天然气被膨胀以形成所生产的LNG。