公开(公告)号：US20080193730A1

公开(公告)日：2008-08-14

申请号：US11659882

申请日：2005-08-05

申请人： Takashi Ohkubo ,  Yoshihiro Saida ,  Shuichi Naijo

发明人： Takashi Ohkubo ,  Yoshihiro Saida ,  Shuichi Naijo

IPC分类号： H01B1/12

CPC分类号： H01B1/127 ,  H01B1/128

摘要： The invention relates to an antistatic agent, which comprises a water-soluble electroconductive polymer and a biosurfactant having a hydrophilic site of a molecular weight of 200 to 10,000, excellent in property of preventing film-thinning in chemically amplified resist, and an antistatic film and a coated product obtained by using the antistatic agent.

摘要翻译： 本发明涉及一种抗静电剂，其包含水溶性导电性聚合物和分子量为200〜10000的亲水性部位的生物表面活性剂，防止化学增幅抗蚀剂中的薄膜化的性能优异，以及抗静电膜和 通过使用抗静电剂获得的涂布产品。

公开(公告)号：US5783251A

公开(公告)日：1998-07-21

申请号：US863831

申请日：1997-05-27

申请人： Hideki Tomozawa ,  Yoshihiro Saida ,  Junya Kato ,  Yukie Akakabe ,  Yoshiaki Ikenoue ,  Reiko Ichikawa

发明人： Hideki Tomozawa ,  Yoshihiro Saida ,  Junya Kato ,  Yukie Akakabe ,  Yoshiaki Ikenoue ,  Reiko Ichikawa

IPC分类号： C08G75/00 ,  C08G61/12 ,  C09K3/16 ,  G01N23/225 ,  G03F1/40 ,  G03F7/004 ,  H01B1/12 ,  H01J37/305 ,  H05H1/00

CPC分类号： H01B1/127 ,  C08G61/126 ,  C09K3/16

摘要： An antistatic agent comprising a water-soluble electroconductive polymer comprising at least a repeating unit having a sulfo group-containing isothianaphthenylene structure; a method for suppressing electrification of an article during the production or use of the article by forming an electroconductive film comprising the water-soluble electroconductive polymer on the article; an article of which electrification is suppressed by having an electroconductive film comprising the water-soluble conductive polymer on the article; and a method for observing or inspecting an article with suppressing electrification thereof during irradiation with charged particle beams by forming an electroconductive film comprising the water-soluble electroconductive polymer on the article. The electroconductive film retains the electrification-suppressing effect and removability stably even when subjected to a heat treatment or left to stand for a long period of time. The antistatic agent can be formulated into a film-forming antistatic composition which can be used at any pH value from acidic to basic and which is excellent in storage stability.

摘要翻译： 一种抗静电剂，其包含至少包含具有含磺基的异硫茚结构的重复单元的水溶性导电聚合物; 一种通过在制品上形成包含水溶性导电聚合物的导电膜来抑制在制造或使用制品期间物品带电的方法; 通过在制品上具有包含水溶性导电聚合物的导电膜来抑制带电的制品; 以及通过在制品上形成包含水溶性导电聚合物的导电膜，在带电粒子束照射期间观察或检查物品的带电抑制方法。 导电膜即使经受热处理也可以稳定地保持电气抑制效果和可移除性，或者长时间静置。 抗静电剂可以配制成成膜抗静电组合物，其可以在酸性至碱性的任何pH值下使用，并且储存稳定性优异。

公开(公告)号：US5648453A

公开(公告)日：1997-07-15

申请号：US476977

申请日：1995-06-07

申请人： Yoshihiro Saida ,  Yoshiaki Ikenoue ,  Reiko Ichikawa

发明人： Yoshihiro Saida ,  Yoshiaki Ikenoue ,  Reiko Ichikawa

IPC分类号： C08G61/12 ,  H01B1/12 ,  C08G75/00 ,  C08G63/91

CPC分类号： C08G61/123 ,  H01B1/127

摘要： Electroconductive polymers having a chemical structure represented by, for example, the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 independently represent H, a C.sub.1 to C.sub.20 alkyl or alkoxy group, an amino group, a trihalomethyl group or a phenyl group, X represents S, O, Se, Te or NR.sub.3 R.sub.3 represents H, a C.sub.1 to C.sub.6 alkyl group or an aryl group, M represents a cation such as M.sup.+, an alkali metal ion or a quaternary ammonium ion, and m is 0.2 to 2 and a process for producing the polymer.

摘要翻译： 具有由例如H表示的式（I）表示的化学结构的导电聚合物，C1至C20烷基或烷氧基，氨基，三卤代甲基或苯基，X表示S，O，Se，Te 或NR 3 R 3表示H，C 1〜C 6烷基或芳基，M表示阳离子例如M +，碱金属离子或季铵离子，m为0.2〜2，以及该聚合物的制造方法。

公开(公告)号：US08535394B2

公开(公告)日：2013-09-17

申请号：US12097669

申请日：2006-12-15

申请人： Yoshihiro Saida

发明人： Yoshihiro Saida

IPC分类号： H01G9/00

CPC分类号： H01G9/0036 ,  H01G9/028 ,  H01G9/15

摘要： A method for producing a solid electrolyte, which includes the steps of applying a solution containing a five-membered heterocyclic compound as a polymerizable monomer on a substrate surface, and polymerizing the applied monomer to give a solid electrolyte. The monomer-containing solution contains the polymerizable monomer and at least one polymerizable compound selected from a dimer of the monomer and a trimer of the monomer, at a proportion satisfying the equation: A/(B+C)=100-1,000,000 where A: concentration of the polymerizable monomer, B: concentration of the dimmer in terms of the concentration of its monomer, and C: concentration of the trimer in terms of the concentration of its monomer. In another aspect, a method is disclosed wherein a solution of a compound having a thiophene skeletal structure, which solution has a light absorbance of 1.5-10 at 300-340 nm, is applied on a substrate surface and polymerized.

摘要翻译： 一种固体电解质的制造方法，其特征在于，在基材表面上涂布含有5元杂环化合物作为聚合性单体的溶液，使所施加的单体聚合，得到固体电解质。 含单体的溶液以满足以下等式的比例含有可聚合单体和选自单体的二聚体和单体的三聚体的至少一种可聚合化合物：A /（B + C）= 100-1,000,000其中A： 可聚合单体的浓度，B：以单体浓度计的二聚体浓度，C：以其单体浓度计的三聚体浓度。 在另一方面，公开了一种方法，其中将具有噻吩骨架结构的化合物的溶液在300-340nm处的吸光度为1.5-10的溶液涂覆在基材表面上并聚合。

公开(公告)号：US20110157776A1

公开(公告)日：2011-06-30

申请号：US12970058

申请日：2010-12-16

申请人： Kouhel Ishida ,  Yoshihiro Saida ,  Masaaki Nishioka

发明人： Kouhel Ishida ,  Yoshihiro Saida ,  Masaaki Nishioka

IPC分类号： H01G9/15 ,  H01G9/00

CPC分类号： H01G9/15 ,  H01G9/0029 ,  Y10T29/417

摘要： A solid electrolytic capacitor containing a solid electrolytic capacitor element with increased heat resistance, resistance to leakage current, and a low ESR and high reliability, includes a solid electrolytic capacitor element having a dielectric layer, a solid electrolyte layer, a carbon paste layer, and a conductive paste layer sequentially stacked on a surface of a valve acting metal plate, where the carbon paste layer has an end thereof on the solid electrolyte layer, the end of the carbon paste layer is covered with an insulating resin layer, and the largest thickness of the capacitor element in the section of the insulating resin layer is not more than the largest thickness of the capacitor element in the section of the conductive paste layer. A manufacturing method is also described.

摘要翻译： 包含具有增加的耐热性，耐漏电流和低ESR和高可靠性的固体电解电容器元件的固体电解电容器包括具有电介质层，固体电解质层，碳糊层和 导电浆料层依次层叠在阀作用金属板的表面上，其中碳糊层的端部位于固体电解质层上，碳糊层的端部被绝缘树脂层覆盖，最大厚度 在绝缘树脂层的截面中的电容器元件的厚度不大于导电膏层的截面中的电容器元件的最大厚度。 还描述了制造方法。

公开(公告)号：US20100103590A1

公开(公告)日：2010-04-29

申请号：US11993240

申请日：2006-06-27

申请人： Yoshihiro Saida ,  Hirofumi Fukunaga

发明人： Yoshihiro Saida ,  Hirofumi Fukunaga

IPC分类号： H01G9/025

CPC分类号： H01G9/0036 ,  C08G61/126 ,  H01G9/028 ,  H01G9/042

摘要： The present invention relates to a solid electrolytic capacitor comprising a layer of self-doping type conductive polymer having a crosslink between polymer chains thereof on the dielectric film formed on a valve-acting metal. The present invention enables to stably produce thin capacitor elements suitable for laminated type solid electrolytic capacitors, showing less short-circuit failure and less fluctuation in the shape of element, which allows to increase the number of laminated elements in a solid electrolytic capacitor chip to make a capacitor having a high capacity, and having less fluctuation in equivalent series resistance.

摘要翻译： 固体电解电容器技术领域本发明涉及一种固体电解电容器，其包括在阀作用金属上形成的介电膜上具有在其聚合物链之间的交联的自掺杂型导电聚合物层。 本发明能够稳定地制造适合于层叠型固体电解电容器的薄型电容器元件，其显示出较少的短路故障和较少的元件形状的波动，这允许增加固体电解电容器芯片中的层叠元件的数量 具有高容量的电容器，并且具有较小的等效串联电阻的波动。

公开(公告)号：US07691157B2

公开(公告)日：2010-04-06

申请号：US11667952

申请日：2005-11-18

申请人： Yoshihiro Saida ,  Hiroshi Konuma

发明人： Yoshihiro Saida ,  Hiroshi Konuma

IPC分类号： H01G9/00

CPC分类号： H01G9/15 ,  H01G9/0036 ,  H01G9/042 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10T29/417

摘要： The present invention relates to a method for producing a solid electrolytic capacitor in which a solid electrolyte layer is provided by a process comprising a step of dipping a valve-acting metal having thereon a dielectric film layer in a monomer-containing solution, followed by drying (Step 1), a step of dipping the valve-acting metal in an oxidizing agent-containing solution, followed by drying (Step 2), and a step of dipping the valve-acting metal in an oxidizing agent-free solution, followed by drying (Step 3); and to a solid electrolytic capacitor produced thereof. According to the present invention, a thin capacitor element with reduced failure of short circuit and less fluctuation in the element shape can be stably produced, the number of capacitor elements stacked in a solid electrolytic capacitor chip can be increased to realize high capacitance, and a solid electrolytic capacitor element suitable for a solid electrolytic multilayer capacitor with less fluctuation in the equivalent series resistance can be provided.

摘要翻译： 固体电解电容器的制造方法技术领域本发明涉及一种固体电解电容器的制造方法，该固体电解电容器的制造方法包括以下步骤：在含有单体的溶液中浸渍其上具有电介质膜层的阀作用金属，然后干燥 （步骤1），将阀作用金属浸渍在含氧化剂溶液中，然后干燥（步骤2）的步骤，以及将阀作用金属浸渍在不含氧化剂的溶液中的步骤，然后 干燥（步骤3）; 以及由其制造的固体电解电容器。 根据本发明，可以稳定地制造具有短路故障和元件形状波动小的薄电容元件，可以增加堆叠在固体电解电容器芯片中的电容器元件的数量，以实现高电容，并且 可以提供适用于等效串联电阻波动较小的固体电解多层电容器的固体电解电容器元件。

公开(公告)号：US07638071B2

公开(公告)日：2009-12-29

申请号：US10593498

申请日：2005-03-23

申请人： Yoshihiro Saida ,  Takashi Ohkubo

发明人： Yoshihiro Saida ,  Takashi Ohkubo

IPC分类号： H01B1/10 ,  H01B1/12

CPC分类号： C08G61/126 ,  C08G2261/135 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/512 ,  C08G2261/76 ,  C08G2261/79 ,  H01B1/127 ,  H01L51/5088 ,  Y10T428/265 ,  Y10T428/31533

摘要： The invention relates to a self-doping type electrically conducting polymer comprising an isothianaphthene or thiophene skeleton where the polymer chains are crosslinked preferably through a sulfone bond which is imparted with water resistance and solvent resistance; a production process thereof; an electrically conducting composition film obtained by coating a composition containing the self-doping type electrically conducting polymer on a substrate and heating it; a product coated using the composition; and an electronic device containing the self-doping type electrically conducting polymer.

摘要翻译： 本发明涉及一种包含异硫茚或噻吩骨架的自掺杂型导电聚合物，其中聚合物链优选通过赋予耐水性和耐溶剂性的砜键进行交联; 其生产工艺; 通过将含有自掺杂型导电聚合物的组合物涂布在基板上并加热而获得的导电性组合物膜; 使用该组合物涂覆的产品; 和含有自掺杂型导电聚合物的电子器件。

公开(公告)号：US20070252111A1

公开(公告)日：2007-11-01

申请号：US11663199

申请日：2005-09-21

申请人： Takashi Ohkubo ,  Yoshihiro Saida

发明人： Takashi Ohkubo ,  Yoshihiro Saida

IPC分类号： C09K3/16 ,  B32B27/18 ,  G03F7/11

CPC分类号： C09K3/16 ,  C08G2261/312 ,  G03F7/093 ,  Y10T428/31855

摘要： The invention provides an antistatic treatment agent having an ability of preventing resist film thinning phenomenon in a chemically amplified resist, an antistatic film, a coated article and a pattern forming method using such antistatic treatment agent, in particular, the invention provides an antistatic treatment agent comprising an aqueous solvent-soluble electroconductive polymer, a diamine (divalent) or polyamine (polyvalent) aliphatic basic compound and an anionic surfactant, an antistatic film, a coated article and a pattern forming method using such antistatic treatment agent. As the aqueous solvent-soluble electroconductive polymer, a π-conjugated electroconductive polymer having a Brönsted acid group is a sulfonic acid group is preferred and it is preferable that the amount of the diamine (divalent) or polyamine (polyvalent) aliphatic basic compound be from 0.1 to 75 mol % based on the total number of moles of the basic compounds.

摘要翻译： 本发明提供一种具有防止化学放大型抗蚀剂，抗静电膜，涂布制品和使用这种抗静电处理剂的图案形成方法中的抗蚀剂薄膜化现象的抗静电处理剂，特别是本发明提供一种抗静电处理剂 包含水性溶剂可溶性导电聚合物，二胺（二价）或多胺（多价）脂族碱性化合物和阴离子表面活性剂，抗静电膜，涂布制品和使用这种抗静电处理剂的图案形成方法。 作为水性溶剂可溶性导电性聚合物，优选具有布朗斯台德酸基的π-共轭导电性聚合物为磺酸基，优选二胺（二价）或多胺（多价）脂肪族碱性化合物的量为 相对于碱性化合物的总摩尔数为0.1〜75摩尔％。

公开(公告)号：US20070129534A1

公开(公告)日：2007-06-07

申请号：US10573415

申请日：2004-09-24

申请人： Hideki Ohata ,  Yoshihiro Saida ,  Shuichi Naijo

发明人： Hideki Ohata ,  Yoshihiro Saida ,  Shuichi Naijo

IPC分类号： C08G75/00

CPC分类号： C08G61/124 ,  C08G61/126 ,  H01G9/028 ,  H01G11/48 ,  H01M4/624 ,  Y02E60/13

摘要： The present invention relates to a novel π-conjugated copolymer having a high conductivity, obtained through chamically oxidative polymerization of a thiophene-based unit represented by formula (IV) and a pyrrole-based unit represented by formula (III) at a low temperature, preferably in the presence of a compound containing a counter anion, and production method therefor, and further relates to an article coated with the copolymer, a solid electrolytic capacitor using the copolymer as solid electrolyte and production method for the capacitor.

摘要翻译： 本发明涉及一种具有高导电性的新型π-共轭共聚物，其通过在式（IV）表示的噻吩基单元和式（III）表示的吡咯基单元）的低温下进行二氧化聚合， 优选在含有抗衡阴离子的化合物的存在下，以及其制备方法，还涉及涂覆有共聚物的制品​​，使用该共聚物作为固体电解质的固体电解电容器及其制造方法。