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公开(公告)号：US20080063946A1
公开(公告)日：2008-03-13
申请号：US11575533
申请日：2005-09-21
IPC分类号： H01M10/40
CPC分类号： H01M10/0569 , H01M4/0404 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M10/052 , H01M10/0567 , H01M2300/0042 , Y02E60/122
摘要： An electrolytic solution and a battery capable of improving high temperature characteristics are provided. A separator (23) is impregnated with an electrolytic solution. The electrolytic solution includes a solvent including 4,5-difluoro-1,3-dioxolane-2-one. The content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 wt % to 50 wt %, or in the case where 4,5-difluoro-1,3-dioxolane-2-one is mixed and used with 4-fluoro-1,3-dioxolane-2-one, the content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 vol ppm to 2000 vol ppm.
摘要翻译： 提供了能够提高高温特性的电解液和电池。 用电解液浸渍分离器（23）。 电解液包括包含4,5-二氟-1,3-二氧戊环-2-酮的溶剂。 4,5-二氟-1,3-二氧戊环-2-酮的含量优选在5重量％〜50重量％的范围内，或者在4,5-二氟-1,3-二氧戊环-2 - 酮混合并与4-氟-1,3-二氧戊环-2-酮一起使用，4,5-二氟-1,3-二氧戊环-2-酮的含量优选在5体积ppm至2000的范围内 体积ppm。
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公开(公告)号：US08715864B2
公开(公告)日：2014-05-06
申请号：US11575533
申请日：2005-09-21
IPC分类号： H01M6/16
CPC分类号： H01M10/0569 , H01M4/0404 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M10/052 , H01M10/0567 , H01M2300/0042 , Y02E60/122
摘要： An electrolytic solution and a battery capable of improving high temperature characteristics are provided. A separator (23) is impregnated with an electrolytic solution. The electrolytic solution includes a solvent including 4,5-difluoro-1,3-dioxolane-2-one. The content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 wt % to 50 wt %, or in the case where 4,5-difluoro-1,3-dioxolane-2-one is mixed and used with 4-fluoro-1,3-dioxolane-2-one, the content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 vol ppm to 2000 vol ppm.
摘要翻译： 提供了能够提高高温特性的电解液和电池。 用电解液浸渍分离器（23）。 电解液包括包含4,5-二氟-1,3-二氧戊环-2-酮的溶剂。 4,5-二氟-1,3-二氧戊环-2-酮的含量优选在5重量％〜50重量％的范围内，或者在4,5-二氟-1,3-二氧戊环-2 - 酮混合并与4-氟-1,3-二氧戊环-2-酮一起使用，4,5-二氟-1,3-二氧戊环-2-酮的含量优选在5体积ppm至2000的范围内 体积ppm。
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23.发明授权公开(公告)号：US08652682B2
公开(公告)日：2014-02-18
申请号：US11872389
申请日：2007-10-15
IPC分类号： H01M10/056
CPC分类号： C07F5/022 , C07F5/04 , H01M6/166 , H01M10/0525 , H01M10/0568 , H01M10/0587
摘要： A battery capable of improving the cycle characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. The electrolytic solution contains an ionic compound such as (2,2-difluoromalonate oxalate)lithium borate and [bis(3,3,3-trifluoromethyl)glycolate oxalate]lithium borate as an electrolyte salt. In the ionic compound, an anion has an asymmetric structure, and a ligand having an oxygen chelate structure in the anion has a halogen as an element. In the battery, the chemical stability of the electrolytic solution is improved, compared to a battery in which the electrolytic solution contains bis(oxalate)lithium borate or the like as an electrolyte salt.
摘要翻译： 提供了能够改善循环特性的电池。 电池包括阴极，阳极和电解液。 将电解液浸渍在设置在阴极和阳极之间的隔膜中。 电解液含有离子化合物如（2,2-二氟丙醛酸酯草酸盐）硼酸锂和[双（3,3,3-三氟甲基）乙醇酸酯草酸盐]硼酸锂作为电解质盐。 在离子化合物中，阴离子具有不对称结构，阴离子中具有氧螯合结构的配体具有卤素作为元素。 与电解液中含有双（草酸）硼酸锂等作为电解质盐的电池相比，电池中的电解液的化学稳定性提高。
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公开(公告)号：US08613873B2
公开(公告)日：2013-12-24
申请号：US12274940
申请日：2008-11-20
CPC分类号： H01M10/0525 , H01M4/134 , H01M4/525 , H01M4/58 , H01M4/62 , H01M4/624 , H01M4/625 , H01M4/626 , H01M10/0568 , H01M10/0569
摘要： A battery capable of improving the cycle characteristics and the swollenness characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. The anode has a coat on an anode active material layer provided on an anode current collector. The coat contains a metal salt. The metal salt has a hydroxyl group and at least one of a sulfonic acid group and a carboxylic acid group. Thereby, lithium ions are easily inserted in the anode and extracted from the anode, and decomposition of the electrolytic solution is prevented.
摘要翻译： 提供能够改善循环特性和膨胀特性的电池。 电池包括阴极，阳极和电解液。 将电解液浸渍在设置在阴极和阳极之间的隔膜中。 阳极在设置在阳极集电器上的阳极活性材料层上具有涂层。 外套含有金属盐。 金属盐具有羟基和磺酸基和羧酸基中的至少一个。 因此，锂离子容易插入阳极并从阳极中提取，并且防止了电解液的分解。
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公开(公告)号：US07776476B2
公开(公告)日：2010-08-17
申请号：US11298162
申请日：2005-12-07
IPC分类号： H01M4/58
CPC分类号： H01M10/0525 , H01M10/0568 , H01M2300/0025
摘要： A battery capable of improving cycle characteristics is provided. A spirally wound electrode body in which a cathode and an anode are wound with a separator in between is included. An electrolytic solution in which an electrolyte salt is dissolved in a solvent is impregnated in the separator. The electrolytic solution contains a cyclic ester carbonate derivative having halogen atom such as 4-fluoro-1,3-dioxolan-2-one and a light metal salt such as difluoro[oxolate-O,O′]lithium borate, tetrafluoro[oxolate-O,O′]lithium phosphate, and difluoro bis[oxolate-O,O′]lithium phosphate.
摘要翻译： 提供了能够改善循环特性的电池。 包括其中阴极和阳极缠绕有隔膜的螺旋缠绕的电极体。 将电解质盐溶解在溶剂中的电解液浸渍在隔膜中。 电解液含有具有卤素原子的环状碳酸酯衍生物如4-氟-1,3-二氧戊环-2-酮和轻金属盐如二氟[草酸酯-O，O']硼酸锂，四氟[ O，O']磷酸锂和二氟双[氧代甲酸酯-O，O']磷酸锂。
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公开(公告)号：US20100196764A1
公开(公告)日：2010-08-05
申请号：US12693622
申请日：2010-01-26
IPC分类号： H01M6/16
CPC分类号： H01M10/0569 , H01M4/133 , H01M4/134 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/48 , H01M4/525 , H01M4/587 , H01M4/62 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M2300/0025 , H01M2300/0091 , Y02E60/122
摘要： A secondary battery capable of achieving superior cycle characteristics, superior storage characteristics, and superior swollenness characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolyte containing a solvent and an electrolyte salt. The solvent contains halogenated cyclic ester carbonate. The halogenated cyclic ester carbonate is a cyclic compound that has one or more fluorine groups, one or more fluorinated alkyl groups, and a carbonyl group.
摘要翻译： 提供能够实现优异的循环特性，优异的储存特性和优异的膨胀特性的二次电池。 二次电池包括阴极，阳极和含有溶剂和电解质盐的电解质。 溶剂含有卤代环状碳酸酯。 卤代环状碳酸酯是具有一个或多个氟基，一个或多个氟化烷基和羰基的环状化合物。
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公开(公告)号：US20090233180A1
公开(公告)日：2009-09-17
申请号：US12403699
申请日：2009-03-13
IPC分类号： H01M6/16
CPC分类号： H01M4/0471 , H01M4/0419 , H01M4/0421 , H01M4/134 , H01M4/1395 , H01M4/362 , H01M4/366 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M2004/027 , H01M2300/0037 , H01M2300/004
摘要： A secondary battery capable of improving the cycle characteristics and the storage characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode contains an anode active material containing a material that is capable of inserting and extracting an electrode reactant and has at least one of metal elements and metalloid elements. Further, the electrolytic solution contains a solvent containing a sulfone compound having a structure in which —S(═O)2—S—C(═O)— bond is introduced to a benzene skeleton.
摘要翻译： 提供能够改善循环特性和存储特性的二次电池。 二次电池包括阴极，阳极和电解液。 阳极包含负极活性材料，其包含能够插入和提取电极反应物并且具有金属元素和准金属元素中的至少一种的材料。 此外，电解液含有含有具有-S（-O）2 -S-C（-O） - 键被引入苯骨架的结构的砜化合物的溶剂。
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公开(公告)号：US20090226821A1
公开(公告)日：2009-09-10
申请号：US12401190
申请日：2009-03-10
IPC分类号： H01M6/16
CPC分类号： H01M10/0569 , H01M4/134 , H01M4/366 , H01M10/0567
摘要： A secondary battery capable of improving the cycle characteristics while securing the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer containing a plurality of anode active material particles having silicon (Si). The anode active material layer contains at least one of an oxide-containing film covering a surface of the anode active material particles and a metal material not being alloyed with an electrode reactant provided in a gap in the anode active material layer. The electrolytic solution contains a solvent containing an organic acid that has a portion including an electron attractive group such as —(O═)C—C(═O)— bond in the center and a hydroxyl group on the both ends.
摘要翻译： 提供能够在确保初始充放电特性的同时改善循环特性的二次电池。 二次电池包括阴极，阳极和电解液。 阳极具有包含多个具有硅（Si）的负极活性物质粒子的负极活性物质层。 所述负极活性物质层含有覆盖所述负极活性物质粒子的表面的含氧化物膜和与所述阳极活性物质层的间隙中设置的电极反应物未合金化的金属材料中的至少一种。 电解液含有含有中心具有电子吸引基团 - （O-C-C（-O） - 键的部分的有机酸的溶剂和两端的羟基。
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公开(公告)号：US20090226819A1
公开(公告)日：2009-09-10
申请号：US12401288
申请日：2009-03-10
CPC分类号： H01M10/0569 , H01M4/131 , H01M4/134 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M10/052 , H01M10/0567 , H01M2300/0037 , Y02E60/122
摘要： A secondary battery is provided and includes a cathode, an anode and an electrolytic solution, in which the anode includes an anode active material layer including a plurality of anode active material particles, the plurality of anode active material particles including silicon as a constituent element. The anode active material layer includes at least one of an oxide-containing film and a metal material as a constituent element. The oxide-containing film with which surfaces of the anode active material particles are covered. The metal material includes a metal element which is not alloyed with an electrode reactant, and being arranged in a gap in the anode active material layer. The electrolytic solution includes a solvent including at least one kind selected from the group consisting of specific isocyanate compounds.
摘要翻译： 提供二次电池，其包括阴极，阳极和电解液，其中阳极包括包含多个负极活性物质颗粒的负极活性物质层，所述多个阳极活性物质颗粒包含硅作为构成元素。 负极活性物质层包含含氧化物膜和作为构成元素的金属材料中的至少一种。 负极活性物质粒子的表面覆盖有氧化物膜。 金属材料包括不与电极反应物合金化的金属元素，并且布置在阳极活性物质层的间隙中。 所述电解液包含含有选自特定异氰酸酯化合物中的至少一种的溶剂。
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公开(公告)号：US20090111020A1
公开(公告)日：2009-04-30
申请号：US12255279
申请日：2008-10-21
IPC分类号： H01M10/26
CPC分类号： H01M4/62 , H01M4/134 , H01M4/139 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569
摘要： An anode and a secondary battery capable of improving the charge and discharge efficiency are provided. The anode includes an anode current collector, and an anode active material layer provided on the anode current collector. The anode active material layer has a plurality of anode active material particles containing at least one of a simple substance of silicon, a compound of silicon, a simple substance of tin and a compound of tin, and has a coat containing an oxo acid salt in at least part of the surface of the anode active material particles.
摘要翻译： 提供了能够提高充放电效率的阳极和二次电池。 阳极包括阳极集电器和设置在阳极集电器上的阳极活性材料层。 负极活性物质层具有多个负极活性物质粒子，其含有硅的单质，硅的化合物，锡的单质和锡的化合物中的至少一种，并且具有包含含有酸的酸的盐 阳极活性物质颗粒的表面的至少一部分。
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