公开(公告)号：US09178246B2

公开(公告)日：2015-11-03

申请号：US13034952

申请日：2011-02-25

申请人： Atsumichi Kawashima ,  Haruo Watanabe ,  Noritoshi Araki ,  Shuhei Sugita ,  Shinichi Katayama ,  Hideki Nakai

发明人： Atsumichi Kawashima ,  Haruo Watanabe ,  Noritoshi Araki ,  Shuhei Sugita ,  Shinichi Katayama ,  Hideki Nakai

IPC分类号： H01M10/0567 ,  H01M10/0566 ,  H01M10/0564 ,  H01M10/02

CPC分类号： H01M10/02 ,  Y02E60/122

摘要： A nonaqueous electrolyte battery includes: a positive electrode; a negative electrode; a nonaqueous electrolyte that includes a solvent and an electrolyte salt, the solvent including a halogenated cyclic carbonate of the Formula (1) below, or at least one of unsaturated cyclic carbonates of the Formulae (2) and (3) below; and a polyacid and/or a polyacid compound contained in the battery, where X is a F group or a Cl group, R1 and R2 are each independently a CnH2n+1 group (0≦n≦4), and R3 is CnH2n+1−mXm (0≦n≦4, 0≦m≦2n+1), where R4 and R5 are each independently a CnH2n+1 group (0≦n≦4), where R6 to R11 are each independently a CnH2n+1 group (0≦n≦4).

摘要翻译： 非水电解质电池包括：正极; 负极; 包含溶剂和电解质盐的非水电解质，所述溶剂包括下述式（1）的卤代环状碳酸酯或下述式（2）和（3）中的至少一种不饱和环状碳酸酯; 和包含在电池中的多酸和/或多酸化合物，其中X为F基或Cl基，R 1和R 2各自独立地为C n H 2n + 1基（0＆nl E; n＆nl E; 4），并且R 3为C n H 2n + 1 -mXm（0＆nlE; n＆nlE; 4,0＆nlE; m＆nlE; 2n + 1），其中R4和R5各自独立地为CnH2n + 1基团（0＆lt; nEE; n＆lt; IL1; 4），其中R6至R11各自独立地为CnH2n + （0＆nlE; n＆nlE; 4）。

公开(公告)号：US08980497B2

公开(公告)日：2015-03-17

申请号：US11561612

申请日：2006-11-20

申请人： Hideki Nakai ,  Atsumichi Kawashima ,  Akinori Kita

发明人： Hideki Nakai ,  Atsumichi Kawashima ,  Akinori Kita

IPC分类号： H01M4/36 ,  H01M10/052 ,  H01M4/133 ,  H01M4/136 ,  H01M4/58 ,  H01M4/485 ,  H01M6/16 ,  H01M10/0568

CPC分类号： H01M10/052 ,  H01M4/133 ,  H01M4/136 ,  H01M4/485 ,  H01M4/581 ,  H01M4/5815 ,  H01M6/16 ,  H01M6/166 ,  H01M10/0568 ,  Y02E60/122

摘要： A battery capable of reducing swelling is provided. A battery includes a cathode, an anode and an electrolyte. The anode includes a coating containing a SO3-containing compound, and the electrolyte contains an electrolyte salt having reduction power. Therefore, on the surface of the anode, the SO3-containing compound is preferentially reduced and decomposed to become a sulfur-containing compound. In the result, decomposition reaction of the electrolyte is prevented.

摘要翻译： 提供能够减少膨胀的电池。 电池包括阴极，阳极和电解质。 阳极包括含有含SO 3的化合物的涂层，并且电解质含有具有还原能力的电解质盐。 因此，在阳极表面上，含SO 3的化合物优先被还原并分解成含硫化合物。 结果，可以防止电解液的分解反应。

公开(公告)号：US08980473B2

公开(公告)日：2015-03-17

申请号：US11270099

申请日：2005-11-09

申请人： Hideki Nakai ,  Akinori Kita ,  Atsumichi Kawashima ,  Tadahiko Kubota

发明人： Hideki Nakai ,  Akinori Kita ,  Atsumichi Kawashima ,  Tadahiko Kubota

IPC分类号： H01M4/13 ,  H01M4/58 ,  H01M4/134 ,  H01M4/36 ,  H01M4/38 ,  H01M4/62 ,  H01M10/052 ,  H01M4/131 ,  H01M4/1395 ,  H01M4/40 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0587 ,  H01M4/02

CPC分类号： H01M4/134 ,  H01M4/131 ,  H01M4/1395 ,  H01M4/364 ,  H01M4/366 ,  H01M4/38 ,  H01M4/382 ,  H01M4/386 ,  H01M4/387 ,  H01M4/405 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0587 ,  H01M2004/027 ,  Y02E60/122

摘要： An anode and a battery capable of improving battery characteristics such as cycle characteristics are provided. A coating containing at least one from the group consisting of oligomers having a polyene structure and derivatives thereof is provided on the surface of an anode active material layer. The anode active material layer contains a substance containing Si or Sn as an element as an anode active material. By the coating, oxidation of the anode active material layer is inhibited, and decomposition reaction of the electrolytic solution is inhibited.

摘要翻译： 提供能够提高循环特性等电池特性的阳极和电池。 在阳极活性物质层的表面上设置有含有至少一种具有多烯结构的低聚物及其衍生物的涂层。 负极活性物质层含有含有作为阳极活性物质的元素的Si或Sn的物质。 通过涂布，负极活性物质层的氧化被抑制，并且电解液的分解反应被抑制。

公开(公告)号：USRE44489E1

公开(公告)日：2013-09-10

申请号：US13475199

申请日：2012-05-18

申请人： Akira Yamaguchi ,  Tadahiko Kubota ,  Atsumichi Kawashima ,  Akinori Kita ,  Satoshi Mizutani ,  Hiroshi Inoue

发明人： Akira Yamaguchi ,  Tadahiko Kubota ,  Atsumichi Kawashima ,  Akinori Kita ,  Satoshi Mizutani ,  Hiroshi Inoue

IPC分类号： H01M6/04 ,  H01M6/16

CPC分类号： H01M4/58 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/525 ,  H01M6/168 ,  H01M10/0431 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/4235 ,  H01M2004/027

摘要： A battery capable of improving battery characteristics such as cycle characteristics is provided. An electrolytic solution is impregnated in a separator. The electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Fluorine ion content in the electrolytic solution is preferably from 10 weight ppm to 3200 weight ppm. Thereby, chemical stability of the electrolytic solution is improved, and cycle characteristics are improved. The present invention is effective for the case using an anode active material containing Sn or Si as an element for an anode.

摘要翻译： 提供了能够提高电池特性例如循环特性的电池。 将电解液浸渍在隔膜中。 电解液含有4-氟-1,3-二氧戊环-2-酮。 电解液中的氟离子含量优选为10重量ppm〜3200重量ppm。 由此，提高了电解液的化学稳定性，提高了循环特性。 本发明对于使用含有Sn或Si作为阳极元素的负极活性物质的情况是有效的。

公开(公告)号：US20120244410A1

公开(公告)日：2012-09-27

申请号：US13421130

申请日：2012-03-15

申请人： Atsumichi Kawashima ,  Hiroshi Imoto ,  Tomoyuki Shiratsuchi ,  Takuma Sakamoto ,  Naoto Ueda ,  Atsushi Nishimoto ,  Tadahiko Kubota ,  Masayuki Ihara

发明人： Atsumichi Kawashima ,  Hiroshi Imoto ,  Tomoyuki Shiratsuchi ,  Takuma Sakamoto ,  Naoto Ueda ,  Atsushi Nishimoto ,  Tadahiko Kubota ,  Masayuki Ihara

IPC分类号： H01M10/04 ,  H01M4/525 ,  H01M4/485 ,  H01M4/505 ,  H01M10/00 ,  H01M2/16

CPC分类号： H01M10/052 ,  H01M2/1653 ,  H01M2/1686 ,  H01M4/485 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  Y02E60/122 ,  Y02T10/7011

摘要： A secondary battery capable of suppressing resistance rise even after repeated charge and discharge is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode contains titanium-containing lithium composite as an anode active material, and the electrolytic solution contains cyclic disulfonic acid anhydride.

摘要翻译： 提供即使在重复充电和放电之后能够抑制电阻上升的二次电池。 二次电池包括阴极，阳极和电解液。 阳极含有含钛的锂复合物作为负极活性物质，电解液含有环状二磺酸酐。

公开(公告)号：US20090123839A1

公开(公告)日：2009-05-14

申请号：US12263840

申请日：2008-11-03

申请人： Masanori Soma ,  Kenichi Kawase ,  Masayuki Ihara ,  Atsumichi Kawashima ,  Kazumi Izumitani

发明人： Masanori Soma ,  Kenichi Kawase ,  Masayuki Ihara ,  Atsumichi Kawashima ,  Kazumi Izumitani

IPC分类号： H01M4/48 ,  H01M4/54 ,  H01M4/52 ,  H01M4/50 ,  H01M4/56 ,  B05D5/12

CPC分类号： H01M4/621 ,  H01M4/1315 ,  H01M4/13915 ,  H01M4/364 ,  H01M4/525 ,  H01M4/5815 ,  H01M4/582 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/623 ,  H01M10/0525 ,  H01M2004/028

摘要： A positive electrode for a lithium-ion secondary battery includes a positive-electrode mixture layer, which includes a positive-electrode active material containing lithium composite oxide, a conductive material, and a binder, and a current collector. The positive-electrode mixture layer contains a compound including sulfur and/or phosphorous, a first polymer serving as a main binder, and a second polymer different from the first polymer.

摘要翻译： 锂离子二次电池用正极包括正极复合层，其包含含有锂复合氧化物的正极活性物质，导电材料和粘合剂，以及集电体。 正极混合物层含有包含硫和/或磷的化合物，作为主要粘合剂的第一聚合物和不同于第一聚合物的第二聚合物。

公开(公告)号：US20080032194A1

公开(公告)日：2008-02-07

申请号：US11781776

申请日：2007-07-23

申请人： Hideki Nakai ,  Atsumichi Kawashima ,  Akinori Kita

发明人： Hideki Nakai ,  Atsumichi Kawashima ,  Akinori Kita

IPC分类号： H01M4/58 ,  C01B25/30 ,  C01B25/455

CPC分类号： H01M10/0525 ,  H01M2/0207 ,  H01M2/0287 ,  H01M4/136 ,  H01M4/5825 ,  H01M4/62 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/028 ,  H01M2300/0068

摘要： A positive electrode having a positive-electrode active material and used for a nonaqueous electrolyte cell is provided. The positive electrode includes a coating, wherein the coating contains at least one first compound for which a binding-energy peak in a phosphorus 2p spectrum obtained by X-ray photoelectron spectroscopy is in the range of 132 to 135 eV.

摘要翻译： 提供具有正极活性物质并用于非水电解质电池的正极。 正极包括涂层，其中涂层含有至少一种第一化合物，通过X射线光电子能谱法获得的磷2p光谱中的结合能峰在132至135eV的范围内。

公开(公告)号：US20060019170A1

公开(公告)日：2006-01-26

申请号：US11183513

申请日：2005-07-18

申请人： Momoe Adachi ,  Shigeru Fujita ,  Atsumichi Kawashima

发明人： Momoe Adachi ,  Shigeru Fujita ,  Atsumichi Kawashima

IPC分类号： H01M10/40

CPC分类号： H01M10/0569 ,  H01M6/164 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567

摘要： A battery capable of inhibiting decrease in capacity and inhibiting swollenness even in hot environment is provided. A battery comprises a cathode, an anode and an electrolyte inside a film exterior member. The electrolytic solution contains carboxylate ester or ketone, in which a third alkyl group is directly bonded to a carbonyl group. Thereby, decomposition reaction of the solvent in the cathode is inhibited.

摘要翻译： 提供能够抑制即使在高温环境下的容量降低，抑制肿胀的电池。 电池包括阴极，阳极和膜外部构件内的电解质。 电解液含有羧酸酯或酮，其中第三个烷基直接键合到羰基上。 因此，阴极中的溶剂的分解反应被抑制。

公开(公告)号：US10147933B2

公开(公告)日：2018-12-04

申请号：US11763222

申请日：2007-06-14

申请人： Masanori Soma ,  Atsumichi Kawashima ,  Masayuki Ihara ,  Hideki Nakai ,  Kenichi Kawase

发明人： Masanori Soma ,  Atsumichi Kawashima ,  Masayuki Ihara ,  Hideki Nakai ,  Kenichi Kawase

IPC分类号： H01M4/02 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M10/0569 ,  H01M10/0525

摘要： A secondary battery having a cathode, an anode, and an electrolyte is provided. The cathode includes a cathode active material containing at least one kind selected from the group consisting of sulfur S and phosphorus P in a portion near the particle surface of a lithium composite oxide. A content of the kind in the portion is larger than that in the particle of the lithium composite oxide.

公开(公告)号：US09509015B2

公开(公告)日：2016-11-29

申请号：US12708227

申请日：2010-02-18

申请人： Shunsuke Saito ,  Masayuki Ihara ,  Atsumichi Kawashima ,  Takehiko Tanaka ,  Tadahiko Kubota

发明人： Shunsuke Saito ,  Masayuki Ihara ,  Atsumichi Kawashima ,  Takehiko Tanaka ,  Tadahiko Kubota

IPC分类号： H01M6/04 ,  H01M10/0525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M4/02

CPC分类号： H01M10/0525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/021 ,  H01M2300/0025 ,  Y02E60/122

摘要： A battery capable of improving the cycle characteristics even if the thickness of an anode active material layer is increased is provided. The battery includes a cathode, an anode and an electrolytic solution. The anode has an anode active material layer on an anode current collector, and the anode active material layer contains a carbon material and has a thickness of 30 μm or more. The electrolytic solution contains a solvent and an electrolyte salt, and the solvent contains at least one of sulfone compounds such as a cyclic disulfonic acid anhydride.

摘要翻译： 提供即使增加阳极活性物质层的厚度也能够改善循环特性的电池。 电池包括阴极，阳极和电解液。 阳极在阳极集电体上具有负极活性物质层，阳极活性物质层含有碳材料，其厚度为30μm以上。 电解液含有溶剂和电解质盐，溶剂含有环状二磺酸酐等砜化合物中的至少一种。