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21.发明授权公开(公告)号：US06551956B1
公开(公告)日：2003-04-22
申请号：US08953296
申请日：1997-10-17
申请人： Jean Malinge
发明人： Jean Malinge
IPC分类号： B01J3100
CPC分类号： C08F110/02 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , Y10S526/943 , C08F4/6492 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： The present invention relates to a catalytic composition for the polymerization of olefins combining a number of catalytic components for the polymerization of olefins and to a process for preparing it. The catalytic component according to the invention is obtained by impregnation of a prepolymer with a solution of a catalytic component for the polymerization of olefins. The invention brings about control of the combination of different catalytic components and provides for improvement in the control of the quality of the polymers manufactured by virtue of the catalytic action of the combined catalytic components.
摘要翻译： 本发明涉及一种用于烯烃聚合的催化组合物，其结合了许多用于烯烃聚合的催化组分及其制备方法。 根据本发明的催化组分通过用用于烯烃聚合的催化组分的溶液浸渍预聚物来获得。 本发明实现了对不同催化组分的组合的控制，并提供了通过组合的催化组分的催化作用来制备的聚合物的质量控制的改进。
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22.发明授权公开(公告)号：US06534433B1
公开(公告)日：2003-03-18
申请号：US09628685
申请日：2000-07-28
IPC分类号： B01J3102
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/02 , C08F4/6555 , C08F2500/24 , C08F2500/12 , C08F2500/04
摘要： A process is provided for preparing a catalyst support for polymerizing &agr;-olefins comprising the steps of: (i) reacting, in the presence of a first electron donor, a chlorine-containing organic compound and a prior mixture of an alkylmagnesien and an aluminoxane and/or aluminosiloxane and/or alkylaluminum and, optionally, a second electron donor; and (ii) activating a product from step (i) in suspension in an inert liquid by means of an activation electron donor, together with the support thus obtained, a catalyst for polymerizing &agr;-olefins, comprising this catalyst support and a group IV transition metal halide, and a process for polymerizing &agr;-olefins, particularly propylene, comprising contacting the &agr;-olefin with the catalyst.
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公开(公告)号：US6057258A
公开(公告)日：2000-05-02
申请号：US104983
申请日：1998-06-26
申请人： Roger Spitz , Thierry Saudemont , Jean Malinge
发明人： Roger Spitz , Thierry Saudemont , Jean Malinge
IPC分类号： C08F2/34 , C08F4/02 , C08F4/639 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/12 , B01J27/135
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/65912 , C08F4/6592
摘要： The invention relates to a process for the preparation of a solid catalytic component of metallocene type for the polymerization of olefins comprising a stage of reaction between a support and a derivative of formula R.sup.1 M.sup.1 X.sup.1.sub.3, in which R.sup.1 represents a hydrocarbon radical, M.sup.1 represents a silicon, germanium or tin atom and X.sup.1 represents a halogen atom. The solid catalytic component according to the invention exhibits a high activity in the polymerization or copolymerization of olefins and can lead to polymers or copolymers of high molecular mass and of low polydispersity, for example less than 2.5.
摘要翻译： 本发明涉及一种制备用于烯烃聚合的金属茂型固体催化组分的方法，包括载体与式R1M1X13的衍生物之间的反应阶段，其中R 1表示烃基，M 1表示硅， 锗或锡原子，X 1表示卤素原子。 根据本发明的固体催化组分在烯烃的聚合或共聚中表现出高活性，并且可以导致高分子量和低多分散性的聚合物或共聚物，例如小于2.5。
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24.发明授权Prepolymer for the polymerization of olefins combining a number of solid catalytic components 失效用于烯烃聚合的预聚物，其结合许多固体催化组分
公开(公告)号：US5852141A
公开(公告)日：1998-12-22
申请号：US710438
申请日：1996-09-17
申请人： Jean Malinge
发明人： Jean Malinge
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/904
摘要： The present invention relates to a prepolymer for the polymerization of olefins, the said prepolymer achieving a combination of a number of solid catalytic components for the polymerization of olefins. The combination of catalytic components makes it possible to combine two properties within the same polymer, one of the properties being contributed by one of the catalytic components and the other property being contributed by the other catalytic component.
摘要翻译： 本发明涉及用于烯烃聚合的预聚物，所述预聚物实现了许多用于烯烃聚合的固体催化组分的组合。 催化组分的组合使得可以在同一聚合物中组合两种性质，其中一种性质由催化组分之一引起，另一种性质由另一种催化组分贡献。
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