公开(公告)号：US20190176078A1

公开(公告)日：2019-06-13

申请号：US16280481

申请日：2019-02-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Youssef BELMABKHOUT ,  Osama SHEKHAH

IPC: B01D53/02 ,  B01J20/28 ,  B01J20/22 ,  A61M16/22 ,  H01M8/0668

Abstract: Embodiments of the present disclosure describe a device for removing CO2 comprising a gas flow inlet, a housing including a SIFSIX-3-Cu metal-organic framework (MOF) composition for sorbing and/or desorbing CO2, and a gas flow outlet. Embodiments of the present disclosure describe an anesthetic system comprising one or more regeneratable cartridges for sorbing and/or desorbing CO2, wherein each of the one or more regeneratable cartridge includes a metal-organic framework composition, wherein at least one of the regeneratable cartridges includes a SIFSIX-3-Cu MOF. Embodiments of the present disclosure describe an alkaline fuel cell comprising a catalyst layer including a SIFSIX-3-Cu MOF composition for sorbing and/or desorbing CO2.

公开(公告)号：US20180264394A1

公开(公告)日：2018-09-20

申请号：US15770808

申请日：2016-10-26

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Infas Haja MOHIDEEN ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI ,  Prashant M. BHATT

IPC: B01D53/047 ,  B01J20/22 ,  B01J20/28

CPC classification number: B01D53/047 ,  B01D53/02 ,  B01D53/0462 ,  B01D2253/204 ,  B01D2256/24 ,  B01D2257/304 ,  B01D2257/504 ,  B01J20/226 ,  B01J20/2808 ,  B01J20/3085 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/847 ,  C07C45/78 ,  Y02C10/08 ,  Y02E50/346

Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.

公开(公告)号：US20180195990A1

公开(公告)日：2018-07-12

申请号：US15797933

申请日：2017-10-30

Applicant: King Abdullah University of Science and Technology

Inventor： Omar YASSINE ,  Osama SHEKHAH ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI ,  Khaled N. SALAMA

IPC: G01N27/12 ,  G01N33/00 ,  G01N27/22

CPC classification number: G01N27/125 ,  G01N27/128 ,  G01N27/226 ,  G01N27/227 ,  G01N33/0044 ,  G01N33/0054 ,  Y02A50/246

Abstract: Embodiments of the present disclosure describe a gas sensor comprising a gas-sensing material including a metal-organic framework with fcu topology and a substrate with a pair of electrodes proximate to the gas-sensing material, wherein the gas sensor is configured to detect toxic gas. Embodiments of the present disclosure further describe a method of detecting gas comprising contacting a gas sensor including a metal-organic framework with fcu topology with a gas/vapour composition including at least one toxic gas, capturing the at least one toxic gas from the fluid composition, and measuring an electrical property to detect a presence of the at least one toxic gas.

公开(公告)号：US20180093250A1

公开(公告)日：2018-04-05

申请号：US15564909

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Osama SHEKHAH ,  Prashant M. BHATT ,  Amandine CADIAU

IPC: B01J20/22 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01D2253/204 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2258/05 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/2808 ,  B01J20/3078 ,  B01J20/3085 ,  C07D241/10 ,  C07F19/005 ,  Y02C10/08 ,  Y02P20/152

Abstract: Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US20170203261A1

公开(公告)日：2017-07-20

申请号：US15328186

申请日：2015-07-24

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: B01D71/06 ,  C07F15/04 ,  B01D69/12 ,  B01D53/22 ,  B01D71/02

CPC classification number: B01D71/06 ,  B01D53/228 ,  B01D69/02 ,  B01D69/10 ,  B01D69/125 ,  B01D71/00 ,  B01D71/022 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/245 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2323/40 ,  B01D2325/20 ,  C07F15/045 ,  Y02C10/08 ,  Y02C10/10 ,  Y02P20/152

Abstract: Embodiments include a method of making a metal organic framework membrane comprising contacting a substrate with a solution including a metal ion and contacting the substrate with a solution including an organic ligand, sufficient to form one or more layers of a metal organic framework on a substrate. Embodiments further include a defect-free metal organic framework membrane comprising MSiF6(pyz)2, wherein M is a metal, wherein the thickness of the membrane is less than 1,000 μm, and wherein the metal organic has a growth orientation along the [110] plane relative to a substrate.

公开(公告)号：US20200306685A1

公开(公告)日：2020-10-01

申请号：US16903820

申请日：2020-06-17

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Infas Haja MOHIDEEN ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI ,  Prashant M. BHATT

IPC: B01D53/047 ,  B01J20/28 ,  B01J20/22 ,  B01J20/30 ,  C07C45/78 ,  B01D53/02

Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.

公开(公告)号：US20190388846A1

公开(公告)日：2019-12-26

申请号：US16557029

申请日：2019-08-30

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: B01D71/06 ,  B01D53/22 ,  C07F15/04 ,  B01D69/12 ,  B01D71/02

Abstract: Embodiments include a method of making a metal organic framework membrane comprising contacting a substrate with a solution including a metal ion and contacting the substrate with a solution including an organic ligand, sufficient to form one or more layers of a metal organic framework on a substrate. Embodiments further include a defect-free metal organic framework membrane comprising MSiF6(pyz)2, wherein M is a metal, wherein the thickness of the membrane is less than 1,000 μm, and wherein the metal organic framework has a growth orientation along the [110] plane relative to a substrate.

公开(公告)号：US20190282998A1

公开(公告)日：2019-09-19

申请号：US16434472

申请日：2019-06-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Osama SHEKHAH ,  Prashant M. BHATT ,  Amandine CADIAU

IPC: B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  B01D53/02 ,  C07D241/10 ,  C07F19/00

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US20190185491A1

公开(公告)日：2019-06-20

申请号：US16280504

申请日：2019-02-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Dong-Xu Dong-Xu ,  Amy J. CAIRNS ,  Youssef BELMABKHOUT

IPC: C07F5/00 ,  B01J20/22 ,  B01J31/16 ,  C07C51/41

CPC classification number: C07F5/00 ,  B01J20/226 ,  B01J31/1691 ,  C07C51/418 ,  Y02C10/08

Abstract: Embodiments of the present disclosure describe compositions comprising a molecular building block (MBB) having the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion. Embodiments of the present disclosure further describe methods of making a metal-organic framework (MOF) composition comprising contacting one or more molecular building blocks (MBBs) with one or more bidentate ligands, wherein the MBBs have the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion.

公开(公告)号：US20190046923A1

公开(公告)日：2019-02-14

申请号：US16159903

申请日：2018-10-15

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Bassem A. ALMAYTHALONY ,  Osama SHEKHAH ,  Youssef BELMABKHOUT

IPC: B01D53/22 ,  B01D53/28 ,  B01D69/02 ,  B01D69/10 ,  B01D67/00 ,  B01D71/02

Abstract: Metal organic framework membranes can be used in gas separation applications.