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公开(公告)号：US4525552A
公开(公告)日：1985-06-25
申请号：US577327
申请日：1984-02-08
CPC分类号： C08F10/00 , Y10S526/901
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed, which is carried out in the presence of a catalyst system comprising the combination of at least one organometallic compound with a transition metal compound supported on a solid carrier, said solid carrier being obtained by the reaction of (a) a magnesium halide, (b) a compound represented by the formula: Al(OR).sub.n X.sub.3-n, where R is a hydrocarbon residual group having 1 to 24 carbon atoms, X is a hydrogen atom, and n is 0
摘要翻译： 公开了一种烯烃的均聚或共聚方法，该方法是在包含至少一种有机金属化合物与负载在固体载体上的过渡金属化合物的组合的催化剂体系的存在下进行的，所述固体载体由 （a）卤化镁的反应，（b）下式表示的化合物：Al（OR）nX3-n，其中R为碳原子数为1〜24的烃残基，X为氢原子，n为 0
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公开(公告)号：US5120472A
公开(公告)日：1992-06-09
申请号：US359530
申请日：1989-06-01
摘要： A polymer composition which is superior in processability, exhibits an extremely superior electroconductive characteristic when doped using an electron acceptor, and which comprises.(A) a copolymer represented by the following general formula (I): ##STR1## wherein R.sup.1 is a hydrogen atom or a hydrocarbon residue having 1 to 20 carbon atoms, R.sup.2 is a hydrogen atom, a hydrocarbon residue having 1 to 20 carbon atoms, furyl, pyridyl, nitrophenyl, chlorophenyl, or methoxyphenyl, n and x are each an integer not smaller than 2; and(B) one or more compounds selected from the group consisting of: polypyrrole compounds represented by the following general formula (II): ##STR2## wherein R.sup.3, R.sup.4 and R.sup.5 are each a hydrogen atom or a hydrocarbon residue having 1 to 20 carbon atoms, and p is an integer not smaller than 2; polythiophene compounds represented by the following general formula (III): ##STR3## wherein R.sup.6 and R.sup.7 are each a hydrogen atom or a hydrocarbon residue having 1 to 10 carbon atoms, and q is an integer not smaller than 2, and polyaniline compounds represented by the following general formula (IV): ##STR4## wherein R.sup.8, R.sup.9, R.sup.10 and R.sup.11 are each a hydrogen atom or a hydrocarbon residue having 1 to 10 carbon atoms, and r is an integer not smaller than 2.
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公开(公告)号：US5116708A
公开(公告)日：1992-05-26
申请号：US447649
申请日：1989-12-08
摘要： A hole transporting material is constituted by a compound represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5, which may be the same or different, are each independently hydrogen or a hydrocarbon residue having 1 to 20 carbon atoms; Ar.sup.1 and Ar.sup.2 are each independently a divalent hydrocarbon residue; l is an integer of 0 or more; m is an integer of 1 or more; and n is an integer of 2 or more.
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公开(公告)号：US5006633A
公开(公告)日：1991-04-09
申请号：US395803
申请日：1989-08-18
摘要： An electroactive polymer is obtained by doping a copolymer represented by the following general formula (I): ##STR1## wherein R.sup.1 is hydrogen or a hydrocarbon residue having 1 to 20 carbon atoms; R.sup.2 is hydrogen, a hydrocarbon residue having 1 to 20 carbon atoms, furyl, pyridyl, nitrophenyl, chlorophenyl, or methoxyphenyl; l is an integer not smaller than 2; m is an integer not smaller than 1; and n is an integer not smaller than 2.
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公开(公告)号：US4507448A
公开(公告)日：1985-03-26
申请号：US374627
申请日：1982-05-04
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/906
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed, which is carried out in the presence of a catalyst system comprising the combination of at least one organometallic compound with a component resulting from the reaction of (a) a magnesium halide, (b) a compound represented by the formula, Al(OR).sub.n X.sub.3-n, where R is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a hydrogen atom, and n is 0.ltoreq.n.ltoreq.3, (c) a compound represented by the formula, Si(OR').sub.m X.sub.4-m, where R' is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a halogen atom, and m is 0.ltoreq.m.ltoreq.4, and (d) a titanium compound and/or a vanadium compound. The resulting polymers have a large bulk density and a narrow range of molecular weight distribution.
摘要翻译： 公开了一种用于烯烃均聚或共聚的方法，该催化剂体系包括至少一种有机金属化合物与由（a）卤化镁反应得到的组分的组合的催化剂体系，（b） 由式Al（OR）nX3-n表示的化合物，其中R是具有1至20个碳原子的烃残基，X是氢原子，n是0
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公开(公告)号：US4518752A
公开(公告)日：1985-05-21
申请号：US551516
申请日：1983-11-15
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/906
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed, which is carried out in the presence of an improved catalyst comprising a solid catalyst component and an organometal compound, said solid catalyst component being obtained by the reaction of: (a) a magnesium halide, (b) a compound represented by the formula: Me(OR).sub.n X.sub.z-n where Me is any of the Group I-VIII elements of the Periodic Table, excluding Al, Si, Ti and V, R is a hydrocarbon residual group having 1-24 carbon atoms, X is a halogen atom, z represents the valence of Me and n is 0
摘要翻译： 公开了一种烯烃均聚或共聚合的方法，该方法在包含固体催化剂组分和有机金属化合物的改进催化剂存在下进行，所述固体催化剂组分通过以下反应获得：（a）卤化镁 ，（b）由Me（OR）n X z-n表示的化合物，其中Me是元素周期表中的I-VIII族元素中的任何一种，不包括Al，Si，Ti和V，R是具有 1-24个碳原子，X是卤素原子，z代表Me的价数，n是0
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公开(公告)号：US4088812A
公开(公告)日：1978-05-09
申请号：US752003
申请日：1976-12-20
CPC分类号： C08F10/00
摘要： This invention discloses an improved catalyst for the polymerization or copolymerization of olefins, and a process for preparing polyolefins which comprises polymerizing or copolymerizing olefins using the said catalyst. According to the invention there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins using as a catalyst at least one compound selected from the group consisting of a titanium compound and a vanadium compound supported on a solid carrier, and an organometallic compound, said solid carrier comprising a product obtained by treatment with SO.sub.3 of at least one member selected from the group consisting of an oxide of Group II-IV metals of the Periodic Table and a double oxide of the said oxide and other oxide, which other oxide may be another oxide of Group II-IV metals of the Periodic Table or may be an oxide of other Group metals of the same Table.
摘要翻译： 本发明公开了一种用于烯烃聚合或共聚的改进催化剂，以及一种制备聚烯烃的方法，该方法包括使用所述催化剂聚合或共聚烯烃。 根据本发明，提供了一种通过使用至少一种选自负载在固体载体上的钛化合物和钒化合物和有机金属化合物的化合物作为催化剂聚合或共聚烯烃的方法，所述方法 固体载体，其包含通过用SO 3处理由选自元素周期表中的II-IV族金属的氧化物和所述氧化物和其它氧化物的二氧化物中的至少一种获得的产物，其它氧化物可以是 元素周期表第II-Ⅳ族金属的另一种氧化物，或者可以是同一表中其他族金属的氧化物。
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公开(公告)号：US4202953A
公开(公告)日：1980-05-13
申请号：US6431
申请日：1979-01-25
摘要： A process for the production of polyolefins using an improved catalyst which exhibits enhanced activity in the polymerization or copolymerization of olefins such that the yields of the polymers or copolymers are increased with a minimum catalyst residue remaining. The catalyst is produced by reacting a magnesium dihalide anhydride with an aluminum alkoxy compound to produce a carrier on which a titanium compound and/or a vanadium compound is applied. The molar ratio of magnesium dihalide to aluminum compound ranges between 1:0.001 to 1:20, and most effectively is in the range of 1:0.05 to 1:5.
摘要翻译： 使用改进的催化剂生产聚烯烃的方法，其在烯烃的聚合或共聚中表现出增强的活性，使得聚合物或共聚物的产率随着剩余的最小催化剂残余物而增加。 该催化剂是通过使二卤化镁酐与一种烷氧基铝化合物反应制得一种其上涂有钛化合物和/或钒化合物的载体。 二卤化镁与铝化合物的摩尔比范围在1:0.001- 1:20之间，最有效地在1:0.05至1:5的范围内。
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公开(公告)号：US4154915A
公开(公告)日：1979-05-15
申请号：US575788
申请日：1975-05-08
CPC分类号： C08F10/00
摘要： An improved catalyst system is disclosed for use in the polymerization or copolymerization of olefins. The catalyst comprises a transition metal compound, an organometal compound and a composite carrier. This carrier is constituted by a SO.sub.3 treated alumina and a magnesium and/or a calcium compound. The polymerization or copolymerization of olefins such as ethylene, propylene and 1-butene is effected under conditions similar to those for reactions by means of Ziegler catalysts, but the resulting polyolefins have a wider molecular weight distribution, viz, a larger flow parameter as required for extrusion or blow molding.
摘要翻译： 公开了用于烯烃聚合或共聚的改进的催化剂体系。 催化剂包括过渡金属化合物，有机金属化合物和复合载体。 该载体由SO 3处理的氧化铝和镁和/或钙化合物构成。 烯烃如乙烯，丙烯和1-丁烯的聚合或共聚在与通过齐格勒催化剂进行反应的条件类似的条件下进行，但是得到的聚烯烃具有更宽的分子量分布， 挤出或吹塑。
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公开(公告)号：US5079317A
公开(公告)日：1992-01-07
申请号：US420556
申请日：1989-10-11
摘要： A process for producing polyethylene is disclosed in which ethylene is polymerized in the presence of a composite catalyst. The catalyst is made up of a solid catalyst component typified by a selected chromium compound, a modified aluminum compound typified by a trialkylaluminum and an R.sub.n.sup.1 Al(OR.sup.2).sub.3-n compound wherein R.sup.1 and R.sup.2 are represented by selected hydrocarbon groups and n by 0.ltoreq.n.ltoreq.3. The polymer has improved melt index, flow parameter and melt tension characteristics.
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