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21.发明授权Optimized cell configurations for stable LSCF-based solid oxide fuel cells 有权稳定的基于LSCF的固体氧化物燃料电池的优化电池配置公开(公告)号：US08182965B2
公开(公告)日：2012-05-22
申请号：US12241277
申请日：2008-09-30
申请人： Jin Yong Kim , Vincent L. Sprenkle , Nathan L. Canfield , Kerry D. Meinhardt , Lawrence A. Chick
发明人： Jin Yong Kim , Vincent L. Sprenkle , Nathan L. Canfield , Kerry D. Meinhardt , Lawrence A. Chick
CPC分类号： H01M4/8885 , H01M4/8605 , H01M4/9033 , H01M4/905
摘要： Lanthanum strontium cobalt iron oxides (La(1-x)SrxCoyFe1-yO3-f; (LSCF) have excellent power density (>500 mW/cm2 at 750° C.). When covered with a metallization layer, LSCF cathodes have demonstrated increased durability and stability. Other modifications, such as the thickening of the cathode, the preparation of the device by utilizing a firing temperature in a designated range, and the use of a pore former paste having designated characteristics and combinations of these features provide a device with enhanced capabilities.
摘要翻译： 镧锶钴铁氧化物（La（1-x）SrxCoyFe1-yO3-f;（LSCF）具有优异的功率密度（750℃时> 500 mW / cm2），当被金属化层覆盖时，LSCF阴极显示出增加 耐久性和稳定性，其它的改进，例如阴极增厚，通过利用指定范围内的烧制温度制备器件，以及使用具有指定特征和这些特征的组合的成孔剂膏体， 增强功能。
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22.发明申请GLASS COMPOSITION AND PROCESS FOR SEALING VOID SPACES IN ELECTROCHEMICAL DEVICES 有权玻璃组合物和在电化学设备中密封空隙的方法公开(公告)号：US20110226017A1
公开(公告)日：2011-09-22
申请号：US12729096
申请日：2010-03-22
申请人： Kerry D. Meinhardt , Brent W. Kirby
发明人： Kerry D. Meinhardt , Brent W. Kirby
CPC分类号： C03C8/24 , C03C11/007 , H01M8/0282 , H01M8/0286 , H01M2008/1293
摘要： A glass foaming material and method are disclosed for filling void spaces in electrochemical devices. The glass material includes a reagent that foams at a temperature above the softening point of the glass. Expansion of the glass fills void spaces including by-pass and tolerance channels of electrochemical devices. In addition, cassette to cassette seals can also be formed while channels and other void spaces are filled, reducing the number of processing steps needed.
摘要翻译： 公开了用于填充电化学装置中的空隙的玻璃发泡材料和方法。 玻璃材料包括在高于玻璃软化点的温度下发泡的试剂。 玻璃的膨胀填充空隙，包括电化学装置的旁路和公差通道。 此外，也可以在填充通道和其他空隙空间的同时形成盒式密封件，减少了所需的处理步骤的数量。
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公开(公告)号：US20110092361A1
公开(公告)日：2011-04-21
申请号：US12972801
申请日：2010-12-20
CPC分类号： H01M4/90 , B01J23/83 , B01J23/894 , H01M4/8885 , H01M4/9066 , H01M2008/1293
摘要： Methods for improving the sulfur-tolerance of nickel-based catalyst systems, as well as the improved catalyst systems, are disclosed. The methods can include adding praseodymium alone, or in combination with ruthenium and/or cerium, to a nickel-based catalyst system, thereby inhibiting sulfur poisoning of the catalyst system. Improved catalyst systems can have an added amount of praseodymium alone, or in combination with ruthenium and/or cerium, sufficient to inhibit poisoning of the system by sulfur.
摘要翻译： 公开了用于提高镍基催化剂体系耐硫性的方法以及改进的催化剂体系。 所述方法可以包括将镨单独添加或与钌和/或铈组合加入到镍基催化剂体系中，从而抑制催化剂体系的硫中毒。 改进的催化剂体系可以单独添加镨，或与钌和/或铈组合，足以抑制硫系统的中毒。
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公开(公告)号：US07879754B2
公开(公告)日：2011-02-01
申请号：US12106423
申请日：2008-04-21
IPC分类号： B01J23/10
CPC分类号： H01M4/90 , B01J23/83 , B01J23/894 , H01M4/8885 , H01M4/9066 , H01M2008/1293
摘要： Methods for improving the sulfur-tolerance of nickel-based catalyst systems, as well as the improved catalyst systems, are disclosed. The methods can include adding praseodymium alone, or in combination with ruthenium and/or cerium, to a nickel-based catalyst system, thereby inhibiting sulfur poisoning of the catalyst system. Improved catalyst systems can have an added amount of praseodymium alone, or in combination with ruthenium and/or cerium, sufficient to inhibit poisoning of the system by sulfur.
摘要翻译： 公开了用于提高镍基催化剂体系耐硫性的方法以及改进的催化剂体系。 所述方法可以包括将镨单独添加或与钌和/或铈组合加入到镍基催化剂体系中，从而抑制催化剂体系的硫中毒。 改进的催化剂体系可以单独添加镨，或与钌和/或铈组合，足以抑制硫系统的中毒。
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25.发明申请OPTIMIZED CELL CONFIGURATIONS FOR STABLE LSCF-BASED SOLID OXIDE FUEL CELLS 有权用于稳定的基于LSCF的固体氧化物燃料电池的优化电池配置公开(公告)号：US20100081035A1
公开(公告)日：2010-04-01
申请号：US12241277
申请日：2008-09-30
申请人： Jin Yong Kim , Vincent L. Sprenkle , Nathan L. Canfield , Kerry D. Meinhardt , Lawrence A. Chick
发明人： Jin Yong Kim , Vincent L. Sprenkle , Nathan L. Canfield , Kerry D. Meinhardt , Lawrence A. Chick
IPC分类号： H01M4/08
CPC分类号： H01M4/8885 , H01M4/8605 , H01M4/9033 , H01M4/905
摘要： Lanthanum strontium cobalt iron oxides (La(1-x)SrxCoyFe1-yO3-f; (LSCF) have excellent power density (>500 mW/cm2 at 750° C.). When covered with a metallization layer, LSCF cathodes have demonstrated increased durability and stability. Other modifications, such as the thickening of the cathode, the preparation of the device by utilizing a firing temperature in a designated range, and the use of a pore former paste having designated characteristics and combinations of these features provide a device with enhanced capabilities.
摘要翻译： 镧锶钴铁氧化物（La（1-x）SrxCoyFe1-yO3-f;（LSCF）具有优异的功率密度（750℃时> 500 mW / cm2），当被金属化层覆盖时，LSCF阴极显示出增加 耐久性和稳定性，其它的改进，例如阴极增厚，通过利用指定范围内的烧制温度制备器件，以及使用具有指定特征和这些特征的组合的成孔剂膏体， 增强功能。
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26.发明申请SUPPORTING ELECTRODES FOR SOLID OXIDE FUEL CELLS AND OTHER ELECTROCHEMICAL DEVICES 有权支持固体氧化物燃料电池和其他电化学装置的电极公开(公告)号：US20080038611A1
公开(公告)日：2008-02-14
申请号：US10425857
申请日：2003-04-28
IPC分类号： H01M8/12
CPC分类号： H01M4/8885 , H01M4/9016 , H01M4/9025 , H01M8/1253 , H01M2008/1293 , Y02E60/525 , Y02P70/56
摘要： An electrode supported electrolyte membrane includes an electrode layer 630 facing an electrolyte layer 620. The opposing side of the electrode layer 630 includes a backing layer 640 of a material with a thermal expansion coefficient approximately equal to the thermal expansion coefficient of the electrolyte layer 620. The backing layer 640 is in a two dimensional pattern that covers only a portion of the electrolyte layer 630. An electrochemical cell such as a SOFC is formed by providing a cathode layer 610 on an opposing side of the electrolyte layer 620.
摘要翻译： 电极支撑的电解质膜包括面向电解质层620的电极层630.电极层630的相对侧包括热膨胀系数近似等于电解质层620的热膨胀系数的材料的背衬层640。 背衬层640是仅覆盖电解质层630的一部分的二维图案。通过在电解质层620的相对侧上设置阴极层610来形成诸如SOFC的电化学电池。
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27.发明授权公开(公告)号：US07306872B2
公开(公告)日：2007-12-11
申请号：US11027095
申请日：2004-12-30
申请人： Karl J. Haltiner, Jr. , Subhasish Mukerjee , Lawrence A. Chick , Kerry D. Meinhardt , Dean M. Paxton , Vincent L. Sprenkle , K. Scott Weil , John E. Deibler , Paul E. George, II , Kurtis P. Recknagle
发明人： Karl J. Haltiner, Jr. , Subhasish Mukerjee , Lawrence A. Chick , Kerry D. Meinhardt , Dean M. Paxton , Vincent L. Sprenkle , K. Scott Weil , John E. Deibler , Paul E. George, II , Kurtis P. Recknagle
CPC分类号： H01M8/2425 , H01M8/0232 , H01M8/0247 , H01M8/0282 , H01M8/247 , H01M8/2483 , H01M2008/1293
摘要： A modular fuel cell cassette for use in assembling a fuel cell stack comprising a metal separator plate and a metal cell-mounting plate joined at their edges to form a hollow cassette. A fuel cell subassembly is attached to the mounting plate and extends through an opening in the mounting plate. The plates include openings to form chimney manifolds for supply and exhaust of fuel gas to the anode and air to the cathode. A conductive interconnect element extends from the fuel cell subassembly to make contact with the next cassette in a stack. The anode openings in the mounting plate and separator plate are separated by spacer rings such that the cassette is incompressible. A fuel cell stack comprises a plurality of cassettes, the mounting plate of one cassette being attached to, and insulated from, the separator plate of the next-adjacent cassette by a dielectric seal surrounding the interconnect.
摘要翻译： 一种用于组装燃料电池堆的模块化燃料电池盒，包括金属隔板和在其边缘连接以形成中空盒的金属电池安装板。 燃料电池子组件附接到安装板并延伸穿过安装板中的开口。 这些板包括用于形成烟囱歧管的开口，用于将燃料气体供给和排出到阳极和空气到阴极。 导电互连元件从燃料电池子组件延伸以与堆叠中的下一个盒体接触。 安装板和隔离板中的阳极开口由间隔环分开，使得盒不可压缩。 燃料电池堆包括多个盒，一个盒的安装板通过围绕互连的电介质密封件附接到下一相邻盒的隔板并与之隔绝。
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28.发明授权公开(公告)号：US11193696B2
公开(公告)日：2021-12-07
申请号：US15937776
申请日：2018-03-27
摘要： A process for liquefying a process gas that includes introducing a heat transfer fluid into an active magnetic regenerative refrigerator apparatus that comprises a single stage comprising dual multilayer regenerators located axially opposite to each other.
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29.发明授权公开(公告)号：US08293426B2
公开(公告)日：2012-10-23
申请号：US12242165
申请日：2008-09-30
CPC分类号： H01M8/0273 , H01M8/0247 , H01M8/0256 , H01M8/028 , H01M8/1231 , H01M8/2475 , Y10T29/4911
摘要： Solid-oxide fuel cell (SOFC) stack assembly designs are consistently investigated to develop an assembly that provides optimal performance, and durability, within desired cost parameters. A new design includes a repeat unit having a SOFC cassette and being characterized by a three-component construct. The three components include an oxidation-resistant, metal window frame hermetically joined to an electrolyte layer of a multi-layer, anode-supported ceramic cell and a pre-cassette including a separator plate having a plurality of vias that provide electrical contact between an anode-side collector within the pre-cassette and a cathode-side current collector of an adjacent cell. The third component is a cathode-side seal, which includes a standoff that supports a cathode channel spacing between each of the cassettes in a stack. Cassettes are formed by joining the pre-cassette and the window frame.
摘要翻译： 一贯研究固体氧化物燃料电池（SOFC）堆叠组件设计，以开发在所需成本参数内提供最佳性能和耐久性的组件。 一种新的设计包括具有SOFC盒的重复单元，其特征在于三组分构造。 三个部件包括与多层阳极支撑的陶瓷电池的电解质层气密接合的耐氧化金属窗框，以及包括隔板的预磁带，隔板具有提供阳极之间的电接触的多个通孔 内部集电器和相邻电池的阴极侧集电器。 第三部件是阴极侧密封件，其包括支撑在叠层中的每个盒之间的阴极通道间隔的支架。 通过连接前盒和窗框形成盒。
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30.发明授权Glass composition and process for sealing void spaces in electrochemical devices 有权用于密封电化学装置空隙的玻璃组成和工艺公开(公告)号：US08166777B2
公开(公告)日：2012-05-01
申请号：US12729096
申请日：2010-03-22
申请人： Kerry D. Meinhardt , Brent W. Kirby
发明人： Kerry D. Meinhardt , Brent W. Kirby
IPC分类号： H01M2/08
CPC分类号： C03C8/24 , C03C11/007 , H01M8/0282 , H01M8/0286 , H01M2008/1293
摘要： A glass foaming material and method are disclosed for filling void spaces in electrochemical devices. The glass material includes a reagent that foams at a temperature above the softening point of the glass. Expansion of the glass fills void spaces including by-pass and tolerance channels of electrochemical devices. In addition, cassette to cassette seals can also be formed while channels and other void spaces are filled, reducing the number of processing steps needed.
摘要翻译： 公开了用于填充电化学装置中的空隙的玻璃发泡材料和方法。 玻璃材料包括在高于玻璃软化点的温度下发泡的试剂。 玻璃的膨胀填充空隙，包括电化学装置的旁路和公差通道。 此外，也可以在填充通道和其他空隙空间的同时形成盒式密封件，减少了所需的处理步骤的数量。
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