Abstract:
Disclosed are a transition metal precursor for preparation of a lithium composite transition metal oxide, the transition metal precursor including a composite transition metal compound represented by Formula 1 below and a hydrocarbon compound, and a method of preparing the same: MnaMb(OH1−x)2 (1) wherein M is at least two selected from the group consisting of Ni, Co, Mn, Al, Cu, Fe, Mg, B, Cr, and second period transition metals; 0.4≦a≦1; 0≦b≦0.6; a+b≦1; and 0
Abstract:
The present invention provides a negative electrode active material for a secondary battery, the negative electrode active material including a core that includes a lithium titanium oxide and a surface treatment layer located on a surface of the core, wherein the surface treatment layer includes a boron-containing lithium oxide at an amount that allows a boron content to have a molar ratio of 0.002 to 0.02 with respect to 1 mole of the lithium titanium oxide, and when 2 g of the negative electrode active material is titrated at pH 5 or lower using 0.1 M HCl, a titrated amount is 0.9 to 1.5 ml, and a secondary battery including the same. The negative electrode active material exhibits an excellent capacity recovery rate and an output characteristic when applied to a battery and is capable of reducing gas generation by preventing electrolyte decomposition.
Abstract:
Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2 (1) wherein M is represented by MnaM′1-b, M′ is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95≤x≤1.5, and 0.5≤a≤1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.
Abstract:
The present invention provides a lithium secondary battery, including a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, and a separator provided between the positive electrode and the negative electrode, wherein the negative electrode active material may include a titanium-based composite, wherein, when the lithium secondary battery is charged to SOC 50 under C-rate conditions of 0.1 to 40 C, the titanium-based composite has a ratio of the peak area of a plane (400) and the peak area of a plane (111) of 0.76 or more in a measured X-ray diffraction spectrum (XRD). Therefore, the present invention may provide a lithium secondary battery having excellent output characteristics and a battery pack in which a BMS prediction algorithm is simplified.
Abstract:
Disclosed are a precursor for preparation of a lithium composite transition metal oxide, a method for preparing the same and a lithium composite transition metal oxide obtained from the same. More particularly, the transition metal precursor which has a composition represented by Formula 1 below and is prepared in an aqueous transition metal solution, mixed with a transition metal-containing salt, including an alkaline material, the method for preparing the same and the lithium composite transition metal oxide obtained from the same are disclosed. MnaMb(OH1-x)2-yAy (1) wherein M is at least one selected form the group consisting of Ni, Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals; A is at least one selected form the group consisting of anions of PO4, BO3, CO3, F and NO3, and 0.5≤a≤1.0; 0≤b≤0.5; a+b=1; 0
Abstract:
Disclosed is a lithium-cobalt based complex oxide represented by Formula 1 below including lithium, cobalt and manganese wherein the lithium-cobalt based complex oxide maintains a crystal structure of a single O3 phase at a state of charge (SOC) of 50% or more based on a theoretical amount: LixCo1-y-zMnyAzO2 (1) wherein 0.95≤x≤1.15, 0
Abstract:
The present invention relates to an active material for a lithium secondary battery, which includes a secondary particle formed by agglomeration of primary particles which include a lithium titanium composite oxide represented by Formula 1 or Formula 2, wherein a pore volume is in a range of 0.001 cm3/g to 0.05 cm3/g, and a method of preparing the same, wherein the active material for a lithium secondary battery according to the present invention may maintain an adequate pore volume even during rolling, because strength of the secondary particle is improved by controlling a particle diameter of the primary particle by introducing a metallic element.
Abstract:
Disclosed is a lithium-cobalt based complex oxide represented by Formula 1 below including lithium, cobalt and manganese wherein the lithium-cobalt based complex oxide maintains a crystal structure of a single O3 phase at a state of charge (SOC) of 50% or more based on a theoretical amount: LixCo1-y-zMnyAzO2 (1) wherein 0.95≦x≦1.15, 0≦y≦0.3 and 0≦z≦0.2; and A is at least one element selected the group consisting of Al, Mg, Ti, Zr, Sr, W, Nb, Mo, Ga, and Ni.
Abstract:
Disclosed is a lithium manganese (Mn)-based oxide including Mn as an essential transition metal and having a layered crystal structure, in which the amount of Mn is greater than that of other transition metal(s), the lithium manganese-based oxide exhibits flat level section characteristics in which release of oxygen occurs together with lithium deintercalation during first charging in a high voltage range of 4.4 V or higher, and at least one of a transition metal layer including Mn and an oxygen layer is substituted or doped with a pillar element.
Abstract:
Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2 (1) wherein M is represented by MnaM′1-b, M′ is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95≦x≦1.5, and 0.5≦a≦1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.