Abstract:
An electrolyte for a lithium secondary battery of the present invention may improve high-rate charge and discharge characteristics and high-temperature storage and life characteristics of a lithium secondary battery and may achieve an effect of increasing reversible capacity by simultaneously including lithium bis(fluorosulfonyl)imide (LiFSI) and a second lithium salt, as a lithium salt, while including a second additive as well as a novel borate-based lithium compound, as an additive.
Abstract:
The present invention relates to a non-aqueous electrolyte solution including a non-aqueous organic solvent, a lithium salt, and an oligomer represented by Formula 1 described in the present specification, and a lithium secondary battery including the same. Since the non-aqueous electrolyte solution according to an embodiment of the present invention may reduce gas, such as CO or CO2, generated in the secondary battery during high-temperature storage, it may further improve high-temperature stability of the lithium secondary battery.
Abstract:
The present invention relates to a non-aqueous electrolyte solution which includes an ionizable lithium salt, an organic solvent, and a mixed additive, wherein the organic solvent comprises at least one cyclic carbonate-based organic solvent selected from the group consisting of ethylene carbonate, 1,2-butylene carbonate, 2,3-butylene carbonate, 1,2-pentylene carbonate, 2,3-pentylene carbonate, vinylene carbonate, and fluoroethylene carbonate, and at least one linear carbonate-based organic solvent selected from the group consisting of dimethyl carbonate, diethyl carbonate, dipropyl carbonate, ethylmethyl carbonate, methylpropyl carbonate, and ethylpropyl carbonate, the mixed additive includes vinylene carbonate, 1,3-propylene sulfate, and 1,3-propane sultone in a weight ratio of 1:1:1 to 1:0.5:0.2, and a total amount of the mixed additive is in a range of 1 to 4.5 wt % based on a total weight of the non-aqueous electrolyte solution for a lithium secondary battery, and a lithium secondary battery including the same.
Abstract:
The present invention relates to a composition for a gel polymer electrolyte comprising a liquid electrolyte solvent, a lithium salt, a polymerization initiator, and a mixed compound of a first compound and a second compound, and a lithium secondary battery comprising a positive electrode, a negative electrode, a separator, and a gel polymer electrolyte, wherein the gel polymer electrolyte is formed by polymerizing the composition for a gel polymer electrolyte. By comprising a mixed compound of a first compound and a second compound in which the first compound is an amine-based compound comprising polyethylene glycol as a functional group and the second compound is an epoxy-based compound, a composition for a gel polymer electrolyte of the present invention exhibits, when used in a lithium secondary battery, enhanced battery lifespan, excellent high temperature storability, and enhanced battery capacity property by readily inducing a hopping phenomenon.
Abstract:
The present invention relates to a polymer electrolyte, which includes a lithium salt and a copolymer including a fluorine-substituted or unsubstituted polyalkylene ether repeating unit, and a lithium secondary battery including the same.
Abstract:
The present invention relates to a lithium secondary battery comprising a non-aqueous electrolyte solution comprising lithium bis(fluorosulfonyl)imide (LiFSI) and a phosphazene compound as additives, a positive electrode comprising a lithium-nickel-manganese-cobalt-based oxide as a positive electrode active material, a negative electrode and a separator. According to a non-aqueous electrolyte solution for a lithium secondary battery of the present invention, a rigid SEI layer may be formed at a negative electrode during the initial charging of the lithium secondary battery comprising the same, the output properties of the lithium secondary battery may be improved, and the output properties after storing at high temperature and capacity properties may be increased.
Abstract:
An additive for an electrolyte solution includes a lithium salt having an oxalato complex as an anion and a compound represented by following Chemical Formula 1. Wherein, a represents C or Si, b represents H or F, and n represents an integer of 1 to 5. A non-aqueous electrolyte solution including the additive and a lithium secondary battery including the electrolyte solution also are provided.
Abstract:
The present invention relates to a lithium secondary battery comprising a non-aqueous liquid electrolyte comprising lithium bis(fluorosulfonyl)imide (LiFSI) and a fluorinated ether compound as additives, a positive electrode comprising a lithium-nickel-manganese-cobalt-based oxide as a positive electrode active material, a negative electrode and a separator. According to a non-aqueous liquid electrolyte for a lithium secondary battery of the present invention, a rigid SEI layer may be formed at a negative electrode during the initial charging of the lithium secondary battery comprising the same, the output properties of the lithium secondary battery may be improved, and the output properties after storing at high temperature and capacity properties may be increased.
Abstract:
Disclosed is a lithium secondary battery having improved lifespan characteristics. More particularly, a lithium secondary battery comprising a cathode, an anode, a separator interposed between the cathode and anode, and an electrolyte, wherein the anode comprises lithium titanium oxide (LTO) as an anode active material, the electrolyte comprises a lithium salt; a non-aqueous-based solvent; and (a) a phosphate compound which can prevent gas generation during high-temperature storage, (b) a sulfonate compound which can reduce discharge resistance by forming a low-resistance SEI layer, or a mixture of the compound (a) and the compound (b), is disclosed.
Abstract:
Provided are a non-aqueous electrolyte including a non-aqueous organic solvent, a lithium salt, and a borate-based compound, and a lithium secondary battery using the same. According to the present invention, a lithium secondary battery having improved cycle characteristics and high-temperature storage stability may be prepared by including a non-aqueous electrolyte which includes at least one borate-based compound as an additive.