公开(公告)号：US20130137568A1

公开(公告)日：2013-05-30

申请号：US13307215

申请日：2011-11-30

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/654

CPC classification number: C08F110/06 ,  C08F4/6494 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6543 ,  C08F4/6545

Abstract: The presently disclosed and claimed inventive concept(s) relates to solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound having at least one ester group and at least one alkoxy group, and catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds. The presently disclosed and claimed inventive concept(s) further relates to methods of making the catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.

Abstract translation: 目前公开和要求保护的发明构思涉及包含钛，镁，卤素和具有至少一个酯基和至少一个烷氧基的内电子给体化合物的固体催化剂组分，以及含有催化剂固体组分的催化剂体系，有机铝 化合物和有机硅化合物。 目前公开和要求保护的发明构思还涉及制备催化剂组分和催化剂体系的方法，以及使用催化剂体系聚合或共聚α-烯烃的方法。

公开(公告)号：US20120116031A1

公开(公告)日：2012-05-10

申请号：US12943512

申请日：2010-11-10

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/16 ,  B01J31/14

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F4/651

Abstract: A catalyst system containing (a) a solid catalyst component containing a titanium halide, a magnesium halide, a first internal electron donor compound, and a second internal electron donor compound, (b) an organoaluminum compound, and (c) an external electron donor compound is disclosed. The first internal electron donor compound contains at least one ether group and at least one ketone group. The second internal electron donor compound is a 1,8-naphthyl diester compound. Methods of polymerizing or copolymerizing alpha-olefins using the catalyst system also are disclosed.

Abstract translation: 一种催化剂体系，其包含（a）含有卤化钛，卤化镁，第一内部电子给体化合物和第二内部电子给体化合物的固体催化剂组分，（b）有机铝化合物和（c）外部电子给体 公开了化合物。 第一内给电子体化合物含有至少一个醚基和至少一个酮基。 第二内电子给体化合物是1,8-萘基二酯化合物。 还公开了使用催化剂体系聚合或共聚α-烯烃的方法。

公开(公告)号：US20070243998A1

公开(公告)日：2007-10-18

申请号：US11753471

申请日：2007-05-24

Applicant: Zhidong Zhu ,  Main Chang

Inventor： Zhidong Zhu ,  Main Chang

IPC: B01J31/38 ,  B01J21/16 ,  B01J29/04 ,  B01J31/26

CPC classification number: C08F110/06 ,  C08F210/16 ,  C08F4/6545 ,  C08F4/651 ,  C08F4/025 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/24 ,  C08F210/06

Abstract: Disclosed are catalyst systems and methods of making the catalyst systems for the polymerization of an olefin containing a solid titanium catalyst component containing an inorganic titanium compound, a magnesium alcohol adduct made from an inorganic magnesium compound and an alcohol, and a porous support having at least one of a certain specific surface area, a certain pore volume, and a certain median particle size. The catalyst system may further contain an organoaluminum compound and optionally an organosilicon compound. Also disclosed are methods of making polyolefins.

Abstract translation: 公开了催化剂体系和制备用于聚合含有含有无机钛化合物的固体钛催化剂组分的烯烃的催化剂体系，由无机镁化合物和醇制成的镁醇加合物的催化剂体系和至少具有至少 一定的比表面积，一定的孔体积和一定的中值粒径之一。 催化剂体系还可以含有有机铝化合物和任选的有机硅化合物。 还公开了制备聚烯烃的方法。

公开(公告)号：US20050288460A1

公开(公告)日：2005-12-29

申请号：US10879572

申请日：2004-06-28

Applicant: Zhidong Zhu ,  Main Chang ,  Christopher Aarons

Inventor： Zhidong Zhu ,  Main Chang ,  Christopher Aarons

IPC: B01J31/00 ,  C08F4/44 ,  C08F10/00 ,  C08F110/02

CPC classification number: C08F10/00 ,  C08F110/02 ,  Y02P20/52 ,  C08F4/6567 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/24

Abstract: Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of polyethylene containing a solid titanium catalyst component containing a titanium compound and a support made from a magnesium compound, an alkyl silicate, and a monoester. The catalyst system may further contain an organoaluminum compound. Also disclosed are methods of making various types of polyethylene involving polymerizing ethylene in the presence of hydrogen and a catalyst system containing a support made from a magnesium compound, an alkyl silicate and a monoester.

Abstract translation: 公开了制备用于聚合聚乙烯的催化剂体系和载体的方法，所述聚乙烯含有含钛化合物的固体钛催化剂组分和由镁化合物，硅酸烷基酯和单酯制成的载体。 催化剂体系还可以含有有机铝化合物。 还公开了制备各种类型的聚乙烯的方法，包括在氢存在下聚合乙烯和含有由镁化合物，硅酸烷基酯和单酯制成的载体的催化剂体系。

公开(公告)号：US5529965A

公开(公告)日：1996-06-25

申请号：US330893

申请日：1994-10-28

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/642 ,  C08F4/619 ,  C08F4/646 ,  C08F4/654 ,  C08F10/00 ,  B01J37/02 ,  C08F4/44

CPC classification number: C08F10/00 ,  C08F4/61904 ,  C08F4/61912 ,  C08F4/61916

Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported mixed metallocene/non-metallocene catalyst useful in a process for polymerizing olefins.

Abstract translation: 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 用于负载本发明的催化剂的方法提供了用于聚合烯烃的方法中的负载型混合茂金属/非茂金属催化剂。

公开(公告)号：US5086025A

公开(公告)日：1992-02-04

申请号：US567489

申请日：1990-08-14

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/639 ,  C08F4/6392 ,  C08F4/656 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65925 ,  Y10S526/943

Abstract: This invention relates to a process for preparing a supported metallocene alumoxane catalyst for use in the slurry or liquid phase polymerization of olefins. The invention particularly relates to the use of silica gel containing from about 10 to about 50 percent by weight adsorbed water as the catalyst support material. It has been found that such silica gel may be safely added to an aluminum trialkyl solution to form by direct reaction with the adsorbed water content of the silica gel catalyst support material the alumoxane component of the catalyst system. An alumoxane coated silica gel is formed to which a metallocene may be added. The resulting material can either be used in this slurry state for slurry polymerization or can be used for liquid phase polymerization of olefins.

Abstract translation: 本发明涉及制备用于烯烃淤浆或液相聚合的负载型金属茂铝氧烷催化剂的方法。 本发明特别涉及含有约10至约50重量％吸附水的硅胶作为催化剂载体材料的用途。 已经发现，通过与催化剂体系的硅氧烷组分的硅胶催化剂载体材料的吸附水含量的直接反应，可以将这种硅胶安全地加入到三烷基铝溶液中形成。 形成可以加入金属茂的铝氧烷涂覆的硅胶。 所得到的材料可以以这种淤浆状态用于淤浆聚合，也可以用于烯烃的液相聚合。

公开(公告)号：US4925821A

公开(公告)日：1990-05-15

申请号：US268834

申请日：1988-11-08

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/02 ,  C08F4/60 ,  C08F4/622 ,  C08F4/639 ,  C08F4/6392 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  C08F4/63922 ,  Y10S526/943

Abstract: This invention relates to a process for preparing a supported metallocene alumoxane catalyst for use in the polymerization of olefins. The invention particularly relates to the use of silica gel containing from about 6 to about 20 percent by weight adsorbed water as the catalyst support material. It has been found that such silica gel may be safely added to a solution, of trialkylaluminum to form by direct reaction with the adsorbed water content of the silica gel catalyst support material the majority of the alumoxane component requirement of the catalyst system. An alkylalumoxane coated silica gel is formed to which a trimethylaluminum treated metallocene may be added and the resulting material dried to free-flowing powder. The dry free flowing powder may then be used as a supported metallocene alumoxane catalyst complex for gas phase or liquid phase polymerization of olefins. The supported catalyst produced by such procedure has an activity at least comparable to a catalyst of similar composition which is produced exclusively with trimethylaluminum as the alumoxane forming aluminum alkyl.

Abstract translation: 本发明涉及制备用于烯烃聚合的负载金属茂铝氧烷催化剂的方法。 本发明特别涉及含有约6至约20重量％吸附水的硅胶作为催化剂载体材料的用途。 已经发现，通过与催化剂体系的大部分铝氧烷组分要求的硅胶催化剂载体材料的吸附水含量直接反应，可以将这种硅胶安全地加入到三烷基铝的溶液中。 形成烷基铝氧烷涂覆的硅胶，其中可以加入三甲基铝处理的茂金属，并将所得材料干燥成自由流动的粉末。 然后可将干燥的自由流动的粉末用作用于烯烃气相或液相聚合的负载金属茂铝氧烷催化剂络合物。 通过这种方法制备的负载型催化剂具有至少与类似组合物的催化剂相当的活性，该催化剂专门用作为形成烷基铝的铝氧烷的三甲基铝制备。

公开(公告)号：US4914253A

公开(公告)日：1990-04-03

申请号：US267216

申请日：1988-11-04

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F2/34 ,  C08F4/02 ,  C08F4/60 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F8/00 ,  C08F10/02 ,  C08F110/02

CPC classification number: C08F110/02 ,  C08F10/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/901 ,  Y10S526/943

Abstract: This invention relates to a process for preparing polyethylene wax having a narrow molecular weight distribution in a gas phase polymerization reactor. The invention particularly relates to the process of polymerizing ethylene in the presence of a supported metallocene-alumoxane catalyst and hydrogen. The catalyst may be derived from the addition of silica gel containing about 6 to about 20 percent by weight adsorbed water to a trialkylaluminum solution. An alumoxane coated silica gel is formed to which a metallocene may be added and the resulting material dried to free flowing powder. A trimethylaluminum pretreated metallocene may be employed when the trialkylaluminum is selected from the group consisting of triethylaluminum, tripropylaluminum, tri-n-butyl-aluminum, tri-isobutylaluminum, tri(2-methylpentyl)aluminum, trihexylaluminum, tri-n-octylaluminum and tri-n-decylaluminum.

公开(公告)号：US4814310A

公开(公告)日：1989-03-21

申请号：US134413

申请日：1987-12-17

Applicant: Main Chang

Inventor： Main Chang

Abstract: This invention relates to a process for preparing a supported metallocene alumoxane catalyst for use in the gas phase polymerization of olefins. The invention particularly relates to the use of silica gel containing from about 6 to about 10 percent by weight adsorbed water as the catalyst support material. It has been found that such silica gel may be safely added to an aluminum trialkyl solution to form by direct reaction with the adsorbed water content of the silica gel catalyst support material the alumoxane component of the catalyst system. An alumoxane coated silica gel is formed to which a metallocene may be added and the resulting material dried to free flowing powder. The dry free flowing powder may then be used as a supported metalllocene alumoxane catalyst complex for gas phase polymerization of olefins.

公开(公告)号：US09217047B2

公开(公告)日：2015-12-22

申请号：US14255050

申请日：2014-04-17

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C08F4/6494 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6543 ,  C08F4/6545

Abstract: The presently disclosed and claimed inventive concept(s) relates to solid catalyst components comprising titanium, magnesium, halogen and an internal electron donor compound having at least one ester group and at least one alkoxy group, and catalyst systems containing the catalyst solid components, organoaluminum compounds, and organosilicon compounds. The presently disclosed and claimed inventive concept(s) further relates to methods of making the catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.

Abstract translation: 目前公开和要求保护的发明构思涉及包含钛，镁，卤素和具有至少一个酯基和至少一个烷氧基的内电子给体化合物的固体催化剂组分，以及含有催化剂固体组分的催化剂体系，有机铝 化合物和有机硅化合物。 目前公开和要求保护的发明构思还涉及制备催化剂组分和催化剂体系的方法，以及使用催化剂体系聚合或共聚α-烯烃的方法。