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公开(公告)号：US5763368A
公开(公告)日：1998-06-09
申请号：US655539
申请日：1996-05-30
申请人： Michael M. Brezinski
发明人： Michael M. Brezinski
CPC分类号： C09K8/74 , C23F11/04 , C09K2208/32 , Y10S507/934 , Y10S507/939
摘要： The present invention provides corrosion inhibited well acidizing compositions and methods of using the compositions to acidize wells. The compositions basically comprise an aqueous acid solution, a corrosion inhibitor comprising at least one quaternary ammonium compound and a corrosion inhibitor intensifier comprised of aliphatic carboxylic acids, crude tall oil, tall oil fatty acids, rosin acids and mixtures thereof.
摘要翻译： 本发明提供腐蚀抑制良好的酸化组合物和使用该组合物来酸化孔的方法。 组合物基本上包含酸性水溶液，包含至少一种季铵化合物的腐蚀抑制剂和由脂族羧酸，粗妥尔油，妥尔油脂肪酸，松香酸及其混合物组成的缓蚀剂增强剂。
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公开(公告)号：US5756004A
公开(公告)日：1998-05-26
申请号：US855049
申请日：1997-05-13
申请人： Michael M. Brezinski
发明人： Michael M. Brezinski
CPC分类号： C23F11/04 , C09K8/54 , Y10S507/922 , Y10S507/923 , Y10S507/933 , Y10S507/934 , Y10S507/939
摘要： The present invention provides improved quaternary ammonium compounds useful as metal corrosion inhibitors in aqueous acid solutions, methods of preparing the compounds, metal corrosion inhibited aqueous acid solutions containing the compounds and methods of protecting metal surfaces from acid corrosion using the compounds. The compounds are prepared by contacting the still bottoms residue produced in the distillation of quinoline from coal tar with oxygen to oligomerize aromatic amines contained therein and then reacting the oligomerized amines with a benzylhalide.
摘要翻译： 本发明提供改进的季铵化合物，其用作酸性水溶液中的金属腐蚀抑制剂，制备化合物的方法，金属腐蚀抑制含有该化合物的酸性水溶液以及使用该化合物保护金属表面免受酸腐蚀的方法。 该化合物是通过使来自煤焦油的喹啉蒸馏产生的残余残留物与氧气接触而使其中所含的芳族胺低聚，然后使低聚胺与苄基卤反应来制备。
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23.发明授权Methods and acidizing compositions for reducing metal surface corrosion and sulfide precipitation 有权减少金属表面腐蚀和硫化物沉淀的方法和酸化组合物公开(公告)号：US06315045B1
公开(公告)日：2001-11-13
申请号：US09519933
申请日：2000-03-07
申请人： Michael M. Brezinski
发明人： Michael M. Brezinski
IPC分类号： E21B4327
CPC分类号： C09K8/72 , C09K8/74 , C09K2208/32 , C23F11/04 , Y10S166/902 , Y10S507/934 , Y10S507/939
摘要： Methods and acidizing compositions for reducing the corrosion of the metal surfaces of tubular goods and the like and reducing the precipitation of metal sulfide from the acidizing compositions are provided. The methods basically comprise the steps of combining an aldol-amine adduct with an aqueous acid solution to preferentially react with sulfide ions subsequently dissolved by the aqueous acid solution and thereby prevent subsequently dissolved metal ions from reacting therewith and precipitating, and then introducing the aqueous acid solution containing the aldol-amine adduct into a well or other location to be acidized.
摘要翻译： 提供了用于减少管状物品等的金属表面的腐蚀并且减少金属硫化物从酸化组合物沉淀的方法和酸化组合物。 所述方法基本上包括以下步骤：将醛醇 - 胺加合物与酸性水溶液组合以优先与随后由酸水溶液溶解的硫化物离子反应，从而防止随后溶解的金属离子与其反应并沉淀，然后将含水酸 将含有醛醇 - 胺加合物的溶液加入待酸化的孔或其它位置。
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公开(公告)号：US5976416A
公开(公告)日：1999-11-02
申请号：US855083
申请日：1997-05-13
申请人： Michael M. Brezinski
发明人： Michael M. Brezinski
CPC分类号： C23F11/141 , C09K8/54 , C23F11/04 , Y10S507/934 , Y10S507/939
摘要： The present invention provides corrosion inhibited organic acid compositions and methods of using the compositions. The compositions basically comprise water, an organic acid, a corrosion inhibitor comprising at least one quaternary ammonium compound and a corrosion inhibitor activator selected from the group consisting of thioglycolic acid, an alkali metal thiosulfate and mixtures thereof.
摘要翻译： 本发明提供腐蚀抑制有机酸组合物和使用该组合物的方法。 组合物基本上包含水，有机酸，包含至少一种季铵化合物的腐蚀抑制剂和选自巯基乙酸，碱金属硫代硫酸盐及其混合物的缓蚀剂活化剂。
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25.发明授权Method and composition for acidizing subterranean formations utilizing corrosion inhibitor intensifiers 失效使用腐蚀抑制剂增强剂酸化地下地层的方法和组成
公开(公告)号：US5697443A
公开(公告)日：1997-12-16
申请号：US599201
申请日：1996-02-09
申请人： Michael M. Brezinski , Bhadra Desai
发明人： Michael M. Brezinski , Bhadra Desai
摘要： The present invention provides a corrosion inhibitor intensifier for acidizing solutions for use in subterranean formation treatments wherein the corrosion inhibitor comprises a quaternary ammonium compound. The intensifier comprises an effective amount of a source of iodide ions and a source of formic acid.
摘要翻译： 本发明提供一种用于地下地层处理用酸化溶液的防腐剂增强剂，其中缓蚀剂包括季铵化合物。 增强剂包括有效量的碘离子源和甲酸源。
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公开(公告)号：US5674817A
公开(公告)日：1997-10-07
申请号：US949659
申请日：1992-11-19
CPC分类号： C09K8/528 , C09K8/62 , Y10S507/933
摘要： Methods and compositions for controlling iron in aqueous well fracturing fluids are disclosed. In accordance with the methods, ferric iron contained in a fracturing fluid is prevented from precipitating or otherwise disadvantageously reacting by adding a thioalkyl acid or derivative thereof to the fracturing fluid. The thioalkyl acid or derivative reduces ferric ion to ferrous ion which remains in solution at pH levels below about 7.5.
摘要翻译： 公开了用于控制含水井压裂液中铁的方法和组合物。 根据该方法，通过将硫代烷基酸或其衍生物加入到压裂液中，防止压裂液中所含的三价铁沉淀或以其他方式不利地发生反应。 硫代烷基酸或衍生物将铁离子还原成亚铁离子，其保留在溶液中，pH值低于约7.5。
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