公开(公告)号：US20060287454A1

公开(公告)日：2006-12-21

申请号：US10548365

申请日：2004-03-05

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F230/08 ,  C07F7/04

CPC分类号： C08G77/04 ,  C07F7/21 ,  C08F10/00 ,  C08F30/08 ,  C08F2500/03

摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.

摘要翻译： 本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构 聚合物作为分子聚集体。 其中R 1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可被氟取代，并且任选的-CH 2 - 可以被-O-，-CH-CH-，亚环烷基或 环亚烯基 在该芳烷基中的亚烷基中，任选的氢可以被氟取代，任选的-CH 2 - 可以被-O-或-CH-CH-取代; 且A 1是具有α-卤代酯键的基团。

公开(公告)号：US20070004932A1

公开(公告)日：2007-01-04

申请号：US11517457

申请日：2006-09-08

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

IPC分类号： C07F7/04 ,  C07F7/08

CPC分类号： C07F7/21 ,  C07F7/0876

摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material. A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.

摘要翻译： 本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅来提供具有羟基的T 8 -S-倍半硅氧烷化合物的新方法 化合物作为原料。 通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。 其中：在式（1）中，七个R 1基团中的每一个独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳基烷基和A 2， / SUP>是羟基末端有机官能团，并且在式（2）中，R 1和R 2各自与式（1）中的R 1相同， A 1是含有酰氧基的有机官能团。

公开(公告)号：US07129370B2

公开(公告)日：2006-10-31

申请号：US10664151

申请日：2003-09-17

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

IPC分类号： C07F7/04

CPC分类号： C07F7/21 ,  C07F7/0876

摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material.A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.

摘要翻译： 本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅来提供具有羟基的T 8 -S-倍半硅氧烷化合物的新方法 化合物作为原料。 通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。 其中：在式（1）中，七个R 1基团中的每一个独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳基烷基和A 2， / SUP>是羟基末端有机官能团，并且在式（2）中，R 1和R 2各自与式（1）中的R 1相同， A 1是含有酰氧基的有机官能团。

公开(公告)号：US20060175684A1

公开(公告)日：2006-08-10

申请号：US11316847

申请日：2005-12-27

申请人： Hisao Oikawa ,  Mikio Yamahiro ,  Koji Ohguma ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Hisao Oikawa ,  Mikio Yamahiro ,  Koji Ohguma ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： H01L23/58 ,  H01L21/31

CPC分类号： C07F7/21

摘要： Since the majority of conventional organic/inorganic composite materials are obtained by mechanical blending of a silsesquioxane and an organic polymer or other means, it was extremely difficult to control the structure of the composite as a molecular agglomerate. In order to solve such a problem, the invention is to provide a silicon compound represented by Formula (1). This novel silicon compound has a living radical polymerization initiating ability for addition polymerizable monomers of a wide range. In Formula (1), R1 is hydrogen, an alkyl, an aryl, or an arylalkyl; R2 is an alkyl, phenyl, or cyclohexyl; and A is a group having a polymerization initiating ability for addition polymerizable monomers.

摘要翻译： 由于大多数常规有机/无机复合材料是通过机械共混倍半硅氧烷和有机聚合物或其它方法获得的，所以非常难以控制复合材料的结构作为分子聚集体。 为了解决这个问题，本发明提供一种由式（1）表示的硅化合物。 该新型硅化合物具有广泛范围的可加聚单体的活性自由基聚合引发能力。 在式（1）中，R 1是氢，烷基，芳基或芳基烷基; R 2是烷基，苯基或环己基; A是具有加成聚合性单体的聚合引发能力的基团。

公开(公告)号：US20050215807A1

公开(公告)日：2005-09-29

申请号：US11121076

申请日：2005-05-04

申请人： Yoshitaka Morimoto ,  Kenya Ito ,  Hisaoi Oikawa ,  Mikio Yamahiro ,  Kenichi Watanabe ,  Nobumasa Ootake

发明人： Yoshitaka Morimoto ,  Kenya Ito ,  Hisaoi Oikawa ,  Mikio Yamahiro ,  Kenichi Watanabe ,  Nobumasa Ootake

IPC分类号： C07F7/21 ,  C08G77/04

CPC分类号： C08G77/04

摘要： If chlorosilane is used in order to introduce a functional group into a silsesquioxane derivative having Si—OH, by-produced hydrogen chloride has to be treated. However, if alkoxysilane is substituted for chlorosilane, the long reaction time is required. A production process for a silsesquioxane derivative represented by Formula (2) characterized by using a compound represented by Formula (1), has been developed in order to solve such problems of conventional techniques.

摘要翻译： 如果使用氯硅烷以将官能团引入具有Si-OH的倍半硅氧烷衍生物中，则必须处理副产的氯化氢。 然而，如果烷氧基硅烷代替氯代硅烷，则需要较长的反应时间。 为了解决现有技术的问题，已经开发出由式（2）表示的倍半硅氧烷衍生物的制备方法，其特征在于使用由式（1）表示的化合物。

公开(公告)号：US07563917B2

公开(公告)日：2009-07-21

申请号：US11517457

申请日：2006-09-08

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

IPC分类号： C07F7/21

CPC分类号： C07F7/21 ,  C07F7/0876

摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material.A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.

摘要翻译： 本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅化合物作为起始原料提供具有羟基的T8-倍半硅氧烷化合物的新方法。 通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。 其中：在式（1）中，七个R 1基团各自独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳基烷基，A2是羟基末端有机官能团，并且在式 2）中，R 1基与式（1）中的R 1相同，且为含有酰氧基的有机官能团。

公开(公告)号：US20090143606A1

公开(公告)日：2009-06-04

申请号：US12318736

申请日：2009-01-07

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C07F7/07

CPC分类号： C08G77/04 ,  C07F7/21 ,  C08F10/00 ,  C08F30/08 ,  C08F2500/03

摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.

摘要翻译： 本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构 聚合物作为分子聚集体。 其中R1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可以被氟取代，任选的-CH 2 - 可以被-O - ， - CH-CH-，亚环烷基或环亚烯基取代; 在该芳基烷基中的亚烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O-或-CH-CH-取代; 并且A1是具有α-卤代酯键的基团。

公开(公告)号：US20090137765A1

公开(公告)日：2009-05-28

申请号：US12318733

申请日：2009-01-07

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F283/12

CPC分类号： C08G77/04 ,  C07F7/21 ,  C08F10/00 ,  C08F30/08 ,  C08F2500/03

摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.

摘要翻译： 本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构 聚合物作为分子聚集体。 其中R1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可以被氟取代，任选的-CH 2 - 可以被-O - ， - CH-CH-，亚环烷基或环亚烯基取代; 在该芳基烷基中的亚烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O-或-CH-CH-取代; 并且A1是具有α-卤代酯键的基团。

公开(公告)号：US07235619B2

公开(公告)日：2007-06-26

申请号：US11121076

申请日：2005-05-04

申请人： Yoshitaka Morimoto ,  Kenya Ito ,  Hisaoi Oikawa ,  Mikio Yamahiro ,  Kenichi Watanabe ,  Nobumasa Ootake

发明人： Yoshitaka Morimoto ,  Kenya Ito ,  Hisaoi Oikawa ,  Mikio Yamahiro ,  Kenichi Watanabe ,  Nobumasa Ootake

IPC分类号： C08G77/16

CPC分类号： C08G77/04

摘要： A silsesquioxane derivative represented by Formula (2): wherein R is hydrogen, an alkyl, an aryl, or an arylalkyl; and X is hydrogen, chlorine, a functional group, or a group having a functional group.

摘要翻译： 由式（2）表示的倍半硅氧烷衍生物：其中R是氢，烷基，芳基或芳基烷基; X为氢，氯，官能团或具有官能团的基团。

公开(公告)号：US20050033077A1

公开(公告)日：2005-02-10

申请号：US10664151

申请日：2003-09-17

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe

IPC分类号： C07F7/08 ,  C07F7/21 ,  C07F7/04

CPC分类号： C07F7/21 ,  C07F7/0876

摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material. A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein:  in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.

摘要翻译： 本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅化合物作为起始原料提供具有羟基的T8-倍半硅氧烷化合物的新方法。 通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。 其中：在式（1）中，七个R 1基团中的每一个独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳烷基，A 2是羟基末端有机官能团 基团，式（2）中，R 1各自与式（1）中的R 1相同，A 1为含有酰氧基的有机官能团。