摘要:
Branched crystalline polypropylene compositions and methods for the preparation of branched crystalline polypropylene compositions are provided. For example, described herein is a process of preparing a branched crystalline polypropylene composition that includes combining two or more different metallocene catalyst compounds with a polymerization medium that includes propylene, for a time sufficient to provide branched crystalline polypropylene that has from 0.0 wt % to 2.0 wt % ethylene and a heat of fusion of 70 J/g or more.
摘要:
Certain specific embodiments of the invention will now be discussed. For example, a process of preparing a copolymer composition that includes a diene-modified polypropylene copolymer is described, which process includes: contacting a metallocene catalyst compound with a polymerization medium that includes at least a propylene monomer and 2-methyl-1,5-hexadiene monomer or an α, internal non-conjugated diene monomer; and conducting polymerization of the monomers in the presence of the metallocene catalyst compound for a time sufficient to provide a diene-modified polypropylene random copolymer that includes monomeric units derived from each of the monomers, and having from 0.0 wt % to 2.0 wt % ethylene and a heat of fusion of 25 J/g or more.
摘要:
A compatibilized polymer blend composition is provided which comprises a mixture of an elastomeric polymer and an acid-grafted polymer of an isomonoolefin and an alkylstyrene such as a blend of EPDM and a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene.
摘要:
Functionalized copolymers of a C.sub.4 to C.sub.7 iso-olefin and para-alkylstyrene are provided which are prepared by a nucleophilic displacement of at least a portion of benzylic halogen present in the alkyl styrene moiety with an S--R.sup.2 (OH).sub.n nucleophile, R.sup.2 being C.sub.1 to C.sub.20 hydrocarbyl and n being an integer from 1 to 10. Polymer blends based on a mixture of a polar polymer and a functionalized isobutylene/para-alkylstyrene copolymer are also provided, wherein at least a portion of the benzylic halogen present in the alkyl styrene moiety is displaced by OH, S--R.sup.2 (OH).sub.n or N(H).sub.2-m ((R3)OH).sub.m, R.sup.3 being C.sub.1 to C.sub.20 hydrocarbyl and m being 1 or 2.
摘要:
Branched crystalline polypropylene compositions and methods for the preparation of branched crystalline polypropylene compositions are provided. For example, described herein is a process of preparing branched crystalline polypropylene composition that comprises contacting a supported metallocene catalyst compound with a polymerization medium that comprises propylene monomers; and conducting polymerization of the propylene monomers at a temperature greater than 70° C. for a time sufficient to provide branched crystalline polypropylene that has from 0.0 wt % to 2.0 wt % ethylene and a heat of fusion of 70 J/g or more.
摘要:
An ethylene cyclic olefin polymer, particularly an ethylene/norbornene copolymer and an ethylene/norbornene/alpha olefin terpolymer resin, of improved toughness and processibility for film production. This invention provides ethylene based resins which are processible like an LLDPE but which are significantly improved with respect to their capability to be fabricated into a film layer, particularly by a blown bubble extrusion technique. Films prepared of the resins of this invention are significantly improved with respect to certain of their film properties, such as tear strength, without detracting from the beneficial properties that an LLDPE-like resin otherwise provides to a film. Molding application of the above E/NB copolymers and E/NB/O terpolymers is also disclosed.
摘要翻译:乙烯环烯烃聚合物,特别是乙烯/降冰片烯共聚物和乙烯/降冰片烯/α-烯烃三元共聚物树脂,具有改进的薄膜生产的韧性和加工性。 本发明提供了乙烯基树脂,它们像LLDPE那样可加工,但是在其制造成膜层的能力方面,特别是通过吹塑气泡挤出技术,其可显着改善。 制备本发明树脂的薄膜相对于它们的某些膜性质如撕裂强度而显着改善,而不会降低LLDPE类树脂另外提供给薄膜的有益性质。 还公开了上述E / NB共聚物和E / NB / O三元共聚物的成型应用。
摘要:
This invention relates to a compatibilized rubber composition and a process for compatibilizing polar/nonpolar rubber blends comprising blending compatiblizers such as ethylene/vinyl acetate copolymer, ethylene/methacrylate copolymer EPDM or EP rubber grafted with a polar monomer such as methyl methacrylate.