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21.发明授权Zinc, iron and manganese stabilization using polyether polyamino methylene phosphonates 失效使用聚醚聚氨基亚甲基膦酸盐的锌，铁和锰稳定性
公开(公告)号：US5262061A
公开(公告)日：1993-11-16
申请号：US907257
申请日：1992-07-01
CPC分类号： C02F5/14
摘要： Polyether polyamino methylene phosphonates, when added to various industrial water systems in concentrations between 0.1 mg/L and 50 mg/L, stabilize soluble zinc, manganese and iron ions and their reaction products, in desirable forms and reduced particle sizes. In particular, this stabilization can be achieved under severe conditions which include elevated pH, high dissolved solids content, and high saturation levels of calcium carbonate.
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公开(公告)号：US5254286A
公开(公告)日：1993-10-19
申请号：US988544
申请日：1992-12-10
CPC分类号： C02F5/10 , C02F5/12 , C02F5/14 , D21C11/106 , D21C3/226
摘要： An anionic/cationic polymer mixture comprising:(a) a polyanion selected from polyacrylic acid, polymethacrylic acid, and polymaleic anhydride, each optionally copolymerized with each other, or optionally copolymerized with acrylamide up to a molar unit ratio of 1:1, provided that the total polyanionic weight average molecular weight is from about 1 to 5 thousand, and(b) the polycation poly(dimethyldiallylammonium chloride) having a weight average molecular weight of from about 25 thousand to 1 million,wherein the weight ratio of polyanion (a) to polycation (b) is from 1:2 to 1:8, has been found to give excellent inhibition of the formation, deposition and adherence of various alkali metal and alkaline earth metal scales, e.g., sodium sulfate, sodium carbonate, and calcium carbonate scales in the stringent conditions which characterize black liquor heaters, evaporators, etc. in paper mills, particularly in association with Kamyr and similar wood chip digesters, characterized by elevated pH's of 12 and higher, high dissolved organic and inorganic solids concentrations, and elevated temperatures and pressures.
摘要翻译： 一种阴离子/阳离子聚合物混合物，其包含：（a）选自聚丙烯酸，聚甲基丙烯酸和聚马来酸酐的聚阴离子，各自任选地彼此共聚，或任选地与丙烯酰胺共聚，直到摩尔单位比为1:1，条件是 总聚阴离子重均分子量为约1〜5万，（b）重均分子量为约2.5万〜1万的聚阳离子聚（二甲基二烯丙基氯化铵），其中聚阴离子（a） 对于聚阳离子（b）为1:2至1:8，已经发现对各种碱金属和碱土金属垢的形成，沉积和粘附具有极好的抑制作用，例如硫酸钠，碳酸钠和碳酸钙 在造纸厂的黑液加热器，蒸发器等特征的严格条件下，特别是与Kamyr和类似的木屑消化器相关联，其特征是eleva pH为12以上，高溶解有机和无机固体浓度，以及升高的温度和压力。
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23.发明授权Method for controlling silica/silicate deposition in aqueous systems using 2-phosphonobutane tricarboxylic acid-1,2,4 and anionic polymers 失效使用2-膦酰基丁酸三羧酸-1,2,4和阴离子聚合物控制含水体系中二氧化硅/硅酸盐沉积的方法
公开(公告)号：US5078879A
公开(公告)日：1992-01-07
申请号：US546810
申请日：1990-07-02
申请人： Jasbir S. Gill , Susan P. Rey , John H. Wiernik
发明人： Jasbir S. Gill , Susan P. Rey , John H. Wiernik
IPC分类号： C02F5/14
摘要： A method for controlling the formation of silica/silicate deposits in aqueous systems by adding an effective amount, preferably at least 0.1 ppm, of 2-phosphonobutane tricarboxylic acid-1,2,4 and, optionally, an anionic polymer, preferably a carboxylic/sulfonic polymer, or salts thereof to the aqueous system being treated. Borate or molybdate ion sources may also be added.
摘要翻译： 通过添加有效量的，优选至少0.1ppm的2-膦酰基丁烷三羧酸-1,2,4-和任选的阴离子聚合物，优选羧酸/硅酸盐，控制水性体系中二氧化硅/硅酸盐沉积物的形成的方法。 磺酸聚合物或其盐与待处理的水性体系。 也可以加入硼酸盐或钼酸盐离子源。
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24.发明申请COMPOSITION AND METHOD FOR CONTROLLING COPPER DISCHARGE AND EROSION OF COPPER ALLOYS IN INDUSTRIAL SYSTEMS 有权控制铜排放和铜合金在工业系统中的腐蚀的组合物和方法公开(公告)号：US20100123100A1
公开(公告)日：2010-05-20
申请号：US12274606
申请日：2008-11-20
IPC分类号： C09K3/00
CPC分类号： C23F11/149 , C02F2101/20 , C02F2303/08 , C23F11/10 , C23F14/02
摘要： Compositions and methods of using such compositions for reducing copper ion discharge from aqueous systems is disclosed and claimed. The composition includes a synergistic combination of at least two different benzotriazoles or salts thereof that effectively provides an erosion-resistant barrier on copper-containing surfaces of industrial systems.
摘要翻译： 公开并要求保护使用这种组合物以减少水系统中的铜离子放电的组合物和方法。 该组合物包括至少两种不同的苯并三唑或其盐的协同组合，其有效地在工业系统的含铜表面上提供抗侵蚀屏障。
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25.发明授权公开(公告)号：US07252096B2
公开(公告)日：2007-08-07
申请号：US11000587
申请日：2004-11-30
申请人： Jasbir S. Gill , Amit Gupta
发明人： Jasbir S. Gill , Amit Gupta
IPC分类号： B08B9/00
CPC分类号： F28G9/00 , A61L2/18 , A61L2/20 , B08B9/00 , B08B9/032 , B08B9/08 , C02F1/50 , C02F1/66 , C02F9/00 , C02F2103/023 , C02F2303/04 , C02F2303/08 , C09K8/52 , C11D3/3956 , C11D7/08 , C11D7/265 , C11D11/0041 , F28F2265/20
摘要： On-Line and Off-Line methods of simultaneously cleaning and disinfecting an industrial water system are described and claimed. The methods involve the addition to the water of the industrial water system of a Compound selected from the group consisting of the alkali salts of chlorite and chlorate and mixtures thereof; and an acid, followed by allowing the water in the industrial water system to circulate for several hours. The reaction of the alkali salts of chlorite and chlorate and acid produces chlorine dioxide in-situ in the water of the industrial water system. The chlorine dioxide kills microorganisms and the acid acts to remove deposits upon the water-contact surfaces of the equipment. An alternative method involves the use of a chelating agent and a biocide. Other possible cleaning and disinfection reagents may be added as needed including corrosion inhibitors, chelating agents, biocides, surfactants and reducing agents. These cleaning and disinfecting methods work in a variety of industrial water systems including cooling water and boiler water systems.
摘要翻译： 描述并要求保护同时清洁和消毒工业水系统的在线和离线方法。 所述方法包括向工业水体系的水中加入选自亚氯酸盐和氯酸盐的碱金属盐及其混合物的化合物; 和酸，然后使工业用水系统中的水循环数小时。 亚氯酸盐和氯酸盐和酸的碱金属盐的反应在工业水系统的水中就地产生二氧化氯。 二氧化氯杀死微生物，酸作用以去除设备的水接触表面上的沉积物。 一种替代方法涉及使用螯合剂和杀生物剂。 可以根据需要添加其它可能的清洁和消毒试剂，包括腐蚀抑制剂，螯合剂，杀生物剂，表面活性剂和还原剂。 这些清洁和消毒方法适用于各种工业水系统，包括冷却水和锅炉水系统。
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26.发明授权Method of forming corrosion inhibiting films with hydrogenated benzotriazole derivatives 失效用氢化苯并三唑衍生物形成腐蚀抑制膜的方法
公开(公告)号：US5874026A
公开(公告)日：1999-02-23
申请号：US982049
申请日：1997-12-01
CPC分类号： C23F11/149
摘要： A method of use of a composition including either or both isomers of hydrogenated methylbenzotriazole, namely, 5-Methyl-1H-Benzotriazole or 4-Methyl-1H-Benzotriazole which have been at least about 50% hydrogenated, to form corrosion inhibiting films on metal surfaces in an aqueous environment. The hydrogenated methylbenzotriazole compositions provide both improved passivation and improved film persistence when charged to aqueous industrial systems either on a continuous or on an intermittent basis. Continuous dosing is generally kept at a constant >0.5, typically 1-2 ppm in the aqueous system to be treated; intermittent doses are generally 10-20 ppm once every week or two or more. Beyond the improved characteristics described above, films formed from the inventive composition also reduce spiking in corrosion rates immediately following halogen addition; foster faster return to pre-halogenation corrosion rates post-halogenation; and reduce the rate of conversion of phosphonate to orthophosphate, which reduces scale potential. For these reasons, the present compositions are either continuously or intermittently fed and effective to inhibit corrosion of copper and copper alloy surfaces subjected to alkaline, neutral or slightly acidic aqueous systems.
摘要翻译： 使用包含氢化甲基苯并三唑的任一种或两种异构体的方法，即至少约50％氢化的5-甲基-1H-苯并三唑或4-甲基-1H-苯并三唑，以在金属上形成腐蚀抑制膜 在水性环境中的表面。 氢化的甲基苯并三唑组合物在连续或间歇地加入含水工业系统时提供改进的钝化和改善的膜持久性。 连续给料通常在待处理的水系统中保持在常数> 0.5，通常为1-2ppm; 间歇剂量通常为每周一次或二次或更多次为10-20ppm。 除了上述改进的特征之外，由本发明组合物形成的薄膜还可以在卤素添加后立即减少腐蚀速率的尖峰; 促进更快地回到卤化后的预卤化腐蚀速率; 并降低膦酸酯转化为正磷酸盐的速度，从而降低了电位。 由于这些原因，本发明的组合物是连续地或间歇地进料并且有效地抑制经受碱性，中性或微酸性水性体系的铜和铜合金表面的腐蚀。
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公开(公告)号：US5772913A
公开(公告)日：1998-06-30
申请号：US719184
申请日：1996-09-24
摘要： An aqueous system containing scale forming salts including both calcium carbonate and calcium phosphate and characterized by high pH and high calcite concentrations which further contains a synergistic effective amount of a combination comprising (A) a polyether polyamino methylene phosphonate, (B) a terpolymer comprising the monomers of acrylic acid, sulfophenoxymethallyl ether and maleic acid, (C) a hydroxyphosphonoacetic acid, and (D) a phosphonocarboxylic acid copolymer comprising the monomers of acrylic acid, telomer with (1-hydroxy-1-methylethyl) phosphinic acid monosodium salt, and 2-acrylamido 2 methylpropane sulfonic acid, is disclosed. A method for inhibiting the formation, deposition and adherence of such scale forming salts in the aqueous system employing the synergistic combination is also provided.
摘要翻译： 一种含有包含碳酸钙和磷酸钙的鳞屑形成盐的水性体系，其特征在于高pH和高方解石浓度，其还包含协同有效量的组合，其包含（A）聚醚聚氨基亚甲基膦酸酯，（B） 丙烯酸，磺基苯氧基甲基丙烯酸醚和马来酸的单体，（C）羟基膦酰基乙酸，和（D）包含丙烯酸单体与（1-羟基-1-甲基乙基）次膦酸单钠盐的共聚物的膦酰基羧酸共聚物，和 2-丙烯酰胺基2甲基丙烷磺酸。 还提供了一种使用协同组合在水系中抑制这种鳞状结晶盐的形成，沉积和粘附的方法。
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28.发明授权
公开(公告)号：US5709814A
公开(公告)日：1998-01-20
申请号：US540268
申请日：1995-10-06
申请人： Jasbir S. Gill
发明人： Jasbir S. Gill
摘要： An aqueous system containing scale forming salts including both calcium carbonate and calcium phosphate and characterized by high pH and high calcite concentrations which further contains a synergistic effective amount of a combination comprising (A) a polyether polyamino methylene phosphonate, (B) a terpolymer comprising the monomers of acrylic acid, sulfophenomethallyl ether and maleic acid, and (C) a hydroxyphosphonoacetic acid, is disclosed. A method for inhibiting the formation, deposition and adherence of such scale forming salts in the aqueous system employing the synergistic combination is also provided.
摘要翻译： 一种含有包含碳酸钙和磷酸钙的鳞屑形成盐的水性体系，其特征在于高pH和高方解石浓度，其还包含协同有效量的组合，其包含（A）聚醚聚氨基亚甲基膦酸酯，（B） 公开了丙烯酸，磺基甲基间苯二甲醚和马来酸的单体，（C）羟基膦酰基乙酸。 还提供了一种使用协同组合在水系中抑制这种鳞状结晶盐的形成，沉积和粘附的方法。
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29.发明授权
公开(公告)号：US5593595A
公开(公告)日：1997-01-14
申请号：US540270
申请日：1995-10-06
申请人： Jasbir S. Gill
发明人： Jasbir S. Gill
摘要： An aqueous system containing scale forming salts including both calcium carbonate and calcium phosphate and characterized by high pH and high calcite concentrations which further contains a synergistic effective amount of a combination comprising (A) a polyether polyamino methylene phosphonate, (B) a terpolymer comprising the monomers of acrylic acid, sulfophenomethallyl ether and maleic acid, and (C) a hydroxyphosphonoacetic acid, is disclosed. A method for inhibiting the formation, deposition and adherence of such scale forming salts in the aqueous system employing the synergistic combination is also provided.
摘要翻译： 一种含有包含碳酸钙和磷酸钙的鳞屑形成盐的水性体系，其特征在于高pH和高方解石浓度，其还包含协同有效量的组合，其包含（A）聚醚聚氨基亚甲基膦酸酯，（B） 公开了丙烯酸，磺基甲基间苯二甲醚和马来酸的单体，（C）羟基膦酰基乙酸。 还提供了一种使用协同组合在水系中抑制这种鳞状结晶盐的形成，沉积和粘附的方法。
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30.发明授权
公开(公告)号：US5580462A
公开(公告)日：1996-12-03
申请号：US540269
申请日：1995-10-06
申请人： Jasbir S. Gill
发明人： Jasbir S. Gill
摘要： An aqueous system containing scale forming salts including both calcium carbonate and calcium phosphate and characterized by high pH and high calcite concentrations which further contains a synergistic effective amount of a combination comprising (A) a polyether polyamino methylene phosphonate, and (B) a terpolymer comprising the monomers of acrylic acid, sulfophenomethallyl ether and maleic acid, is disclosed. A method for inhibiting the formation, deposition and adherence of such scale forming salts in the aqueous system employing the synergistic combination is also provided.
摘要翻译： 含有包含碳酸钙和磷酸钙两者的鳞屑形成盐的水性体系，其特征在于高pH和高方解石浓度，其还包含协同有效量的包含（A）聚醚聚氨基亚甲基膦酸酯的组合，和（B）三元共聚物，所述三元共聚物包含 公开了丙烯酸，磺基甲基烯丙基醚和马来酸的单体。 还提供了一种使用协同组合在水系中抑制这种鳞状结晶盐的形成，沉积和粘附的方法。
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