公开(公告)号：US20090076240A1

公开(公告)日：2009-03-19

申请号：US12095239

申请日：2006-11-28

申请人： Jean-Marie Bernard ,  Philippe Barbeau ,  Philippe Olier

发明人： Jean-Marie Bernard ,  Philippe Barbeau ,  Philippe Olier

IPC分类号： C08G18/32 ,  C09K3/00 ,  C07C69/74

CPC分类号： C08G18/3885 ,  C07F9/6521 ,  C08G18/3212 ,  C08G18/771 ,  C08G18/776 ,  C08G18/7837 ,  C08G18/7843 ,  C08G18/792 ,  C08G18/8016 ,  C09D175/04

摘要： Novel compounds having an average isocyanate functionality of greater than 2 are synthesized by the reaction of a (poly)isocyanate having an average functionality of greater than 2, with a compound X comprising a function B(H)n or B′(H)n′ where n is equal to 1 or 2, n′ is equal to 1, 2 or 3, H is a labile hydrogen atom and B is O, S, N, N being a primary or secondary nitrogen atom, —C(═O)—O, —C(═O)—N, or else the groups O═P(O)2; O═P(O)OR1; O═P(O)3; O═P(O)2OR1; O—P(O)—OR1, and B′ is —SiR2R3R4, such reaction being carried out with a compound X/[compound X+(poly)isocyanate] weight ratio of at most 50%; compositions comprised thereof are of the hardener type and can be formulated into coatings of the paint or varnish type.

摘要翻译： 平均异氰酸酯官能度大于2的新型化合物通过具有平均官能度大于2的（多）异氰酸酯与包含官能B（H）n或B'（H）n 其中n等于1或2，n'等于1,2或3，H是不稳定的氢原子，B是O，S， N，N是伯或仲氮原子，-C（-O）-O，-C（-O）-N，或基团OP（O）2; O-P（O）OR1; O-P（O）3; O-P（O）2OR1; O-P（O）-OR1和B'是-SiR2R3R4，该反应用化合物X / [化合物X +（聚）异氰酸酯]重量比为至多50％进行; 包含它们的组合物是硬化剂类型，并且可以配制成涂料或清漆类型的涂料。

公开(公告)号：US06905540B2

公开(公告)日：2005-06-14

申请号：US10276812

申请日：2001-05-15

申请人： Stefan Breunig ,  Philippe Olier

发明人： Stefan Breunig ,  Philippe Olier

IPC分类号： B29C33/64 ,  C08G77/22 ,  C08G77/38 ,  C08G77/382 ,  B28B7/36

CPC分类号： C08G77/38 ,  B29C33/64 ,  C08G77/22 ,  C08G77/382

摘要： The invention concerns a lubricating organo-functional silicone oil, whether or not in emulsion. The invention aims at improving oils and lubricating silicone emulsions, in terms of emulsion stability, transfer and flow of the oil in emulsion on metal surfaces, of stripping lubricating power, non-clogging of molds and paintability of molded metal articles when used for stripping. In order to achieve said aim, the inventive POS oil is functionalized with the lubricating organophilic radical W (C12-C20 alkyl) and with a radical bearing one or several adhering functions such as diacid, thiol, phosphonate, sulphonate hydroxy, hydroxyamine, amine, ether, amide and their combinations. The invention also concerns emulsions whether or not containing additives, based on said WY functionalized POS oils, the preparation of said oils and said emulsions and their uses when stripping metal articles molded in metal moulds.

摘要翻译： 本发明涉及润滑有机官能硅油，无论是否乳液。 本发明旨在改善油和润滑硅氧烷乳液，就乳液的稳定性，在金属表面上的乳液中的油的转移和流动，剥离润滑力，模具的不堵塞以及用于汽提时的模制金属制品的可涂覆性而言。 为了实现所述目的，本发明的POS油用润滑有机亲油基W（C 12 -C 20烷基）和具有一个或几个粘附官能团的基团进行官能化，例如二酸，硫醇，膦酸酯，磺酸羟基，羟胺，胺， 醚，酰胺及其组合。 本发明还涉及基于所述WY官能化POS油，所述油和所述乳液的制备以及当在金属模具中模制的金属制品剥离时的用途的含有添加剂的乳液。

公开(公告)号：US06743884B2

公开(公告)日：2004-06-01

申请号：US10428446

申请日：2003-05-02

申请人： Philippe Olier

发明人： Philippe Olier

IPC分类号： C08G7714

CPC分类号： C08G77/38 ,  C08G77/14

摘要： Dicarboxy functionalized polyorganosiloxanes having the formula X(R4R5SiO)p(R6ASiO)qY  (I) wherein the X end group represents a triorganosiloxyl end group of formula R1R2R3SiO, or a Z end group, wherein Z represents —OH the Y end group represents a triorganosilyl end group of formula SiR3R2R1, or a W end group, wherein W represents —H R1 to R6 represent a C1-C8 alkyl or phenyl radical, preferably methyl A represents the dicarboxy radical of formula (I′) or salts thereof —(CH2)3—CH(COOH)—CH2COOH  (I′) p is an average value ranging from 0 to 1000 q is an average value ranging from 1 to 100 the ratio of the number of Z and W end groups to the total number of X and Y end groups being from 0/100 to 75/100. They can be used for the water repellent treatment of surfaces, particularly inorganic surfaces or surfaces containing alkaline or earth-alkaline metal, and as anti-corrosion additives for the treatment of metal surfaces.

摘要翻译： 具有X末端基团的二羧基官能化聚有机硅氧烷表示式R 1 R 2 R 3 SiO的三有机甲硅烷基端基或Z端基，其中Z表示-OH，Y端基表示三官能甲硅烷基端基 式SiR 3 R 2 R或W端基，其中W表示-HR 1至R 6表示C 1 -C 8烷基或苯基，优选甲基A表示二价基团， 式（I'）或其盐的平均值为0至1000q的平均值是1至100的平均值，Z和W端基数与X和Y端基的总数之比为0 / 100至75/100。 它们可以用于表面，特别是无机表面或含有碱金属或碱土金属的表面的防水处理，以及用于处理金属表面的防腐蚀添加剂。

公开(公告)号：US06491981B1

公开(公告)日：2002-12-10

申请号：US09743788

申请日：2001-02-20

申请人： Gérald Guichard ,  Gérard Mignani ,  Philippe Olier

发明人： Gérald Guichard ,  Gérard Mignani ,  Philippe Olier

IPC分类号： B05D302

CPC分类号： C08G77/385 ,  C08G77/388 ,  C09D183/08 ,  C09K3/18 ,  D06M15/657 ,  D06M2200/11 ,  D06M2200/12

摘要： A functionalized silicone with perfluorinated polyorganosiloxanes (POS) Rf is used to produce coatings with low surface energy and improved adherence to supports. The compositions include a group POS A bearing, per molecule, bis-perfluoromalonate grafts Gf, functional radicals Fa of the amine (HALS) fa1, epoxy fa2, (poly)ether fa3, carboxy fa4 type, and optionally alkyl groups Galk. The invention is useful for producing soil release coatings for textiles.

摘要翻译： 具有全氟化聚有机硅氧烷（POS）Rf的官能化硅酮用于生产具有低表面能和改善对载体粘附性的涂层。 组合物包括每个分子的基团POS A轴承，双全氟马来酸盐接枝物Gf，胺（HALS）fa1，环氧基fa2，（聚）醚fa3，羧基fa4型和任选的烷基Galk的官能团Fa。 本发明可用于生产纺织品的防污涂层。

公开(公告)号：US06437163B1

公开(公告)日：2002-08-20

申请号：US09647995

申请日：2001-02-23

申请人： Paul Branlard ,  Gérard Mignani ,  Philippe Olier ,  Claudie Willemin

发明人： Paul Branlard ,  Gérard Mignani ,  Philippe Olier ,  Claudie Willemin

IPC分类号： C07F708

CPC分类号： A61Q13/00 ,  A61K8/895 ,  A61Q15/00

摘要： The invention concerns a method for preparing high purity polyorganosiloxanes with arylalkyl function(s) by: hydrosilylation of a hydrogenopolyorganosiloxane, reagent (SiH), and an aromatic monovinyl compound, reagent (Vi), with simultaneous introduction of reagent (SiH) and reagent (Vi), in a reaction medium containing an inert solvent and a hydrosilylation catalyst; then elimination of the solvent, the possible residual reagents (SiH) and (Vi), and/or hydrogenation, the hydrogenation process being optionally followed by an elimination process (or another elimination process) of the products other than polyorganosiloxanes with arylalkyl function(s). The resulting silicones with arylalkyl function(s) can be used as emollients and/or carriers in cosmetic compositions, or as solubilizing agents and emollients in perfume compositions.

摘要翻译： 本发明涉及通过以下方法制备具有芳基烷基官能团的高纯度聚有机硅氧烷的方法：通过氢化有机硅氧烷，试剂（SiH）和芳族单乙烯基化合物，试剂（Vi）的氢化硅烷化，同时引入试剂（SiH）和试剂（ Vi），在含有惰性溶剂和氢化硅烷化催化剂的反应介质中; 然后消除溶剂，可能的残余试剂（SiH）和（Vi）和/或氢化，氢化过程任选地随后除了具有芳烷基官能团的聚有机硅氧烷以外的产物的消除方法（或另一消除方法） ）。 所得到的具有芳基烷基官能团的硅氧烷可用作化妆品组合物中的润肤剂和/或载体，或作为香料组合物中的增溶剂和润肤剂使用。

公开(公告)号：US06395704B1

公开(公告)日：2002-05-28

申请号：US09463678

申请日：2000-04-21

申请人： Paul Branlard ,  Gérard Mignani ,  Claudie Willemin ,  Philippe Olier

发明人： Paul Branlard ,  Gérard Mignani ,  Claudie Willemin ,  Philippe Olier

IPC分类号： A61K700

CPC分类号： A61Q13/00 ,  A61K8/585 ,  A61K8/895 ,  A61Q15/00

摘要： The invention concerns a perfume composition comprising a perfume base and a lipophilic solubilizing agent based on at least an organopolysiloxane having according to Hansen solubility parameter the following characteristics: &dgr;D London interactions ranging from (8) to (21) (J/cm3)½, &dgr;P of Keesom interactions greater than 0 and capable of reaching 25 (J/cm3)½, &dgr;H of hydrogen binding ranging from (0) to (23) (J/cm3)½. Said organotrisiloxanes with polar or polarizsable function of formula (I) are used as solubilizing agents and emollients in perfume composition.

摘要翻译： 本发明涉及一种香水组合物，其包含基于至少有机聚硅氧烷的香料基质和亲脂性增溶剂，其具有根据Hansen溶解度参数的以下特征：δD伦敦相互作用范围从（8）至（21）（J / cm 3）1/2， Keesom相互作用的δP大于0并且能够达到从（0）到（23）（J / cm 3）1/2的氢结合的25（J / cm 3）1/2，δH。 具有式（I）的极性或极性化功能的所述有机基硅氧烷用作香料组合物中的增溶剂和润肤剂。