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    High purity, high pressure hydrogen production with in-situ CO2 and sulfur capture in a single stage reactor
    22.
    发明授权
    High purity, high pressure hydrogen production with in-situ CO2 and sulfur capture in a single stage reactor 有权
    高纯度，高压氢气生产，在单级反应器中原位二氧化碳和硫捕获

    公开(公告)号：US07837975B2

    公开(公告)日：2010-11-23

    申请号：US12409843

    申请日：2009-03-24

    申请人： Mahesh V. Iyer ,  Liang-Shih Fan ,  Shwetha Ramkumar

    发明人： Mahesh V. Iyer ,  Liang-Shih Fan ,  Shwetha Ramkumar

    IPC分类号： C01B3/12 ,  C01B3/16 ,  C01B3/22 ,  C01B3/24 ,  C01B3/26

    CPC分类号： C01B3/38 ,  C01B3/386 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0425 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/1041 ,  C01B2203/86 ,  C10J2300/093 ,  C10J2300/0996 ,  C10J2300/1659 ,  C10K3/04 ,  Y02P30/30

    摘要： A process for producing hydrogen, comprising the steps of: (a) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam and sulfur and halide contaminants in the form of H2S, COS and HX, where X is a halide; (b) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO3, CaS and CaX2; (c) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (d) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO2, in the presence of synthesis gas, in the presence of H2 and O2, under partial vacuum, and combinations thereof. The CaO may have a surface area of at least 12.0 m2/g and a pore volume of at least 0.015 cm3/g, the CaO having a sorption capacity of at least about 70 grams of CO2 per kilogram of CaO.

    摘要翻译： 一种生产氢气的方法，包括以下步骤：（a）将燃料气化成包含CO，氢气，蒸气和硫的原料合成气和H2S，COS和HX形式的卤化物污染物，其中X是卤化物; （b）将原始合成气通过注入CaO和蒸汽的水煤气变换反应器（WGSR），CaO与转移的气体反应以除去含CaCO3的固相含钙产物中的CO 2，硫和卤化物 ，CaS和CaX2; （c）从富集的气态氢产物中分离固相含钙产物; 和（d）通过在选自以下的条件下煅烧所述固相钙含量产物来再生CaO：在蒸气存在下，在CO 2的存在下，在合成气的存在下， H2和O2，以及它们的组合。 CaO可以具有至少12.0m 2 / g的表面积和至少0.015cm 3 / g的孔体积，CaO具有至少约70克CO 2 /千克CaO的吸附能力。

    Integration of Cold Solvent and Acid Gas Removal
    24.
    发明申请
    Integration of Cold Solvent and Acid Gas Removal 审中-公开

    公开(公告)号：US20190054416A1

    公开(公告)日：2019-02-21

    申请号：US16102297

    申请日：2018-08-13

    申请人： David W. Maher ,  Shwetha Ramkumar ,  P. Scott Northrop ,  Robert D. Denton

    发明人： David W. Maher ,  Shwetha Ramkumar ,  P. Scott Northrop ,  Robert D. Denton

    IPC分类号： B01D53/14 ,  B01D61/24

    摘要： A method of separating impurities from a natural gas stream. The natural gas stream is cooled through heat exchange with one or more process streams to produce a chilled gas stream, which is contacted with a lean solvent stream in a contactor to separate hydrogen sulfide (H2S) from the chilled gas stream, thereby producing a rich solvent stream and a partially-treated gas stream. Carbon dioxide (CO2) and H2S are separated from the partially-treated gas stream in a membrane separation system, thereby creating a fully-treated gas stream and a permeate gas stream, the permeate gas stream being comprised primarily of H2S and CO2, and the fully-treated gas stream being comprised primarily of natural gas. The fully-treated gas stream and the permeate gas stream are at a lower temperature than the partially-treated gas stream. The fully-treated gas stream and the permeate gas stream comprise the one or more process streams.

    Fractionation System using Bundled Compact Co-Current Contacting Systems
    25.
    发明申请
    Fractionation System using Bundled Compact Co-Current Contacting Systems 审中-公开

    公开(公告)号：US20180361309A1

    公开(公告)日：2018-12-20

    申请号：US15949613

    申请日：2018-04-10

    申请人： Norman K. Yeh ,  Edward J. Grave ,  Shwetha Ramkumar ,  Juan C. Juarez

    发明人： Norman K. Yeh ,  Edward J. Grave ,  Shwetha Ramkumar ,  Juan C. Juarez

    IPC分类号： B01D53/18 ,  B01D53/14 ,  B01D45/14 ,  C10G5/00

    摘要： A fractionation system for removing heavy hydrocarbons in a gas stream. A stripping section receives a predominantly liquid phase of the feed gas stream. A co-current contacting system receives a predominantly vapor phase of the feed gas stream. The co-current contacting system includes a compact contacting bundle disposed within a vessel and including a plurality of substantially parallel contacting units, each of the plurality of contacting units having a droplet generator, a mass transfer section, and a separation system. Each droplet generator generates droplets from a liquid disperses the droplets into a gas stream. Each mass transfer section provides a mixed, two-phase flow having a vapor phase and a liquid phase. Each separation system separates the vapor phase from the liquid phase such that the concentration of heavy hydrocarbons in the vapor phase is lower than in the liquid phase.

    HIGH PURITY, HIGH PRESSURE HYDROGEN PRODUCTION WITH IN-SITU CO2 AND SULFUR CAPTURE IN A SINGLE STAGE REACTOR
    27.
    发明申请
    HIGH PURITY, HIGH PRESSURE HYDROGEN PRODUCTION WITH IN-SITU CO2 AND SULFUR CAPTURE IN A SINGLE STAGE REACTOR 有权
    单级二次反应器中的高纯度，高压氢生产与二氧化碳和硫吸收

    公开(公告)号：US20090263316A1

    公开(公告)日：2009-10-22

    申请号：US12409843

    申请日：2009-03-24

    申请人： Mahesh V. Iyer ,  Liang-Shih Fan ,  Shwetha Ramkumar

    发明人： Mahesh V. Iyer ,  Liang-Shih Fan ,  Shwetha Ramkumar

    IPC分类号： C01B3/58

    CPC分类号： C01B3/38 ,  C01B3/386 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0425 ,  C01B2203/043 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/1041 ,  C01B2203/86 ,  C10J2300/093 ,  C10J2300/0996 ,  C10J2300/1659 ,  C10K3/04 ,  Y02P30/30

    摘要： A process for producing hydrogen, comprising the steps of: (a) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam and sulfur and halide contaminants in the form of H2S, COS and HX, where X is a halide; (b) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO3, CaS and CaX2; (c) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (d) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO2, in the presence of synthesis gas, in the presence of H2 and O2, under partial vacuum, and combinations thereof. The CaO may have a surface area of at least 12.0 m2/g and a pore volume of at least 0.015 cm3/g, the CaO having a sorption capacity of at least about 70 grams of CO2 per kilogram of CaO.

    摘要翻译： 一种生产氢气的方法，包括以下步骤：（a）将燃料气化成包含CO，氢气，蒸气和硫的原料合成气和H2S，COS和HX形式的卤化物污染物，其中X是卤化物; （b）将原始合成气通过注入CaO和蒸汽的水煤气变换反应器（WGSR），CaO与转移的气体反应以除去含CaCO3的固相含钙产物中的CO 2，硫和卤化物 ，CaS和CaX2; （c）从富集的气态氢产物中分离固相含钙产物; 和（d）通过在选自以下的条件下煅烧所述固相钙含量产物来再生CaO：在蒸气存在下，在CO 2的存在下，在合成气的存在下， H2和O2，以及它们的组合。 CaO可以具有至少12.0m 2 / g的表面积和至少0.015cm 3 / g的孔体积，CaO具有至少约70克CO 2 /千克CaO的吸附能力。