Preparation of phthalic anhydride by heating trimellitic acid in the presence of a catalyst
    23.
    发明授权
    Preparation of phthalic anhydride by heating trimellitic acid in the presence of a catalyst 失效
    在催化剂存在下加热三聚氰酸酯制备极性无水物

    公开(公告)号:US3862145A

    公开(公告)日:1975-01-21

    申请号:US18423271

    申请日:1971-09-27

    CPC classification number: C07C51/56 C07C63/16

    Abstract: Phthalic anhydride is prepared by heating trimellitic acid in the presence of certain metal catalysts such as cobalt, manganese, and cerium as either salts or in the oxide form, and bromine. The trimellitic acid and catalyst are heated and an inert gas is passed through the molten mass to produce a product containing a high concentration of orthophthalic acid which upon further heating yields orthophthalic anhydride or phthalic anhydride.

    Abstract translation: 邻苯二甲酸酐通过在某些金属催化剂如钴,锰和铈作为盐或氧化物形式的存在下加热偏苯三酸和溴来制备。 将偏苯三酸和催化剂加热并使惰性气体通过熔融物质以产生含有高浓度邻苯二甲酸的产物,其在进一步加热时产生邻苯二甲酸酐或邻苯二甲酸酐。

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