摘要:
Golf balls containing at least one layer made from a thermoset polyurethane or polyurethane-urea that is the reaction product of a polyisocyanate with moisture-resistant polyol and a curing agent are provided. The moisture-resistant polyol may be prepared by dimerizing unsaturated aliphatic monocarboxylic acid or ester containing 10 to 60 carbon atoms followed by reacting it with a monomeric, oligomeric, or polymeric diol. In one preferred version, the moisture-resistant polyol is a branched polyester polyol containing 36 carbon atoms. The composition can be prepared using prepolymer or one-shot manufacturing techniques. The thermoset composition has good cross-link density. The resulting golf ball has desirable playing performance properties including high resiliency, toughness, impact durability, moisture-resistance, and soft feel.
摘要:
Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
摘要:
Golf balls containing at least one layer made from a thermoset polyurethane or polyurethane-urea that is the reaction product of a polyisocyanate with moisture-resistant polyol and a curing agent are provided. The moisture-resistant polyol may be prepared by dimerizing unsaturated aliphatic monocarboxylic acid or ester containing 10 to 60 carbon atoms followed by reacting it with a monomeric, oligomeric, or polymeric diol. In one preferred version, the moisture-resistant polyol is a branched polyester polyol containing 36 carbon atoms. The composition can be prepared using prepolymer or one-shot manufacturing techniques. The thermoset composition has good cross-link density. The resulting golf ball has desirable playing performance properties including high resiliency, toughness, impact durability, moisture-resistance, and soft feel.
摘要:
A golf ball comprising a core and at least one layer disposed about the core, wherein at least one of the core and the layer comprises a thermoplastic or thermoset composition comprising a reaction product of a polyurethane or polyurea prepolymer comprising at least one isocyanate and a curative comprising a blend of at least one aliphatic diamine and at least one polyaspartic ester formed from reactants comprising at least one aliphatic primary polyamine and at least one maleic or fumaric diester, and wherein the thermoplastic or thermoset composition comprises a gel time of about 90 seconds or greater. Also, a golf ball comprising a core and at least one layer disposed about the core wherein at least one of the core and the layer comprises a thermoplastic or thermoset composition T comprising a reaction product of a polyurethane or polyurea prepolymer P comprising at least one isocyanate and a curative C comprising a blend of at least one aliphatic diamine D and at least one polyaspartic ester formed from reactants comprising at least one aliphatic primary polyamine and at least one maleic or fumaric diester, wherein the thermoplastic or thermoset composition T has a gel time X such that X>1.25Y, and wherein Y is the gel time of a thermoplastic or thermoset composition T′ comprising a reaction product of the polyurethane or polyurea prepolymer P and a curative C′ comprising a blend of aliphatic diamine D and a polyaspartic ester consisting of N,N′-diethylmaleate-2-methyl-pentamethylene diamine.
摘要:
Golf balls formed with at least one layer incorporating an anionic polyurea material formed from an isocyanate, an amine-terminated component, and an amine-terminated curing agent where at least one of the amine-terminated component and amine-terminated curing agent includes a R′-R″ segment with acid functionalization.
摘要:
Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
摘要:
Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
摘要:
Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
摘要:
Golf balls formed with at least one layer incorporating an anionic polyurea material formed from an isocyanate, an amine-terminated component, and an amine-terminated curing agent where at least one of the amine-terminated component and amine-terminated curing agent includes a R′—R″ segment with acid functionalization.
摘要:
Golf ball compositions, and components formed therefrom, including trifunctional materials, such as trifunctional isocyanates, polyols, and amines, that have improved performance and durability characteristics, e.g., improved heat resistance, improved resiliency, and dimensional stability.