公开(公告)号：US20130095345A1

公开(公告)日：2013-04-18

申请号：US13704786

申请日：2010-06-21

申请人： Jun Maki ,  Shinichi Yamaguchi

发明人： Jun Maki ,  Shinichi Yamaguchi

IPC分类号： C23C2/12

CPC分类号： C23C2/12 ,  B32B15/012 ,  C21D8/0278 ,  C22C21/02 ,  C22C38/001 ,  C22C38/002 ,  C22C38/004 ,  C22C38/02 ,  C22C38/08 ,  C22C38/16 ,  C22C38/60 ,  C23C2/02 ,  C23C2/26 ,  Y10T428/12757

摘要： In conventional Al coated steel sheet, with the Al coating as it is, black discoloration cannot be prevented at 550° C. or more. For this reason, post annealing is used to form a barrier layer and suppress the formation of Fe—Al intermetallic compounds. However, with this method, there were the problems that the steel sheet became poor in workability and, further, high temperature, long time heating was required, so there were problems from the workability, economy, and environmental aspect. The present invention provides steel sheet which has a heat black discoloration resistance even at a 550° C. or more high temperature without additional annealing after Al coating and further is excellent in workability.That is, it is hot dip Al coated steel sheet which comprises steel sheet which contains predetermined ingredients of C, Si, P, S, Al, N, and O plus one or both of furthermoreNi: 0.01 to 0.1% or Cu: 0.01 to 0.1% and satisfies 10×C+Ni+Cu>0.03 and an Al coating layer which contains Si: 4 to 11% on the surface of that steel sheet and which have a thickness 5 μm or less Al—Fe—Si alloy layer in the interface between the Al coating layer and the steel sheet.

摘要翻译： 在常规的Al涂层钢板中，如果使用Al涂层，则在550℃以上不能防止黑色变色。 因此，使用后退火形成阻挡层，抑制Fe-Al金属间化合物的形成。 然而，通过这种方法，存在钢板的加工性变差的问题，进而需要高温，长时间的加热，所以存在从可加工性，经济性，环境等方面出现的问题。 本发明提供即使在550℃或更高的温度下也具有耐热黑变色性的钢板，而在Al涂层之后没有额外的退火，并且加工性优异。 也就是说，是包含含有C，Si，P，S，Al，N和O的预定成分的钢板的热浸镀铝钢板，加上另外一种或两种Ni：0.01至0.1％或Cu：0.01 至0.1％，并且在该钢板的表面上满足10×C + Ni + Cu> 0.03和含有Si：4〜11％的Al涂层，其厚度为5μm以下的Al-Fe-Si合金层 在Al涂层和钢板之间的界面。

公开(公告)号：US08421294B2

公开(公告)日：2013-04-16

申请号：US12810526

申请日：2008-12-01

申请人： Shinichi Yamaguchi ,  Hisashi Otsuka ,  Haruyuki Hasegawa

发明人： Shinichi Yamaguchi ,  Hisashi Otsuka ,  Haruyuki Hasegawa

IPC分类号： H02K21/12 ,  H02K1/06

CPC分类号： H02K21/16 ,  H02K1/146 ,  H02K1/276 ,  H02K29/03 ,  H02K2201/06

摘要： A rotor includes permanent magnets arranged such that magnetic poles of N poles and S poles are arranged alternately in a rotation circumferential direction. The permanent magnets form a plurality of rows in a rotation axis direction. The rotor includes a change section in which arrangements of the magnetic poles change with respect to the rotation axis direction due to the permanent magnets being arranged such that arrangements of the magnetic poles change, in the rotation circumferential direction, between the permanent magnets in the plurality of rows. A stator includes tooth sections opposed to the rotor to surround the rotor, and auxiliary slots each of which is selectively formed at one portion of a front end portion of each tooth section in the rotation axis direction such that substantially a center of the auxiliary slot in the rotation axis direction is opposed to the change section.

摘要翻译： 转子包括设置成使得N极和S极的磁极沿旋转圆周方向交替布置的永磁体。 永磁体在旋转轴方向上形成多列。 转子包括变化部，其中由于永磁体被布置成使得磁极的配置在旋转圆周方向上在多个永磁体之间变化，磁极的配置相对于旋转轴线方向变化 的行。 定子包括与转子相对的围绕转子的齿部分，以及辅助槽，每个辅助槽在旋转轴线方向上选择性地形成在每个齿部的前端部分的一部分处，使得基本上辅助槽的中心位于 旋转轴方向与变更部相对。

公开(公告)号：US08263932B2

公开(公告)日：2012-09-11

申请号：US13125545

申请日：2008-10-30

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01J49/40

CPC分类号： H01J49/408

摘要： A variety of ions generated in an ion source are made to fly while bypassing a loop orbit and mass analyzed to create a mass spectrum. Among the peaks appearing on the mass spectrum, peaks complying with predetermined conditions are extracted to determine a plurality of mass ranges to be measured (S1 through S3). Next, the ion selection conditions for the timing when ions should be injected into the loop orbit and on the loop orbit are determined for each mass range. In addition, deviation conditions under which selected ions will not be mixed are determined (S4 and S5). When the second measurement is performed for the same sample, ions are put into the loop orbit and unnecessary ions are removed from the loop orbit in accordance with the ion selection conditions (S6 and S7). Thus, only the ions to be measured are left on the loop orbit with a high mass resolving power. Then, these ions are sequentially deviated from the loop orbit in accordance with the ion deviation conditions, dissociated, and then mass analyzed (S8). In this manner, MS/MS analyses are performed for each of the plurality of ions to be measured to create an MS/MS spectrum (S10).

摘要翻译： 在离子源中产生的各种离子被制成飞行，同时绕过环路轨道并进行质量分析以产生质谱。 在质谱中出现的峰中，提取符合预定条件的峰以确定待测量的多个质量范围（S1至S3）。 接下来，对于每个质量范围确定离子应注入环路轨道和环路轨道的定时的离子选择条件。 此外，确定不混合选定离子的偏差条件（S4和S5）。 当对相同的样品进行第二次测量时，根据离子选择条件将离子放入环轨道中，并从环路轨道中除去不需要的离子（S6和S7）。 因此，只有待测量的离子留在具有高质量分辨能力的环路轨道上。 然后，这些离子根据离子偏离条件依次偏离环路轨道，解离，然后进行质量分析（S8）。 以这种方式，对待测量的多个离子中的每一个执行MS / MS分析以产生MS / MS谱（S10）。

公开(公告)号：US08180576B2

公开(公告)日：2012-05-15

申请号：US12300373

申请日：2006-05-11

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01J49/26 ,  G06F17/00

CPC分类号： G01N27/62

摘要： When a target substance's composition formula is deduced by using a mass spectrometer, if the target substance's composition formula is deduced based on an MSn spectrum and candidates are found, a composition formula candidate list including all the composition formula candidates is created, and the list is displayed in a list format. The composition formula candidates are narrowed down based on the MSn spectrum by an MS2 analysis or MS3 analysis. If there is a candidate to be excluded, the composition formula candidate list is updated, and the excluded candidate is moved to the exclusion list. Accompanying this, a composition formula candidate table is displayed in a list format on the display window. In this table, the composition formula candidates included in the exclusion list and the remaining composition formula candidates in the composition formula candidate list are simultaneously displayed with different colors so that they are visually discriminable.

摘要翻译： 当通过使用质谱仪推导出目标物质的组成式时，如果基于MSn谱推导出目标物质的组成式，并且找到候选物，则创建包括所有组成式候选的组成式候选列表，并且列表是 以列表格式显示。 通过MS2分析或MS3分析，基于MSn谱，将组成公式候选物缩小。 如果存在要排除的候选者，则更新组成公式候选列表，并将排除的候选者移动到排除列表。 伴随这一点，组合公式候选表在显示窗口上以列表格式显示。 在该表中，包含在排除列表中的组成式候选者和组成式候选列表中的剩余组成公式候选者同时以不同的颜色显示，使得它们在视觉上可辨别。

公开(公告)号：US20120081836A1

公开(公告)日：2012-04-05

申请号：US13226540

申请日：2011-09-07

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01G4/12 ,  C04B35/468

CPC分类号： H01G4/30 ,  C04B35/4682 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3239 ,  C04B2235/3262 ,  C04B2235/3418 ,  C04B2235/79 ,  H01G4/1227

摘要： A laminated ceramic capacitor which exhibits excellent lifetime characteristics in a high temperature loading test uses a dielectric ceramic constituting the dielectric layers which contains (Ba1-xCax)TiO3 as its main constituent, and contains a parts by mol of Al, b parts by mol of V, c parts by mol of Mg, and d parts by mol of Re with respect to 100 parts by mol of the (Ba1-xCax)TiO3. The Re is at least one metal element selected from among Y, La, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb, and the x, a, b, c, and d respectively satisfy the conditions of 0.050≦x≦0.150, a≧0.15, 0.05≦b≦0.50, c≦0.50, and d≧1.00.

摘要翻译： 在高温负载试验中表现出优异的寿命特性的层叠陶瓷电容器使用构成包含（Ba1-xCax）TiO3作为其主要成分的电介质层的电介质陶瓷，并且包含一份摩尔的Al，b份摩尔的 V，c份摩尔的Mg，相对于（Ba1-xCax）TiO3的100份摩尔，d份的Re为Re。 Re是选自Y，La，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm和Yb中的至少一种金属元素，x，a，b，c和d分别满足条件 为0.050＆nlE; x＆lt; l1; 0.150，a≥0.15,0.05＆nlE; b＆nlE; 0.50，c＆nlE; 0.50和d≥1.00。

公开(公告)号：US20100312489A1

公开(公告)日：2010-12-09

申请号：US12739335

申请日：2007-10-23

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01J49/26 ,  G06F19/00

CPC分类号： G06F19/703 ,  G01N33/6848 ,  H01J49/0027 ,  H01J49/004

摘要： A product ion spectrum is created on the basis of MS2 analysis data respectively obtained for a parent compound and a metabolite (S1 and S2). Additionally, a neutral loss spectrum, in which the mass of each product ion is replaced with a mass difference between the mass of the product ion and that of a precursor ion, is created (S3). Then, a common peak having the same mass on the neutral loss spectrums of both the parent compound and the metabolite is extracted (S4), and a complementary peak appearing on the product ion spectrum of the metabolite is extracted (S5); this peak appears at a position corresponding to the difference between the mass of the common peak and that of the precursor ion. The ion corresponding to the complementary peak is designated as a precursor ion for the next MS3 analysis (S6), and this MS3 analysis is performed (S7). By a dissociation operation, if a portion common to the parent compound and the metabolite is desorbed in the form of a neutral molecule while a different portion remains in the form of an ion, an MS3 analysis in which the ion of the different portion is used as the precursor ion is performed to obtain structural information of a site of metabolism.

摘要翻译： 基于分别为母体化合物和代谢物获得的MS2分析数据产生产物离子谱（S1和S2）。 另外，产生中性损失谱，其中每个产物离子的质量被产物离子的质量与前体离子的质量之间的质量差代替（S3）。 然后，提取母体化合物和代谢物的中性损失谱具有相同质量的共同峰（S4），并提取出现在代谢产物的产物离子谱上的互补峰（S5）; 该峰出现在对应于共峰的质量与前体离子的质量之间的差异的位置处。 对应于互补峰的离子被指定为用于下一个MS3分析的前体离子（S6），并且执行该MS3分析（S7）。 通过解离操作，如果母体化合物和代谢物共同的部分以中性分子的形式解吸，而不同部分保持为离子的形式，则使用不同部分的离子被使用的MS3分析 因为进行前体离子以获得代谢位点的结构信息。

公开(公告)号：US20100312487A1

公开(公告)日：2010-12-09

申请号：US12445882

申请日：2006-11-15

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： G06F19/00

CPC分类号： G01N27/62 ,  H01J49/0036

摘要： In deducing the composition of an unknown metabolite, information on the kind of reaction and the component which is added or dropped is provided, based on the prediction and knowledge on the pathways of metabolism (S5). Then, based on the information, the kind of elements and the maximum value of the increase and decrease in the number of atoms of the elements are computed. In addition, based on the values and the composition of the original substance, the kind of the unknown substance and the possible range of numbers of atoms thereof are obtained (S6 and S7). Using the element's kind and range of numbers as a computational condition, the combination of elements that matches the mass of the unknown metabolite obtained by a mass analysis is searched to deduce the composition of the unknown metabolite (S8). Since the computational condition is fairly limited, the composition can be deduced with a practical amount of computation and with a high degree of accuracy.

摘要翻译： 在推测未知代谢物的组成时，根据对代谢途径的预测和知识，提供关于反应种类和添加或降解成分的信息（S5）。 然后，根据信息，计算元素的种类和元素原子数的增减的最大值。 此外，基于原料的值和组成，得到未知物质的种类和原子数的可能范围（S6和S7）。 使用元素种类和数量范围作为计算条件，搜索与通过质量分析获得的未知代谢物的质量匹配的元素的组合以推导出未知代谢物的组成（S8）。 由于计算条件相当有限，所以可以用实际的计算量和高精度推导出组合。

公开(公告)号：US20100258716A1

公开(公告)日：2010-10-14

申请号：US12743932

申请日：2007-11-11

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01J49/40

CPC分类号： H01J49/061 ,  H01J49/408

摘要： A mass analysis is initially performed while applying appropriate voltages to the electrodes so that ions injected through an entrance gate electrode (5) into a loop orbit (3) are guided through approximately one half of the loop orbit (3) and diverted at an exit gate electrode (6) toward an ion detector (7). Based on the intensities of the peaks appearing on a mass spectrum obtained by this mass analysis, one or more objective ions are selected and a time parameter is specified so that the voltage applied to the exit gate electrode (6) changes when none of the ions flying along the loop orbit (3) are passing through the exit gate electrode (6). As a result, the orbit of the objective ions will assuredly changed so that they will be directed toward the ion detector (7) after flying through the loop orbit (3) multiple times. Thus, the mass information of the objective ions can be assuredly obtained.

摘要翻译： 最初执行质量分析，同时向电极施加适当的电压，使得通过入口栅电极（5）注入环形轨道（3）的离子被引导通过环路轨道（3）的大约一半，并在出口 栅电极（6）朝向离子检测器（7）。 基于通过该质量分析获得的质谱出现的峰的强度，选择一个或多个目标离子，并且指定时间参数，使得当没有离子时，施加到出口栅极（6）的电压发生变化 沿环路轨道（3）飞行通过出口栅电极（6）。 结果，目标离子的轨道将确实改变，使得它们在通过环轨道（3）多次之后被引向离子检测器（7）。 因此，可以确实地获得目标离子的质量信息。

公开(公告)号：US20090159789A1

公开(公告)日：2009-06-25

申请号：US12296360

申请日：2006-04-07

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01J49/00

CPC分类号： H01J49/0004

摘要： A laser light is linearly delivered onto the sample 4. The ions generated from the irradiated area are collected, mass-separated in the mass separator 27, and detected by the detector 28. A mass analysis is repeated while moving the sample stage 3 by a predetermined step width in the x-axis direction so that the one-dimensional mass spectrum information of the sample 4 at a certain rotational position is obtained. Additionally, while the sample 4 is rotated by a predetermined angle, the same measurement is repeated for the entire perimeter, so that the one-dimensional mass spectrum information at each rotational position is obtained. Based on the data obtained in this manner, a reconstruction computational processing is performed by the CT method to reconstruct the two-dimensional distribution image for a substance having a certain mass for example and the image is displayed on the display 35.

摘要翻译： 将激光线性地传送到样品4上。从照射区域产生的离子在质量分离器27中被收集，质量分离，并由检测器28检测。重复质量分析，同时将样品台3移动 使x轴方向的规定的台阶宽度成为一定的旋转位置的样品4的一维质谱信息。 此外，当样品4旋转预定角度时，对于整个周边重复相同的测量，从而获得每个旋转位置处的一维质谱信息。 基于以这种方式获得的数据，通过CT方法进行重建计算处理，以重构用于具有一定质量的物质的二维分布图像，并且图像显示在显示器35上。

公开(公告)号：US20090008548A1

公开(公告)日：2009-01-08

申请号：US12166707

申请日：2008-07-02

申请人： Shinichi Yamaguchi

发明人： Shinichi Yamaguchi

IPC分类号： H01J49/26

CPC分类号： H01J49/0027 ,  G01N30/72 ,  G01N30/8624 ,  G06F19/703 ,  H01J49/004

摘要： A chromatograph mass spectrometer is provided for obtaining the information pertinent to a structural analysis, with a simple operation, on a compound series including a plurality of compounds whose structures and characters are similar. First, based on the data obtained by a normal LC/MS analysis, a two-dimensional isointensity line graph is created and displayed with a retention time and a mass-to-charge ratio on the two axes and with a signal intensity represented in contour (S1 and S2). When the operator specifies a desired range by a drag operation or the like by a mouse (S3), peaks included in the range specified are extracted and based on the peaks, precursor ions are selected (S4 through S6). Then a schedule is created so that an MS2 analysis is performed for the precursor ions selected in the course of an LC/MS analysis for the sample to be targeted (S7). Analyses are performed while properly performing the precursor ions' selection/dissociation process in accordance with the schedule to collect the MS2 spectrum data (S8).

摘要翻译： 提供了一种色谱质谱仪，用于通过简单的操作获得与包括其结构和特征相似的多种化合物的化合物系列相关的信息。 首先，基于通过正常LC / MS分析获得的数据，创建并显示二维等距线图，其中在两轴上具有保持时间和质荷比，并且以轮廓表示的信号强度 （S1和S2）。 当操作者通过鼠标的拖动操作等指定期望的范围时（S3），提取包括在指定范围内的峰值，并且基于峰值，选择前体离子（S4至S6）。 然后创建一个时间表，以便对LC / MS分析过程中所选择的前体离子进行MS2分析，以进行对象样本（S7）。 在根据调度来适当地执行前体离子的选择/解离过程以收集MS2光谱数据的同时进行分析（S8）。