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公开(公告)号：US20080188687A1
公开(公告)日：2008-08-07
申请号：US12078293
申请日：2008-03-28
IPC分类号： C07F3/02
CPC分类号： C08F110/06 , C07C29/70 , C08F10/00 , C08F10/06 , C08F4/6543 , C08F4/651 , C08F4/6548 , C08F4/6565 , C08F2500/15 , C08F2500/24 , C07C31/30
摘要： A magnesium compound obtained by reacting metallic magnesium having a sphericity (S) of less than 4.00, the sphericity (S) being represented by the following formula (I), an alcohol, and a halogen and/or a halogen-containing compound containing halogen atoms in an amount of 0.0001 gram atom or more relative to one gram atom of the metallic magnesium, S=(L1/L2)3 (I) wherein L1 represents the maximum diameter of projection views of metallic magnesium determined by photographing with a scanning electron microscope and thereafter an image processing, and L2 represents a diameter of a circle having an area equal to the area of the projection view of metallic magnesium. A solid catalyst component is obtained from the magnesium compound and a titanium compound, and a catalyst for olefin polymerization is obtained using the solid catalyst component.
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公开(公告)号：US07071138B2
公开(公告)日：2006-07-04
申请号：US10493550
申请日：2002-11-01
申请人： Shojiro Tanase , Takanori Sadashima
发明人： Shojiro Tanase , Takanori Sadashima
CPC分类号： C08F110/06 , C08F4/651 , C08F4/6565 , C08F4/6548 , C08F2500/15 , C08F2500/18 , C08F2500/24 , C08F2500/17
摘要： A solid catalyst component for olefin polymerization in which the molar ratio of residual alkoxy groups to supported titanium is 0.60 or less is obtained by reacting the following compound (a1) with the following compound (b1) at a hydroxyl group/magnesium molar ratio of 1.0 or more, reacting the reaction mixture with the following compound (c1) at a halogen/magnesium molar ratio of 0.20 or more, reacting the resultant reaction mixture with the following compounds (d1) and (e) at a temperature of 120° C. or higher but 150° C. or lower, washing the reaction mixture with an inert solvent, reacting the reaction mixture with the following compound (e) again at the above temperature and washing the reaction mixture with an inert solvent, whereby there can be provided the solid catalyst component for olefin polymerization and a catalyst for olefin polymerization which have high polymerization activity and give an olefin polymer having a less residual Cl content and being excellent in stereoregularity and powder form and a process for producing an olefin polymer, (a1) an oxide of at least one element that is selected from Group II to Group IV elements and which supports an alcohol-free halogen-containing magnesium compound, (b1) an alcohol, (c1) a halogen-containing silicon compound, (d1) an electron-donating compound, and (e) a halogen-containing titanium compound.
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公开(公告)号：US07081427B2
公开(公告)日：2006-07-25
申请号：US10473517
申请日：2002-04-19
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6541 , C08F4/651 , C08F4/6565 , C08F2500/15 , C08F2500/17
摘要： A solid catalyst component for olefin polymerization comprising titanium, magnesium and a compound of the general formula (I) wherein R1 and R2 are independently a C3 straight or branched hydrocarbon group, R3 is hydrogen or a C1-4 straight hydrocarbon group, R4 is a C1-4 straight or branched hydrocarbon group or a C3-4 aliphatic cyclic hydrocarbon group when R3 is hydrogen, R4 is the same C1-4 straight hydrocarbon group as R3 when R3 is a C1-4 straight hydrocarbon group, and n is an integer of 1 to 10. A catalyst for olefin polymerization, containing this catalyst component, obtains a high activity with high stereospecificity.
摘要翻译： 一种用于烯烃聚合的固体催化剂组分，其包含钛，镁和通式（I）的化合物，其中R 1和R 2独立地是C 3 - / SUB>直链或支链烃基，R 3是氢或C 1-4烷基直链烃基，R 4是C < 当R 3为氢时，R 4为直链或支链烃基或C 3-4脂族环状烃基， 当R 3是C 1-4烷基时，R S是与R 3相同的C 1-4烷基直链烃基， / SUB>直链烃基，n为1〜10的整数。含有该催化剂成分的烯烃聚合用催化剂以高立体定向性获得高活性。
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24.发明授权Organosilicon compound, catalyst for olefin polymer production, and method for producing olefin polymer 失效有机硅化合物，烯烃聚合物生产用催化剂和烯烃聚合物的制造方法公开(公告)号：US06552136B1
公开(公告)日：2003-04-22
申请号：US09774174
申请日：2001-02-01
IPC分类号： C08F442
CPC分类号： C08F110/06 , C08F4/6465 , C08F4/6545 , C08F4/6565 , C08F2500/15 , C08F2500/17 , C08F2500/12
摘要： Provided are a catalyst for olefin polymer production, which contains an organosilicon compound having a specific structure and with which olefin polymers produced have increased stereospecificity and increased melt fluidity; and a method for producing such olefin polymers.
摘要翻译： 提供了一种用于烯烃聚合物生产的催化剂，其包含具有特定结构的有机硅化合物，并且所生产的烯烃聚合物具有增加的立体定向性和增加的熔体流动性; 以及这种烯烃聚合物的制造方法。
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25.发明授权Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymers 失效用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂，以及烯烃聚合物的制备方法公开(公告)号：US06495639B1
公开(公告)日：2002-12-17
申请号：US09665051
申请日：2000-09-19
IPC分类号： C08F21000
摘要： Provided are a solid catalyst component for olefin polymerization and a catalyst comprising the component for olefin polymerization, in which the electron donor is free from the problem of lacking in safety and sanitation, and is inexpensive and easy to produce, and which exhibit high activity in producing olefin polymers with high stereospecificity, and also a method for producing olefin polymers in the presence of the catalyst. The solid catalyst component comprises titanium, magnesium and an electron donor compound of formula (I): wherein R1 and R2 each represent a linear or branched hydrocarbon residue having from 1 to 20 carbon atoms; R3 represents an alicyclic hydrocarbon residue having from 3 to 20 carbon atoms; and n represents an integer of from 1 to 10. The solid catalyst component is combined with an organic aluminium compound to prepare a catalyst, which is used in producing olefin polymers.
摘要翻译： 提供了用于烯烃聚合的固体催化剂组分和包含用于烯烃聚合的组分的催化剂，其中电子给体没有安全和卫生缺乏的问题，并且便宜并且易于生产，并且其表现出高的活性 制备具有高立体定向性的烯烃聚合物，以及在催化剂存在下生产烯烃聚合物的方法。 固体催化剂组分包括钛，镁和式（I）的电子给体化合物：其中R 1和R 2各自表示具有1至20个碳原子的直链或支链烃残基; R3表示具有3至20个碳原子的脂环族烃残基; n表示1〜10的整数。将固体催化剂成分与有机铝化合物结合，制备用于制造烯烃聚合物的催化剂。
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26.发明授权Solid catalyst components for olefin polymerization, catalysts for olefin polymerization and process for producing olefin polymers 失效用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂和用于生产烯烃聚合物的方法公开(公告)号：US06331620B1
公开(公告)日：2001-12-18
申请号：US09463999
申请日：2000-02-22
IPC分类号： C08F200
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6548 , C08F4/651 , C08F2500/15 , C08F2500/17
摘要： Solid catalyst components for the polymerization of olefins, comprising titanium, magnesium and a compound of general formula (I), wherein R1 and R2 may be the same or different and each represents a linear or branched hydrocarbon group having 1 to 20 carbon atoms, and n is an integer of 1 to 10, as an electron donor, which are combined with organoaluminum compounds to form polymerization catalysts for the production of olefin polymers. This electron donor has no problems of safety and hygiene, and is inexpensive and easily synthesized. This compound can provide highly active and highly stereoregular solid catalyst components for the polymerization of olefins, catalysts for the polymerization of olefins, and processes for producing olefin polymers.
摘要翻译： 用于烯烃聚合的固体催化剂组分，包括钛，镁和通式（I）的化合物，其中R 1和R 2可以相同或不同，并且各自表示具有1至20个碳原子的直链或支链烃基，和 n为1〜10的整数，作为电子给体，与有机铝化合物结合形成用于制备烯烃聚合物的聚合催化剂。 该电子给体没有安全和卫生的问题，并且便宜且易于合成。 该化合物可以为烯烃的聚合，烯烃聚合用催化剂和烯烃聚合物的制备方法提供高活性和高度立构规整的固体催化剂组分。
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27.发明授权Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymers 失效用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂，以及烯烃聚合物的制备方法公开(公告)号：US06204215B1
公开(公告)日：2001-03-20
申请号：US09200851
申请日：1998-11-30
IPC分类号： B01J03104
摘要： Provided are a solid catalyst component for olefin polymerization and a catalyst comprising the component for olefin polymerization, in which the electron donor is free from the problem of lacking in safety and sanitation, and is inexpensive and easy to produce, and which exhibit high activity in producing olefin polymers with high stereospecificity, and also a method for producing olefin polymers in the presence of the catalyst. The solid catalyst component comprises titanium, magnesium and an electron donor compound of formula (I): wherein R1 and R2 each represent a linear or branched hydrocarbon residue having from 1 to 20 carbon atoms; R3 represents an alicyclic hydrocarbon residue having from 3 to 20 carbon atoms; and n represents an integer of from 1 to 10. The solid catalyst component is combined with an organic aluminium compound to prepare a catalyst, which is used in producing olefin polymers.
摘要翻译： 提供了用于烯烃聚合的固体催化剂组分和包含用于烯烃聚合的组分的催化剂，其中电子给体没有安全和卫生缺乏的问题，并且便宜并且易于生产，并且其表现出高的活性 制备具有高立体定向性的烯烃聚合物，以及在催化剂存在下生产烯烃聚合物的方法。 固体催化剂组分包括钛，镁和式（I）的电子给体化合物：其中R 1和R 2各自表示具有1至20个碳原子的直链或支链烃残基; R3表示具有3至20个碳原子的脂环族烃残基; n表示1〜10的整数。将固体催化剂成分与有机铝化合物结合，制备用于制造烯烃聚合物的催化剂。
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28.发明授权Catalyst for bulk polymerization, catalyst for vapor phase polymerization, method of polymerization using these, and olefin polymer obtained with these 失效用于本体聚合的催化剂，用于气相聚合的催化剂，使用它们的聚合方法以及用它们获得的烯烃聚合物公开(公告)号：US06689849B1
公开(公告)日：2004-02-10
申请号：US10018478
申请日：2001-12-19
IPC分类号： C08F442
CPC分类号： C08F110/06 , Y10S526/901 , Y10S526/902 , C08F4/6565 , C08F4/6465 , C08F2500/12 , C08F2500/17
摘要： The present invention provides a catalyst for bulk or vapor-phase polymerization having high polymerization activity during bulk or vapor-phase polymerization and providing an olefin polymer having excellent properties in melt flow rate and stereoregularity by adding a small amount of hydrogen. The catalyst for bulk or vapor-phase polymerization of an &agr;-olefin compound under a presence of hydrogen, the catalyst is made by contacting the following ingredients (A) to (C). (A) a solid catalyst ingredient, comprising: (a) a magnesium compound, (b) titanium tetrachloride, and (c) dialkyl phthalate (Each of the alkyl group denotes a straight-chain or branched-chain hydrocarbon group having a carbon number of 3 to 20.); (B) an organoaluminum compound; and (C) an organosilicon compound, which is expressed by the following general chemical formula (1). (R1)(R2CH2)Si(OR3)(OR4) (1)
摘要翻译： 本发明提供一种用于本体或气相聚合时具有高聚合活性的本体或气相聚合催化剂，并通过加入少量氢提供具有优异的熔体流动速率和立构规整性的烯烃聚合物。本体催化剂 或在氢气存在下气相聚合α-烯烃化合物，催化剂是通过使以下成分（A）与（C）接触来制备的。（A）固体催化剂成分，其包含：（a）镁化合物 ，（b）四氯化钛和（c）邻苯二甲酸二烷基酯（每个烷基表示碳数为3〜20的直链或支链烃基）;（B）有机铝化合物; 和（C）由以下通式（1）表示的有机硅化合物。
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