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    Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymers
    6.
    发明授权
    Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymers 失效
    用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂，以及烯烃聚合物的制备方法

    公开(公告)号：US06204215B1

    公开(公告)日：2001-03-20

    申请号：US09200851

    申请日：1998-11-30

    申请人： Yasunori Kadoi ,  Tsuyoshi Ota ,  Toshio Isozaki ,  Kiyokazu Katayama ,  Takanori Sadashima

    发明人： Yasunori Kadoi ,  Tsuyoshi Ota ,  Toshio Isozaki ,  Kiyokazu Katayama ,  Takanori Sadashima

    IPC分类号： B01J03104

    CPC分类号： C08F10/00 ,  C08F4/651

    摘要： Provided are a solid catalyst component for olefin polymerization and a catalyst comprising the component for olefin polymerization, in which the electron donor is free from the problem of lacking in safety and sanitation, and is inexpensive and easy to produce, and which exhibit high activity in producing olefin polymers with high stereospecificity, and also a method for producing olefin polymers in the presence of the catalyst. The solid catalyst component comprises titanium, magnesium and an electron donor compound of formula (I): wherein R1 and R2 each represent a linear or branched hydrocarbon residue having from 1 to 20 carbon atoms; R3 represents an alicyclic hydrocarbon residue having from 3 to 20 carbon atoms; and n represents an integer of from 1 to 10. The solid catalyst component is combined with an organic aluminium compound to prepare a catalyst, which is used in producing olefin polymers.

    摘要翻译： 提供了用于烯烃聚合的固体催化剂组分和包含用于烯烃聚合的组分的催化剂，其中电子给体没有安全和卫生缺乏的问题，并且便宜并且易于生产，并且其表现出高的活性 制备具有高立体定向性的烯烃聚合物，以及在催化剂存在下生产烯烃聚合物的方法。 固体催化剂组分包括钛，镁和式（I）的电子给体化合物：其中R 1和R 2各自表示具有1至20个碳原子的直链或支链烃残基; R3表示具有3至20个碳原子的脂环族烃残基; n表示1〜10的整数。将固体催化剂成分与有机铝化合物结合，制备用于制造烯烃聚合物的催化剂。

    Process for producing α-olefin polymer
    10.
    发明授权
    Process for producing α-olefin polymer 失效
    生产α-烯烃聚合物的方法

    公开(公告)号：US06870022B2

    公开(公告)日：2005-03-22

    申请号：US10333924

    申请日：2001-07-26

    申请人： Takeshi Iwasaki ,  Tadanori Jyunke ,  Kiyokazu Katayama ,  Kenji Tanaka

    发明人： Takeshi Iwasaki ,  Tadanori Jyunke ,  Kiyokazu Katayama ,  Kenji Tanaka

    IPC分类号： C08F4/646 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F297/08 ,  C08L23/10 ,  C08L23/16

    CPC分类号： C08F297/083 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F297/08 ,  C08F2410/01 ,  C08L23/10 ,  C08L23/16 ,  C08L2308/00 ,  C08L2314/02 ,  C08F4/6565 ,  C08F4/646 ,  C08F4/6492 ,  C08L2666/06 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/15 ,  C08F210/16

    摘要： An α-olefin polymer having extremely high stereoregularity, exhibiting excellent fluidity and containing a decreased amount of catalyst residues in the polymer can be obtained industrially advantageously in accordance with a process for producing an α-olefin polymer which comprises homopolymerizing an α-olefin or copolymerizing two or more α-olefins in the presence of (A) a solid catalyst component comprising magnesium, titanium and a halogen, (B) an organoaluminum compound having a content of hydroaluminum compounds of 0.1% by weight or smaller and (C) an organozinc compound.A block copolymer of propylene comprising a homopolymer portion exhibiting high fluidity and a copolymer portion having a high molecular weight can be obtained in accordance with a process for producing a block copolymer of propylene which comprises polymerizing propylene in the presence of (A) a solid catalyst component comprising a titanium compound and an electron-donating agent, (B) an organoaluminum compound and (C) an organozinc compound to produce crystalline polypropylene and copolymerizing propylene and at least one of ethylene and α-olefins having 4 or more carbon atoms in the presence of the produced crystalline polypropylene.

    摘要翻译： 具有极高立构规整性的，具有优异的流动性并且含有聚合物中催化剂残余量减少的α-烯烃聚合物可以在工业上有利地根据生产α-烯烃聚合物的方法获得，该方法包括使α-烯烃均聚或共聚 （A）包含镁，钛和卤素的固体催化剂组分存在下的两种或更多种α-烯烃，（B）具有0.1重量％以下的氢化铝化合物含量的有机铝化合物和（C）有机锌 根据生产丙烯嵌段共聚物的方法，可以获得包含显示出高流动性的均聚物部分的丙烯嵌段共聚物和具有高分子量的共聚物部分的嵌段共聚物，该方法包括在（A） 包含钛化合物和给电子剂的固体催化剂组分，（B）有机物 铝化合物和（C）有机锌化合物，以在生产的结晶聚丙烯的存在下制备结晶聚丙烯并共聚丙烯和具有4个或更多个碳原子的乙烯和α-烯烃中的至少一种。