公开(公告)号：US20150239803A1

公开(公告)日：2015-08-27

申请号：US14683252

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C2/86 ,  C07C41/06 ,  C07C11/10 ,  C08F36/08 ,  C07C1/207

CPC classification number: C07C2/867 ,  C07C1/2074 ,  C07C1/24 ,  C07C2/10 ,  C07C2521/06 ,  C07C2523/06 ,  C08F36/08 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/09 ,  C07C11/18 ,  C08F210/12 ,  C08F236/08

Abstract: Processes are described for making biobased isoprene, wherein a biobased isobutene prepared from acetic acid in the presence of a catalyst is combined with a formaldehyde source to form a reaction mixture, and the reaction mixture is reacted to yield biobased isoprene. In certain embodiments, methyl-tert-butyl ether prepared by reacting the same biobased isobutene with methanol serves as a formaldehyde source, being oxidatively cracked to produce formaldehyde as well as isobutene for being converted to the biobased isoprene.

Abstract translation: 描述了用于制备生物基异戊二烯的方法，其中在催化剂存在下由乙酸制备的生物基异丁烯与甲醛源组合以形成反应混合物，并使反应混合物反应以产生生物基异戊二烯。 在某些实施方案中，通过使相同的生物基异丁烯与甲醇反应制备的甲基 - 叔丁基醚用作甲醛源，被氧化裂化以产生甲醛以及异丁烯转化为生物基异戊二烯。

公开(公告)号：US20150239800A1

公开(公告)日：2015-08-27

申请号：US14683236

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C1/207

CPC classification number: C07C1/2078 ,  C07C1/207 ,  C07C2521/06 ,  C07C2523/06 ,  C07C11/06 ,  C07C11/09

Abstract: A process is disclosed for converting acetic acid to propylene and isobutene as the principal hydrocarbon products made, in the presence of a catalyst and in the further presence of hydrogen. In certain embodiments, a ZnxZryOz mixed oxide catalyst is used for carrying out a gas phase process, and propylene is produced preferentially to isobutene by using at least a certain amount of hydrogen in the process. In some embodiments, a ZnxZryOz mixed oxide catalyst made by an incipient wetness impregnation method is used and is indicated to be very stable for carrying out the conversion.

Abstract translation: 公开了一种将乙酸转化为丙烯和异丁烯作为主要烃产物的方法，在催化剂存在下和在氢的存在下制备。 在某些实施方案中，使用Zn x Zn y O z混合氧化物催化剂进行气相方法，并且通过在该方法中使用至少一定量的氢气优先产生丙烯。 在一些实施方案中，使用通过初始润湿浸渍法制备的Zn x ZrO x z混合氧化物催化剂，并且表明对于进行转化是非常稳定的。

公开(公告)号：US09212106B2

公开(公告)日：2015-12-15

申请号：US14105249

申请日：2013-12-13

Applicant: Washington State University ,  ARCHER DANIELS MILDAND COMPANY

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Joshua Terrian

IPC: B01J23/06 ,  C07C1/207 ,  C07C5/327 ,  C07C5/48 ,  C10G3/00 ,  B01J21/06 ,  C07C29/60 ,  C07C51/235 ,  C07C29/00 ,  C12P7/52 ,  C12P7/54

CPC classification number: C07C1/2078 ,  B01J21/066 ,  B01J23/06 ,  C07C1/207 ,  C07C1/2074 ,  C07C2/12 ,  C07C5/327 ,  C07C5/48 ,  C07C29/00 ,  C07C29/60 ,  C07C51/12 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C10G3/00 ,  C10G3/44 ,  C10G3/50 ,  C10G9/00 ,  C10G2400/20 ,  C10G2400/22 ,  C12P7/52 ,  C12P7/54 ,  Y02P20/52 ,  C07C11/10 ,  C07C11/09 ,  C07C11/18 ,  C07C31/202 ,  C07C31/205 ,  C07C53/08 ,  C07C53/122 ,  C07C11/167 ,  C07C11/06 ,  C07C11/08

Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene, 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic and through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a ZnxZryOz mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C3, C4 and C5 constituents of the product mixture.

Abstract translation: 描述了从乙酸和丙酸的混合物中制备包括异丁烯，丙烯，1-丁烯，2-丁烯，2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法，并通过在 存在氢源和混合氧化物催化剂，例如Zn x ZrO 2混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C5组分依次制备各种商业上有价值的产品。

公开(公告)号：US20140128650A1

公开(公告)日：2014-05-08

申请号：US14105249

申请日：2013-12-13

Applicant: ARCHER DANIELS MILDAND COMPANY ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Joshua Terrian

IPC: C07C1/207 ,  C07C5/327 ,  C07C5/48

CPC classification number: C07C1/2078 ,  B01J21/066 ,  B01J23/06 ,  C07C1/207 ,  C07C1/2074 ,  C07C2/12 ,  C07C5/327 ,  C07C5/48 ,  C07C29/00 ,  C07C29/60 ,  C07C51/12 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C10G3/00 ,  C10G3/44 ,  C10G3/50 ,  C10G9/00 ,  C10G2400/20 ,  C10G2400/22 ,  C12P7/52 ,  C12P7/54 ,  Y02P20/52 ,  C07C11/10 ,  C07C11/09 ,  C07C11/18 ,  C07C31/202 ,  C07C31/205 ,  C07C53/08 ,  C07C53/122 ,  C07C11/167 ,  C07C11/06 ,  C07C11/08

Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic and through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a ZnxZryOz mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C3, C4 and C3 constituents of the product mixture

Abstract translation: 描述了从乙酸和丙酸的混合物中制备包括异丁烯，丙烯，1-丁烯，2-丁烯-2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法，并通过在存在下的反应 的氢源和混合氧化物催化剂，例如Zn x Zr y O z混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C3组分依次制备各种商业上有价值的产品