公开(公告)号：US09212106B2

公开(公告)日：2015-12-15

申请号：US14105249

申请日：2013-12-13

Applicant: Washington State University ,  ARCHER DANIELS MILDAND COMPANY

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Joshua Terrian

IPC: B01J23/06 ,  C07C1/207 ,  C07C5/327 ,  C07C5/48 ,  C10G3/00 ,  B01J21/06 ,  C07C29/60 ,  C07C51/235 ,  C07C29/00 ,  C12P7/52 ,  C12P7/54

CPC classification number: C07C1/2078 ,  B01J21/066 ,  B01J23/06 ,  C07C1/207 ,  C07C1/2074 ,  C07C2/12 ,  C07C5/327 ,  C07C5/48 ,  C07C29/00 ,  C07C29/60 ,  C07C51/12 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C10G3/00 ,  C10G3/44 ,  C10G3/50 ,  C10G9/00 ,  C10G2400/20 ,  C10G2400/22 ,  C12P7/52 ,  C12P7/54 ,  Y02P20/52 ,  C07C11/10 ,  C07C11/09 ,  C07C11/18 ,  C07C31/202 ,  C07C31/205 ,  C07C53/08 ,  C07C53/122 ,  C07C11/167 ,  C07C11/06 ,  C07C11/08

Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene, 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic and through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a ZnxZryOz mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C3, C4 and C5 constituents of the product mixture.

Abstract translation: 描述了从乙酸和丙酸的混合物中制备包括异丁烯，丙烯，1-丁烯，2-丁烯，2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法，并通过在 存在氢源和混合氧化物催化剂，例如Zn x ZrO 2混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C5组分依次制备各种商业上有价值的产品。

公开(公告)号：US20140128650A1

公开(公告)日：2014-05-08

申请号：US14105249

申请日：2013-12-13

Applicant: ARCHER DANIELS MILDAND COMPANY ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Colin Smith ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Joshua Terrian

IPC: C07C1/207 ,  C07C5/327 ,  C07C5/48

CPC classification number: C07C1/2078 ,  B01J21/066 ,  B01J23/06 ,  C07C1/207 ,  C07C1/2074 ,  C07C2/12 ,  C07C5/327 ,  C07C5/48 ,  C07C29/00 ,  C07C29/60 ,  C07C51/12 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C10G3/00 ,  C10G3/44 ,  C10G3/50 ,  C10G9/00 ,  C10G2400/20 ,  C10G2400/22 ,  C12P7/52 ,  C12P7/54 ,  Y02P20/52 ,  C07C11/10 ,  C07C11/09 ,  C07C11/18 ,  C07C31/202 ,  C07C31/205 ,  C07C53/08 ,  C07C53/122 ,  C07C11/167 ,  C07C11/06 ,  C07C11/08

Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic and through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a ZnxZryOz mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C3, C4 and C3 constituents of the product mixture

Abstract translation: 描述了从乙酸和丙酸的混合物中制备包括异丁烯，丙烯，1-丁烯，2-丁烯-2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法，并通过在存在下的反应 的氢源和混合氧化物催化剂，例如Zn x Zr y O z混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C3组分依次制备各种商业上有价值的产品

公开(公告)号：US20150239812A1

公开(公告)日：2015-08-27

申请号：US14683187

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C41/06 ,  C07C1/207 ,  C10L10/10 ,  C07C43/04 ,  C10L1/18

Abstract: Wholly biobased MTBE and ETBE fuel additive materials are described, together with fuel compositions including such additives and processes for making the wholly biobased MTBE and ETBE using isobutene prepared from acetic acid in the presence of a ZnxZryOz mixed oxide catalyst.

Abstract translation: 描述了完全生物基的MTBE和ETBE燃料添加剂材料，以及包括这些添加剂的燃料组合物以及使用由Zn x Z y O z混合氧化物催化剂存在下由乙酸制备的异丁烯制备全生物基MTBE和ETBE的方法。

公开(公告)号：US20160289155A1

公开(公告)日：2016-10-06

申请号：US15183991

申请日：2016-06-16

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C51/25 ,  C07C1/207 ,  B01J23/06 ,  C07C45/35

CPC classification number: C07C51/252 ,  B01J23/06 ,  C07C1/20 ,  C07C1/2074 ,  C07C1/2078 ,  C07C45/35 ,  C07C2521/06 ,  C07C2523/06 ,  C07C47/22 ,  C07C57/04 ,  C07C11/09

Abstract: Processes are described for making methacrylic acid via methacrolein from a biobased isobutene, wherein the biobased isobutene is prepared from ethanol or from acetic acid in the presence of a ZnxZryOz mixed oxide catalyst, the biobased isobutene is oxidized to methacrolein and the methacrolein is further oxidized to methacrylic acid.

公开(公告)号：US09403749B2

公开(公告)日：2016-08-02

申请号：US14683257

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C51/25 ,  C07C45/35 ,  C07C1/20 ,  C07C1/207

CPC classification number: C07C51/252 ,  B01J23/06 ,  C07C1/20 ,  C07C1/2074 ,  C07C1/2078 ,  C07C45/35 ,  C07C2521/06 ,  C07C2523/06 ,  C07C47/22 ,  C07C57/04 ,  C07C11/09

Abstract: Processes are described for making methacrylic acid via methacrolein from a biobased isobutene, wherein the biobased isobutene is prepared from ethanol or from acetic acid in the presence of a ZnxZryOz mixed oxide catalyst, the biobased isobutene is oxidized to methacrolein and the methacrolein is further oxidized to methacrylic acid.

Abstract translation: 描述了通过甲基丙烯醛从生物基异丁烯制备甲基丙烯酸的方法，其中生物基异丁烯由乙酸或乙酸在Zn x Z y O z混合氧化物催化剂存在下制备，生物基异丁烯被氧化成甲基丙烯醛，甲基丙烯醛被进一步氧化成 甲基丙烯酸。

公开(公告)号：US10774022B2

公开(公告)日：2020-09-15

申请号：US14683187

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C43/04 ,  C07C2/00 ,  C07C41/06 ,  C10L10/10 ,  C10L1/185 ,  C07C1/207 ,  C10L1/02

Abstract: Wholly biobased MTBE and ETBE fuel additive materials are described, together with fuel compositions including such additives and processes for making the wholly biobased MTBE and ETBE using isobutene prepared from acetic acid in the presence of a ZnxZryOz mixed oxide catalyst.

公开(公告)号：US09975818B2

公开(公告)日：2018-05-22

申请号：US14683252

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C2/86 ,  C08F36/08 ,  C07C1/207 ,  C07C1/24 ,  C07C2/10

CPC classification number: C07C2/867 ,  C07C1/2074 ,  C07C1/24 ,  C07C2/10 ,  C07C2521/06 ,  C07C2523/06 ,  C08F36/08 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/09 ,  C07C11/18 ,  C08F210/12 ,  C08F236/08

Abstract: Processes are described for making biobased isoprene, wherein a biobased isobutene prepared from acetic acid in the presence of a catalyst is combined with a formaldehyde source to form a reaction mixture, and the reaction mixture is reacted to yield biobased isoprene. In certain embodiments, methyl-tert-butyl ether prepared by reacting the same biobased isobutene with methanol serves as a formaldehyde source, being oxidatively cracked to produce formaldehyde as well as isobutene for being converted to the biobased isoprene.

公开(公告)号：US20150218077A1

公开(公告)日：2015-08-06

申请号：US14683257

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C51/25 ,  C07C1/20 ,  C07C1/207 ,  C07C45/35

CPC classification number: C07C51/252 ,  B01J23/06 ,  C07C1/20 ,  C07C1/2074 ,  C07C1/2078 ,  C07C45/35 ,  C07C2521/06 ,  C07C2523/06 ,  C07C47/22 ,  C07C57/04 ,  C07C11/09

Abstract: Processes are described for making methacrylic acid via methacrolein from a biobased isobutene, wherein the biobased isobutene is prepared from ethanol or from acetic acid in the presence of a ZnxZryOz mixed oxide catalyst, the biobased isobutene is oxidized to methacrolein and the methacrolein is further oxidized to methacrylic acid.

Abstract translation: 描述了通过甲基丙烯醛从生物基异丁烯制备甲基丙烯酸的方法，其中生物基异丁烯由乙酸或乙酸在Zn x Z y O z混合氧化物催化剂存在下制备，生物基异丁烯被氧化成甲基丙烯醛，甲基丙烯醛被进一步氧化成 甲基丙烯酸。

公开(公告)号：US20150217273A1

公开(公告)日：2015-08-06

申请号：US14683787

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian ,  Colin Smith

IPC: B01J23/06 ,  B01J37/08 ,  B01J27/02 ,  C07C1/20

CPC classification number: H01L21/823842 ,  B01J21/04 ,  B01J21/06 ,  B01J23/06 ,  B01J27/02 ,  B01J37/08 ,  C07C1/20 ,  C07C2523/06 ,  H01L21/26513 ,  H01L21/823821 ,  H01L21/82385 ,  H01L27/0922 ,  H01L27/0924 ,  H01L29/66537 ,  H01L29/66545

Abstract: ZnxZryOz mixed oxide catalysts having improved stability for the conversion of ethanol to isobutene are described, together with methods for making such catalysts.

Abstract translation: 描述了具有改进的将乙醇转化为异丁烯的稳定性的Zn x Zn y O z混合氧化物催化剂，以及制备这种催化剂的方法。

公开(公告)号：US20150210608A1

公开(公告)日：2015-07-30

申请号：US14683272

申请日：2015-04-10

Applicant: Archer Daniels Midland Company ,  Washington State University

Inventor： Junming Sun ,  Changjun Liu ,  Yong Wang ,  Kevin Martin ,  Padmesh Venkitasubramanian

IPC: C07C1/207 ,  C07C29/147 ,  C07C5/48 ,  C07C29/60

CPC classification number: B01J23/06 ,  B01J37/04 ,  B01J37/08 ,  C07C1/2072 ,  C07C5/48 ,  C07C45/52 ,  C07C51/235 ,  C07C2521/06 ,  C07C2523/06 ,  C07C53/08 ,  C07C53/122 ,  C07C47/06 ,  C07C47/02 ,  C07C11/09 ,  C07C11/10 ,  C07C11/18

Abstract: A process is described for making renewable isobutene and renewable isoprene, comprising converting a mixed acid feed including acetic acid and propionic acid to a product mixture including isobutene and at least one or both of 2-methyl-1-butene and 2-methyl-2-butene in the presence of a catalyst, separating isobutene from the product mixture and dehydrogenating either or both of the 2-methyl-1-butene and 2-methyl-2-butene in the remainder to provide isoprene.

Abstract translation: 描述了一种制备可再生异丁烯和可再生异戊二烯的方法，包括将包含乙酸和丙酸的混合酸进料转化成产物混合物，包括异丁烯和2-甲基-1-丁烯和2-甲基-2 在催化剂存在下，将异丁烯从产物混合物中分离出来，然后使其余的2-甲基-1-丁烯和2-甲基-2-丁烯中的任一种或两者脱氢，得到异戊二烯。