公开(公告)号：US20130172457A1

公开(公告)日：2013-07-04

申请号：US13822536

申请日：2011-09-13

申请人： Harald Bauer ,  Sebastian Hoerold ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Martin Sicken

IPC分类号： C07F9/30

CPC分类号： C07F9/303 ,  C07F9/383 ,  C07F9/48 ,  C08K5/5313 ,  C08L25/06 ,  C08L77/00

摘要： The invention provides phosphorus-containing mixtures comprising a) from 50 to 100 mol % of compounds of the formula (1) in which R1 and R2 are identical or different and are C6-C9-alkyl, b) 0 to 50 mol % of compounds of the formula (1) in which R1 is H and R2 is C6-C9-alkyl, c) 0 to 50 mol % of compounds of the formula (1) in which R1 is OH and R2 is C6-C9-alkyl, d) from 0 to 50 mol % of compounds of the formula (1) in which R1 is OH and R2 is H, and e) from 0 to 50 mol % of compounds of the formula (1) in which R1 is H and R2 is H, with the sum of a), b), c), d), and e) always being 100 mol %.

摘要翻译： 本发明提供含磷混合物，其包含a）50-100摩尔％的式（1）化合物，其中R 1和R 2相同或不同，为C 6 -C 9 - 烷基，b）0至50摩尔％的化合物 式（1）中R 1为H且R 2为C 6 -C 9 - 烷基，c）0至50摩尔％的式（1）化合物，其中R 1为OH且R 2为C 6 -C 9 - 烷基，d ）0至50mol％的式（1）化合物，其中R 1为OH且R 2为H，e）0至50mol％的式（1）化合物，其中R 1为H且R 2为 H，与a），b），c），d）和e）总和为100mol％。

公开(公告)号：US20050272839A1

公开(公告)日：2005-12-08

申请号：US11143059

申请日：2005-06-02

申请人： Harald Bauer ,  Sebastian Hoerold ,  Bernd Nass ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Bernd Nass ,  Martin Sicken

IPC分类号： C09K21/12 ,  C07F9/30 ,  C08K5/00 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5377 ,  C08L21/00 ,  C08L101/00 ,  C09K21/02 ,  C09K21/04 ,  C09K21/06 ,  C09K21/08 ,  C09K21/10 ,  C09K21/14 ,  D01F1/10 ,  D01F6/90 ,  D01F6/92 ,  C08K5/34

CPC分类号： C08K5/5313 ,  C08K2201/014 ,  C08L21/00

摘要： The present invention relates to a compression-granulated flame retardant composition which comprises a phosphinic salt of the formula (I) and/or comprises a diphosphinic salt of the formula (II), and/or comprises their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, and comprises a fusible zinc phosphinate; and to a process for preparation of this compression-granulated flame retardant composition, and to the use of the composition.

摘要翻译： 本发明涉及压缩颗粒状阻燃剂组合物，其包含式（I）的次膦酸盐和/或包含式（II）的二膦酸盐和/或包含其聚合物，其中R 1 R 2和R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基 ; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，并且包含可熔融的次膦酸锌; 以及制备该压缩颗粒状阻燃剂组合物的方法以及该组合物的用途。

公开(公告)号：US20060214144A1

公开(公告)日：2006-09-28

申请号：US11388916

申请日：2006-03-24

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

IPC分类号： C09K21/00

CPC分类号： C08K5/5313 ,  C08K5/3492

摘要： The invention relates to phosphorus-containing thermally stabilized flame retardant agglomerates, comprising as component A from 6 to 99.99% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II), and/or of their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Zn, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4; as component B from 0 to 90% by weight of a synergist which comprises a nitrogen compound or which comprises a phosphorus compound, or which comprises a phosphorus-nitrogen compound; as component C from 0 to 20% by weight of compounds of the elements of the second main and transition group; and as component D from 0.01 to 20% by weight of auxiliary. The invention also relates to a process for their production, and to their use.

摘要翻译： 本发明涉及含磷热稳定的阻燃附聚物，其包含作为组分A的6至99.99重量％的由式（I）的次膦酸盐和/或由式（I）的次膦酸盐组成的聚集体和/或一次颗粒和/ 式（II）和/或它们的聚合物，其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基，和 /或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Zn，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1〜4; 作为组分B的0至90重量％的增效剂，其包含氮化合物或包含磷化合物，或包含磷 - 氮化合物; 作为组分C的0至20重量％的第二主要和过渡基团的元素的化合物; 并且作为组分D为辅助剂的0.01至20重量％。 本发明还涉及其生产方法及其用途。

公开(公告)号：US20060226404A1

公开(公告)日：2006-10-12

申请号：US11399982

申请日：2006-04-07

申请人： Harald Bauer ,  Frank Eisentraeger ,  Sebastian Hoerold ,  Werner Krause

发明人： Harald Bauer ,  Frank Eisentraeger ,  Sebastian Hoerold ,  Werner Krause

IPC分类号： C09K21/00

CPC分类号： C09K21/12 ,  C08K5/34928

摘要： The invention relates to a stabilized flame retardant comprising a) from 99 to 1% by weight of melamine polyphosphate b) from 1 to 99% by weight of additive with latent alkalinity.

摘要翻译： 本发明涉及稳定的阻燃剂，其包含a）99至1重量％的三聚氰胺多磷酸盐b）1至99重量％的具有潜在碱度的添加剂。

公开(公告)号：US20110021676A1

公开(公告)日：2011-01-27

申请号：US12919792

申请日：2009-02-25

申请人： Sebastian Hoerold ,  Ottmar Schacker ,  Harald Bauer ,  Werner Krause ,  Daniela Eisenhauer

发明人： Sebastian Hoerold ,  Ottmar Schacker ,  Harald Bauer ,  Werner Krause ,  Daniela Eisenhauer

IPC分类号： C08K5/3492 ,  C08K5/5313 ,  C09K21/12

CPC分类号： C09K21/12 ,  C08K5/0066 ,  C08K5/5313 ,  C08L77/00 ,  C08L67/02

摘要： The invention relates to a process for producing flame-retardant, non-corrosive, highly flawable polyamides and polyesters, which comprises using a flame retardant mixture made of a phosphinic salt of the formula (I), where M═Al, Mg, Ca, Ti, or Na (component A) in which R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; n is from 1 to 3, and, as component B, a metal salt of an organic acid, and/or an inorganic zinc, calcium, magnesium, potassium, sodium, aluminum, titanium, tin, antimony, bismuth, or barium compound, where the amount of component A present in the flame retardant mixture is from 70 to 99.5% by weight and the amount of component B present in the flame retardant mixture is from 0.5 to 30% by weight.

摘要翻译： 本发明涉及一种制造阻燃，非腐蚀性，高度可破坏的聚酰胺和聚酯的方法，其包括使用由式（I）的次膦酸盐制成的阻燃混合物，其中M = Al，Mg，Ca， Ti或Na（组分A），其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基和/或芳基; n为1〜3，作为成分B的有机酸金属盐和/或无机锌，钙，镁，钾，钠，铝，钛，锡，锑，铋或钡化合物， 其中存在于阻燃剂混合物中的组分A的量为70至99.5重量％，并且阻燃混合物中存在的组分B的量为0.5至30重量％。

公开(公告)号：US20060217469A1

公开(公告)日：2006-09-28

申请号：US11388329

申请日：2006-03-24

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

IPC分类号： C08K5/49

CPC分类号： C08K5/5313 ,  C08K3/22 ,  C08K5/0066

摘要： The invention relates to the use of stabilizers in phosphorus-containing thermally stabilized flame retardant agglomerates.

摘要翻译： 本发明涉及在含磷热稳定化阻燃剂附聚物中使用稳定剂。

公开(公告)号：US07838580B2

公开(公告)日：2010-11-23

申请号：US11999986

申请日：2007-12-07

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

IPC分类号： C08K5/5313

CPC分类号： C09K21/12 ,  C07F9/301 ,  C08K5/5313

摘要： The invention relates to salts of alkyl esters of carboxyethyl(alkyl)phosphinic acid, where the salts have the formula (I) R1—P(═O)(OX)—CH2—CH2—CO2R2 in which R1 and R2 are identical or different and, independently of one another, are C1-C20-alkyl, C2-C20-alkenyl, C1-C20-alkynyl, and/or C6-C20-aralkyl, and X is an alkali metal, an element of the second main and transition group, an element of the third main and transition group, an element of the fourth main and transition group, an element of the fifth main and transition group, an element of the sixth main group, an element of the seventh transition group, or an element of the eighth transition group, and also to processes for their preparation, and to their use.

摘要翻译： 本发明涉及羧乙基（烷基）次膦酸的烷基酯的盐，其中盐具有式（I）R 1 -P（= O）（OX）-CH 2 -CH 2 -CO 2 R 2，其中R 1和R 2相同或不同 并且彼此独立地是C 1 -C 20烷基，C 2 -C 20 - 烯基，C 1 -C 20 - 炔基和/或C 6 -C 20 - 芳烷基，X是碱金属，第二主要和转变的元素 集团，第三主体和过渡组的要素，第四主体和过渡组的要素，第五主体和过渡组的元素，第六主要组的元素，第七过渡组的元素，或第 第八个过渡组的要素，以及其准备过程及其使用。

公开(公告)号：US20080188598A1

公开(公告)日：2008-08-07

申请号：US11999986

申请日：2007-12-07

申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause

IPC分类号： C08K5/51 ,  C07F9/30 ,  C07F9/32

CPC分类号： C09K21/12 ,  C07F9/301 ,  C08K5/5313

摘要： The invention relates to salts of alkyl esters of carboxyethyl(alkyl)phosphinic acid, where the salts have the formula (I) R1—P(═O)(OX)—CH2—CH2—CO2R2 in which R1 and R2 are identical or different and, independently of one another, are C1-C20-alkyl, C2-C20-alkenyl, C1-C20-alkynyl, and/or C6-C20-aralkyl, and X is an alkali metal, an element of the second main and transition group, an element of the third main and transition group, an element of the fourth main and transition group, an element of the fifth main and transition group, an element of the sixth main group, an element of the seventh transition group, or an element of the eighth transition group, and also to processes for their preparation, and to their use.

摘要翻译： 本发明涉及羧乙基（烷基）次膦酸的烷基酯的盐，其中盐具有式（I）<？in-line-formula description =“In-line formula”end =“lead”？> R SUP > - > - （ - O）（OX）-CH 2 -CH 2 - - - - - 2 <？in-line-formula description =“在线公式”end =“tail”？>其中R 1和R 2是相同的，或 不同且彼此独立地为C 1 -C 20 - 烷基，C 2 -C 20烷基，C 1 -C 20烷基，C 2 -C 20 - - 烯基，C 1 -C 20炔基和/或C 6 -C 20 - 芳烷基，C 1 -C 20 - X是碱金属，第二主转移体和过渡组的元素，第三主转移基团和过渡组的元素，第四主转移基团和过渡组的元素，第五主转移基团和过渡组的元素， 第六大集团，第七过渡集团的要素或第八过渡集团的要素，以及其准备过程，以及 他们的使用。

公开(公告)号：US20090137707A1

公开(公告)日：2009-05-28

申请号：US12313523

申请日：2008-11-21

申请人： Harald Bauer ,  Werner Krause ,  Wolfgang Wanzke

发明人： Harald Bauer ,  Werner Krause ,  Wolfgang Wanzke

IPC分类号： C09K21/12 ,  C07F19/00

CPC分类号： C07F9/301 ,  C07C63/28 ,  C08K5/0066 ,  C08K5/5313 ,  C08L21/00

摘要： The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate−)x(carboxylic acid anionz−1/z)y] where n=from 1 to 4 x=from 0.01 to n−0.01 y=n−x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.

摘要翻译： 本发明涉及二有机基次膦酸和羧酸的混合物，其结构式为：α-in-line-formula description =“In-line Formulas”end =“lead”→[cationn +（phosphinate-）x（carboxylic acid anionz-1 / z）y] <？in-line-formula description =“In-line Formulas”end =“tail”？>其中n = 1至4 x =从0.01到n-0.01 y = nx z =从1到4 其中“阳离子”是指第二主和/或转移基团的元素，第三主和/或过渡基团的元素，第四主和/或过渡基团的元素，第五主元素和/或过渡基团的元素和/ 或过渡组，第六过渡组的元素，第七过渡组的元素和/或第八过渡组的元素，“次膦酸酯”是指下式的二有机基次膦酸的阴离子，其中R 1和R 2相同或 不同且彼此独立地为H，C 1 -C 6 - 烷基，直链或支链和/或芳基和/或羟烷基，“羧酸阴离子”是指C 1 -C 18羧酸a 国王 本发明还涉及其生产方法及其用途。

公开(公告)号：US08221658B2

公开(公告)日：2012-07-17

申请号：US12313523

申请日：2008-11-21

申请人： Harald Bauer ,  Werner Krause ,  Wolfgang Wanzke

发明人： Harald Bauer ,  Werner Krause ,  Wolfgang Wanzke

IPC分类号： C09K21/00 ,  C09K21/04 ,  C07F9/28

CPC分类号： C07F9/301 ,  C07C63/28 ,  C08K5/0066 ,  C08K5/5313 ,  C08L21/00

摘要： The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate−)x(carboxylic acid anionz−1/z)y] where n=from 1 to 4 x=from 0.01 to n−0.01 y=n−x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.

摘要翻译： 本发明涉及二有机基次膦酸和具有式[阳离子+（次膦酸盐））x（羧酸阴离子z-1 / z）y]的羧酸的混合物，其中n = 1至4×= 0.01至n-0.01y = n -xz =从1到4，其中“阳离子”是指第二主和/或转移基团的元素，第三主和/或过渡基团的元素，第四主和/或过渡基团的元素， 第五主转移组和/或过渡组的元素，第六过渡组的元素，第七过渡组的元素和/或第八过渡组的元素，“次膦酸酯”是指下式的二有机基次膦酸的阴离子 其中R 1和R 2相同或不同，并且彼此独立地为H，C 1 -C 6烷基，直链或支链和/或芳基和/或羟烷基，“羧酸阴离子”是指C 1 -C 18羧酸 阴离子 本发明还涉及其生产方法及其用途。