公开(公告)号：US09505904B2

公开(公告)日：2016-11-29

申请号：US14362884

申请日：2012-11-28

申请人： Harald Bauer ,  Sebastian Hoerold ,  Martin Sicken

发明人： Harald Bauer ,  Sebastian Hoerold ,  Martin Sicken

IPC分类号： C08K3/32 ,  C01B25/163 ,  C01B25/165 ,  C08K7/14

CPC分类号： C08K3/32 ,  C01B25/163 ,  C01B25/165 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/82 ,  C08K7/14 ,  C08K2003/329

摘要： The invention relates to mixtures of aluminum hydrogenphosphites of the formula (I) Al2.00(HPO3)v(H2PO3)yx(H2O)z  (I) and aluminum salts comprising 91 to 99.9% aluminum hydrogenphosphites of the formula (I) 0.1 to 9% aluminum salts and 0 to 50% water (of crystallization), where v in formula (I) is 2 to 2.99, y is 2 to 0.01 and z is 0 to 4, to processes for preparation thereof and to the use thereof.

公开(公告)号：US09279085B2

公开(公告)日：2016-03-08

申请号：US13140555

申请日：2009-10-06

申请人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

IPC分类号： C07F9/02 ,  C07F9/22 ,  C07F9/28 ,  C08K5/53 ,  C09K21/12 ,  C07F9/30 ,  C07F9/32 ,  C08K5/5313

CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/3211 ,  C08K5/5313

摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.

摘要翻译： 本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或 酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数 至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。 还公开了所述二烷基膦酸，酯和盐的用途。

公开(公告)号：US08987489B2

公开(公告)日：2015-03-24

申请号：US13132196

申请日：2009-10-06

申请人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

IPC分类号： C07F9/32 ,  C07F9/30 ,  C07F9/48 ,  C08K5/5313 ,  C09K21/12 ,  C08L21/00

CPC分类号： C07F9/30 ,  C07F9/301 ,  C07F9/32 ,  C07F9/4816 ,  C07F9/4866 ,  C08K5/5313 ,  C08L21/00 ,  C09K21/12

摘要： A method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or the ester (II) thereof, b) reacting the alkylphosphonous acid so obtained, the salt or the ester (II) thereof with a vinyl ether of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting this derivative (VI) with an oxidant or in the presence of a catalyst C to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein the catalysts A and C are transition metals and/or transition metal compounds, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound.

摘要翻译： 使用乙烯基醚制备单羧基官能化的二烷基次膦酸，酯和盐的方法。 该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基亚磷酸，其盐或其酯（II），b）使 所得的烷基亚磷酸，其盐或其酯（II）与式（V）的乙烯基醚在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（VI），和c）使该衍生物 VI）与氧化剂或催化剂C的存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III），其中催化剂A和C为过渡金属和/或过渡金属化合物，催化剂B为 过氧化物形成化合物和/或过氧化合物和/或偶氮化合物。

公开(公告)号：US20150005421A1

公开(公告)日：2015-01-01

申请号：US14364851

申请日：2012-12-08

申请人： Fabian Schneider ,  Frank Osterod ,  Harald Bauer ,  Martin Sicken

发明人： Fabian Schneider ,  Frank Osterod ,  Harald Bauer ,  Martin Sicken

IPC分类号： C09K21/12 ,  C08K5/5313

CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/305 ,  C08K5/5313 ,  C08K2201/014

摘要： The invention relates to mixtures of at least one diphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each independently H, C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, R5 is C1-C18-alkylene, C2-C18-alkenylene, C6-C18-arylene, C7-C18-alkylarylene with at least one dialkylphosphinic acid of the formula (II) in which R3, R4 are the same or different and are each independently C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl. The invention also relates to a process for preparing these mixtures and to the use thereof.

摘要翻译： 本发明涉及式（I）的至少一种二次膦酸的混合物，其中R 1，R 2相同或不同，各自独立地为H，C 1 -C 18烷基，C 2 -C 18 - 烯基，C 6 -C 18 - 芳基 ，C 7 -C 18烷基芳基，R 5是C 1 -C 18亚烷基，C 2 -C 18亚烯基，C 6 -C 18亚芳基，具有式（II）的至少一种二烷基次膦酸的C 7 -C 18烷基亚芳基，其中R 3，R 4是 C 1 -C 18 - 烷基，C 2 -C 18 - 烯基，C 6 -C 18 - 芳基和/或C 7 -C 18 - 烷基芳基各自相同或不同。 本发明还涉及制备这些混合物的方法及其用途。

公开(公告)号：US08772519B2

公开(公告)日：2014-07-08

申请号：US13127110

申请日：2009-10-06

申请人： Michael Hill ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Werner Krause ,  Martin Sicken

IPC分类号： C07F9/30 ,  C07F9/32 ,  C07F5/06

CPC分类号： C09K21/12 ,  C07F9/302 ,  C07F9/3217 ,  C08K5/5313

摘要： The invention relates to a process for preparing mono-allyl-functionalized dialkylphosphinic acids, esters and salts with allylic compounds, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, or salt or ester thereof (II), b) the alkylphosphonous acid, or salt or ester thereof (II) thus formed is reacted with allylic compounds of the formula (V) in the presence of a catalyst B and of a base to give a mono-allyl-functionalized dialkylphosphinic acid derivative (III), where R1, R2, R3, R4, R5, R6, R7, R8, R9 are the same or different and are each independently, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, and X is H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base, and the catalysts A and B are transition metals and/or transition metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition metal compound and at least one ligand.

摘要翻译： 本发明涉及用烯丙基化合物制备单烯丙基官能化二烷基次膦酸，酯和盐的方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（Ⅳ）反应， 得到烷基亚磷酸或其盐或酯（II），b）将如此形成的烷基亚膦酸或其盐或酯（II）与式（Ⅴ）的烯丙基化合物在催化剂B的存在下反应，和 得到单烯丙基官能化的二烷基次膦酸衍生物（III）的碱，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9相同或不同，并且各自独立地为H， C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X是H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18 - 烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱， 催化剂A和B是过渡金属和/或过渡金属 nds和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。

公开(公告)号：US08735476B2

公开(公告)日：2014-05-27

申请号：US13132153

申请日：2009-10-06

申请人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Mathias Dietz ,  Werner Krause ,  Martin Sicken

IPC分类号： C08K5/5313

CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/4816 ,  C07F9/4866 ,  C08K5/5313

摘要： The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkylphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III).

摘要翻译： 本发明涉及使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸，酯和盐的方法。 该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基次膦酸，其盐或其酯（II），b）使 如此获得的烷基次膦酸，其盐或其酯（II）与式（V）的羧酸的乙烯基酯在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（Ⅵ）和c） 使在催化剂C存在下得到的单官能化二烷基次膦酸衍生物（Ⅵ）反应，得到单官能化二烷基次膦酸衍生物（Ⅶ），和d）使单官能化二烷基次膦酸衍生物（Ⅶ）反应; 与氧化剂或在催化剂D存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III）。

公开(公告)号：US08592505B2

公开(公告)日：2013-11-26

申请号：US13140563

申请日：2009-10-06

申请人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

IPC分类号： C08K5/00 ,  C08K5/53 ,  C07F5/02 ,  C07F9/28

CPC分类号： C09K21/12 ,  A01N57/20 ,  A01N57/22 ,  B27K3/15 ,  B27K2240/30 ,  C07F9/4006 ,  C07F9/4093 ,  C07F9/505 ,  C07F9/5072 ,  C08K5/5393 ,  C08L77/00 ,  C08L97/02 ,  C09D5/086 ,  C09D5/185

摘要： Addition compounds of a) alkylphosphonous acid derivatives of the formula A-P(═O)(OX)—H (I) and b) diester-forming olefins of formula (II) Methods for the production of the addition compounds and the use thereof are also disclosed.

摘要翻译： a）a）式AP（= O）（OX）-H（I）的烷基亚膦酸衍生物和b）式（II）的二酯形成烯烃的加成化合物加成化合物的制备方法及其用途也 披露

公开(公告)号：US20130190432A1

公开(公告)日：2013-07-25

申请号：US13878145

申请日：2011-09-30

申请人： Werner Krause ,  Harald Bauer ,  Martin Sicken ,  Sebastian Hoerold ,  Wolfgang Wanzke ,  Elke Schlosser

发明人： Werner Krause ,  Harald Bauer ,  Martin Sicken ,  Sebastian Hoerold ,  Wolfgang Wanzke ,  Elke Schlosser

IPC分类号： C08K5/5313 ,  C08K5/3492 ,  C08K5/10 ,  C08K3/22 ,  C08K5/5317 ,  C08K5/56 ,  C08K5/52 ,  C08K3/38

CPC分类号： C08K5/5313 ,  C08K3/22 ,  C08K3/38 ,  C08K5/0008 ,  C08K5/10 ,  C08K5/34922 ,  C08K5/34924 ,  C08K5/52 ,  C08K5/5317 ,  C08K5/56

摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.

摘要翻译： 一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物 其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％ 含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物 氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。

公开(公告)号：US20110213078A1

公开(公告)日：2011-09-01

申请号：US13127072

申请日：2009-10-06

申请人： Michael Hill ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Werner Krause ,  Martin Sicken

IPC分类号： C08L67/02 ,  C07F9/30 ,  C07F9/32 ,  C07F5/06 ,  C07F7/28 ,  C08G63/183 ,  C08L77/06 ,  C08G69/26

CPC分类号： C07F9/3211 ,  C07F9/301 ,  C07F9/3264 ,  C07F9/4816 ,  C07F9/4866 ,  C08K5/5313 ,  C09K21/12

摘要： The invention relates to a method for producing mono-aminofunctionalized dialkylphosphinic acids and esters and salts thereof by means of acrylnitriles, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with an acrylnitrile of formula (V) to yield a mono-functionalized dialkylphosphinic acid derivative (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VI) is reacted to yield a mono-aminofunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst C or a reduction agent, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X stands for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and Y stands for a mineral acid, a carboxylic acid, a Lewis acid or an organic acid, n=an integer or fractional number of 0 to 4 and the catalysts A and C are formed by transition metals, transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides, peroxo compounds, azo compounds, alkali metals, alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.

摘要翻译： 本发明涉及一种通过丙烯腈生产单氨基官能化二烷基次膦酸及其酯及其盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸盐或盐 酯（II），b）将由此得到的烷基膦酸，其盐或酯（II）与式（V）的丙烯腈反应，得到单官能化二烷基次膦酸衍生物（Ⅵ） 在催化剂B存在下，和c）将由此得到的单官能化二烷基次膦酸衍生物（Ⅵ）反应，得到单氨基官能化二烷基次膦酸衍生物（Ⅲ），其中催化剂C或还原剂存在下，其中 对于H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基，R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同，彼此独立 烷基芳基，X代表H，C1-C18烷基，C6-C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K 和/或质子化的氮碱，Y表示无机酸，羧酸，路易斯酸或有机酸，n = 0至4的整数或分数，催化剂A和C由过渡金属形成 由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属化合物和/或催化剂体系和催化剂B通过形成过氧化物，过氧化合物，偶氮化合物，碱金属，碱土金属， 碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属盐。

公开(公告)号：US20110213061A1

公开(公告)日：2011-09-01

申请号：US13125359

申请日：2009-10-06

申请人： Michael Hill ,  Werner Krause ,  Martin Sicken

发明人： Michael Hill ,  Werner Krause ,  Martin Sicken

IPC分类号： C08K5/5313 ,  C07F9/30 ,  C08L67/02 ,  C08L77/06

CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/3211 ,  C08K5/5313

摘要： The invention relates to a method for producing mono-aminofunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with acetylenic compounds of formula (V) to yield a mono-functionalized dialkylphosphinic acid derivative (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VI) is reacted with a hydrogen cyanide source to yield a mono-functionalized dialkylphosphinic acid derivative (VII) in the presence of a catalyst C, and d) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VII); is reacted to yield a mono-aminofunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst D or a reduction agent, wherein R1, R2, R3, R4, R5, R6 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X stands for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and Y stands for a mineral acid, a carboxylic acid, a Lewis acid or an organic acid, n=0 to 4 and the catalysts A, B, C and D are formed by transition metals, transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand.

摘要翻译： 本发明涉及一种用于制备单氨基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸盐或酯（Ⅱ） 在催化剂A存在下，将由此得到的烷基膦酸，其盐或酯（II）与式（Ⅴ）的炔属化合物反应，得到单官能化二烷基次膦酸衍生物（Ⅵ） 催化剂B和c）由此获得的单官能化二烷基次膦酸衍生物（VI）与氰化氢源反应，在催化剂C存在下得到单官能化二烷基次膦酸衍生物（Ⅶ），和d） 得到单官能化二烷基次膦酸衍生物（VII）; 在催化剂D或还原剂的存在下反应得到单氨基官能化二烷基次膦酸衍生物（III），其中R1，R2，R3，R4，R5，R6相同或不同并且彼此独立， 对于H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X代表H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基， C18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱，Y 代表无机酸，羧酸，路易斯酸或有机酸，n = 0〜4，催化剂A，B，C和D由过渡金属，过渡金属化合物和/或催化剂体系 过渡金属和/或过渡金属化合物和至少一种配体。