摘要:
The invention provides an OLED device comprising a cathode, an anode, and having therebetween a layer containing an acridone compound including a diarylamine or carbazole substituent where the nitrogen of the acridone and the nitrogen of the diarylamine or carbazole are connected by an aromatic hydrocarbon linking group. OLED devices of the invention exhibit improved efficiency and drive voltage.
摘要:
An OLED device including a cathode, an anode, and having therebetween a phosphorescent light-emitting layer that contains a light-emitting organometallic complex including a precious metal, a first ligand including an imidazole group and a second nitrogen heterocycle group, and at least one second different ligand.
摘要:
A process for forming a facial tris-cyclometallated iridium or rhodium complex isomer comprises heating an original solid composition containing meridional isomer of the metal complex at a temperature and for a time sufficient to form a product containing the facial isomer in an increased ratio to meridional isomer compared to the original composition.
摘要:
An OLED device comprises an anode, a cathode and therebetween a light emitting layer containing a compound represented by Formula I below: wherein: each A is independently selected from N and P; each E is independently selected from N, P, and As; each Z is a radical independently selected from each R is an independently selected substituent; and each R′ is independently selected from H and a substituent; provided that two substituent groups can join to form a ring.
摘要:
A microcavity OLED device including a substrate; a metallic bottom-electrode layer disposed over the substrate; a metallic top-electrode layer spaced from the metallic bottom-electrode layer; and an organic EL medium structure having a defined thickness, and including a light-emitting layer comprising a host material and at least one dopant disposed between the top-electrode layer and the bottom-electrode layer; wherein one of the metallic electrode layers is light transmissive and the other one is essentially opaque and reflective; wherein the material for reflective metallic electrode layer includes Ag, Au, Al, or alloys thereof, and the material for the light transmissive metallic electrode layer includes Ag, Au, or alloys thereof. The at least one dopant is selected to generate one of red, green, or blue light in the light-emitting layer. The defined thickness of the EL medium structure is selected so that the microcavity OLED device is tuned for emission of one of red, green, or blue light through the light transmissive electrode layer.
摘要:
The invention provides a radiation-sensitive silver halide emulsion comprisingsilver halide grains including tabular grains(a) having {111} major faces(b) containing greater than 70 mole percent bromide, based on silver,(c) accounting for greater than 90 percent of total grain projected area,(d) exhibiting an average equivalent circular diameter of at least 0.7 .mu.m,(e) exhibiting an average thickness of less than 0.07 .mu.m, and(f) having latent image forming chemical sensitization sites on the surfaces of the tabular rains, anda spectral sensitizing dye adsorbed to the surfaces of the tabular grains,wherein the surface chemical sensitization sites include at least one silver salt epitaxially located on said tabular rains and wherein said grains further comprise a mercapto compound represented by Formula III ##STR1## where R.sup.1 is an aliphatic or aromatic radical containing up to 20 carbon atoms.
摘要:
An improved spectrally sensitized ultrathin tabular grain emulsion is disclosed in which tabular grains (a) having {111} major faces, (b) containing greater than 70 mole percent bromide and at least 0.25 mole percent iodide, based on silver, (c) accounting for greater than 90 percent of total grain projected area, (d) exhibiting an average equivalent circular diameter of at least 0.7 .mu.m, (e) exhibiting an average thickness of less than 0.07 .mu.m, and (f) having latent image forming chemical sensitization sites on the surfaces of the tabular grains, are spectrally sensitized. The speed-granularity relationship of the emulsion is improved by employing in forming the surface chemical sensitization sites at least one silver salt epitaxially located on tabular grain surface sites that contain increased iodide concentrations.A photographic element is disclosed comprised of a support, a first silver halide emulsion layer coated on the support and sensitized to produce a photographic record when exposed to specular light within the minus blue visible wavelength region of from 500 to 700 nm, a second silver halide emulsion layer capable of producing a second photographic record coated over the first silver halide emulsion layer to receive specular minus blue light intended for the exposure of the first silver halide emulsion layer, the second silver halide emulsion layer being capable of acting as a transmission medium for the delivery of at least a portion of the minus blue light intended for the exposure of the first silver halide emulsion layer in the form of specular light, wherein the second silver halide emulsion layer is comprised of the improved spectrally sensitized ultrathin tabular grain emulsion of the invention.The ultrathin tabular grain emulsions with silver salt epitaxy chemical sensitization have been observed to produce larger than expected speed increases, to produce higher than expected contrasts, to be unexpectedly specularly transmissive and therefore compatible with forming sharp photographic images in underlying emulsion layers, to exhibit a higher percentage of total light absorption in the wavelength region of maximum absorption by the spectral sensitizing dye or dyes employed, and to exhibit a surprising tolerance of inadvertent manufacturing variances.
摘要:
This invention provides gold(I) complexes comprising sulfur- and selenium-substituted macrocyclic polyether ligands, photographic elements containing the compounds, and emulsions containing the compounds. The compounds include monomers and dimers having the following formulas, respectively:[AuL].sup.+ X.sup.- or [AuL].sub.2.sup.2+ 2X.sup.-wherein X.sup.- is any suitable anion such as tetrafluoroborate, nitrate, etc., and wherein L is a macrocyclic ligand containing at least two thioether and/or selenoether linkages and comprising from about 12 to about 30 members in the ring. The general structural formula for the macrocyclic compounds L may be represented as follows: ##STR1## wherein Q.sub.1 and Q.sub.2 are each independently sulfur or selenium, and R.sub.1 and R.sub.2 are alkylene groups, the chain of which comprises from about 5 to 14 members that may include heteroatoms such as oxygen, sulfur, selenium, nitrogen, and that may include functional groups such as carboxylic ester or carboxylic amide linkages and the like. The alkylene group may be further substituted with alkyl groups or other functional groups such as carboxylic acids or esters, alcohols, and the like.
摘要:
An organic light-emitting device (OLED) including an anode; a cathode; a blue light-emitting layer disposed between the anode and the cathode and includes at least one blue host and at least one fluorescent blue dopant; a first light-emitting layer disposed between the anode and the blue light-emitting layer, including a first phosphorescent dopant and a host; and a second light-emitting layer disposed between the blue light-emitting layer and the cathode, including a second phosphorescent dopant and a host.
摘要:
A process for forming an organometallic cyclometallated Group viiib metal complex comprises reacting a Group viiib metal compound with a heterocyclic compound capable of forming an organometallic cyclometallated complex in the presence of a solvent comprising an aromatic oxygen containing compound.