公开(公告)号：US3816410A

公开(公告)日：1974-06-11

申请号：US20619971

申请日：1971-12-08

Applicant: TEXACO INC

Inventor： DURANLEAU R ,  LOVE R

IPC: C07C205/51 ,  C07D201/02 ,  C07D201/10 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07C201/12 ,  C07D201/10 ,  Y02P20/582 ,  C07C205/51

Abstract: A METHOD FOR PREPARAING LACTAMS BY THE STEPS OF (1) CLEAVING AND ESTERIFYING A CYCLIC ALPHA-NITROKETONE WITH AN ALCOHOL TO FORM AN ALKYL OMEGA-NITROESTER AND (2) CATALYST HYDROGENATING AND CYCLIZING THE NITROESTER TO A LACTAM.

公开(公告)号：US3705152A

公开(公告)日：1972-12-05

申请号：US3705152D

申请日：1970-07-20

Applicant: BP CHEM INT LTD

Inventor： HALL ANTONY HAROLD PATRICK ,  DANCER STUART NEIL

IPC: C07D201/02 ,  C07D41/00 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07C255/00

Abstract: THIS INVENTION RELATES TO A PROCESS FOR PRODUCING DERIVATIVES OF 1,12-DODECANEDIOIC ACID E.G. 11-CYANOUNDECANOIC ACID BY SPRAYING DROPLETS OF 1,1''-PEROXDICYCLOHEXYLAMINE INTO A REACTOR CONTAINING AN INERT GASS MAINTAINED AT AN ELEVATED TEMPERATURE AND AT A PRESSURE OF AT LEAST 300 MM. HG.

公开(公告)号：US3676431A

公开(公告)日：1972-07-11

申请号：US3676431D

申请日：1968-05-21

Applicant: BP CHEM INT LTD

Inventor： CAPP CLIFFORD WILLIAM ,  DENBIGH KEITH WARWICK

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: In the production of caprolactam by reaction of 1,1''peroxydicyclohexylamine with alkali metal alkoxides, the reaction is carried out in a reaction medium which is a mixture of methanol and dimethylsulphoxide.

Abstract translation: 在通过1,1'-过氧二环己基胺与碱金属醇盐的反应生产己内酰胺时，反应在作为甲醇和二甲基亚砜的混合物的反应介质中进行。

公开(公告)号：US3676430A

公开(公告)日：1972-07-11

申请号：US3676430D

申请日：1968-05-08

Applicant: BP CHEM INT LTD

Inventor： CAPP CLIFFORD WILLIAM ,  HARRIS BRIAN WALTON ,  HAWKINS EDWIN GEORGE EDWARD

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: Caprolactam is made by reacting 1,1''-peroxydicyclohexylamine with alkali metal methoxide dissolved in methanol at a concentration of at least 4 gram moles/liter.

Abstract translation: 己内酰胺通过使1,1'-过氧二环己基胺与溶解在甲醇中的碱金属甲醇盐以至少4克摩尔/升的浓度反应制得。

公开(公告)号：US3336299A

公开(公告)日：1967-08-15

申请号：US47269165

申请日：1965-07-16

Applicant: UNION OIL CO

Inventor： FENTON DONALD M

IPC: C07D201/02

CPC classification number: C07D201/02

公开(公告)号：US3326899A

公开(公告)日：1967-06-20

申请号：US3326899D

CPC classification number: C07D201/02

公开(公告)号：US2763644A

公开(公告)日：1956-09-18

申请号：US50173555

申请日：1955-04-15

Applicant: DU PONT

Inventor： GUY DONARUMA LORRAINE

IPC: C07D201/02

CPC classification number: C07D201/02

公开(公告)号：US20190144385A1

公开(公告)日：2019-05-16

申请号：US16098138

申请日：2017-04-26

Applicant: Bayer CropScience Aktiengesellschaft

Inventor： Taraneh FARIDA ,  Martin LITTMANN ,  Rafael WARSITZ ,  Michael ESSER ,  Albert SCHNATTERER

IPC: C07D207/38 ,  C07D201/08

CPC classification number: C07D207/38 ,  C07D201/02 ,  C07D201/08

Abstract: The present invention relates to novel methods for preparing cis-alkoxy-substituted spirocyclic 1-H-pyrrolidine-2,4-dione derivatives and also to novel intermediates and starting compounds, which are passed through or used in the method according to the invention.

公开(公告)号：US09586898B2

公开(公告)日：2017-03-07

申请号：US13819951

申请日：2011-08-16

Applicant: Jihad Mohammed Dakka ,  Francisco Manuel Benitez ,  Bryan Amrutlal Patel ,  Edmund John Mozeleski

Inventor： Jihad Mohammed Dakka ,  Francisco Manuel Benitez ,  Bryan Amrutlal Patel ,  Edmund John Mozeleski

IPC: C07C409/14 ,  C07C2/74 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C45/32 ,  C07C51/00 ,  C07C249/04 ,  C07D201/02 ,  C08G69/00

CPC classification number: C07C409/14 ,  C07C2/74 ,  C07C37/08 ,  C07C45/32 ,  C07C45/53 ,  C07C51/00 ,  C07C249/04 ,  C07C407/00 ,  C07C2601/14 ,  C07D201/02 ,  C08G69/00 ,  Y02P20/52 ,  C07C13/28 ,  C07C49/403 ,  C07C39/04

Abstract: In a process for oxidizing a feed comprising cyclohexylbenzene, the feed is contacted with oxygen and an oxidation catalyst in a plurality of reaction zones connected in series, the contacting being conducted under conditions being effective to oxidize part of the cyclohexylbenzene in the feed to cyclohexylbenzene hydroperoxide in each reaction zone. At least one of the plurality of reaction zones has a reaction condition that is different from another of the plurality of reaction zones. The different reaction conditions may include one or more of (a) a progressively decreasing temperature and (b) a progressively increasing oxidation catalyst concentration as the feed flows from one reaction zone to subsequent reaction zones in the series.

Abstract translation: 在用于氧化包含环己基苯的进料的方法中，将进料与串联连接的多个反应区中的氧和氧化催化剂接触，在有效地将进料中的环己基苯的一部分氧化成环己基苯氢过氧化物的条件下进行 在每个反应区。 多个反应区中的至少一个具有与多个反应区中的另一个不同的反应条件。 不同的反应条件可以包括（a）逐渐降低的温度和（b）随着进料从一个反应区流向该系列中的后续反应区的逐渐增加的氧化催化剂浓度中的一个或多个。

公开(公告)号：US20100145003A1

公开(公告)日：2010-06-10

申请号：US12527848

申请日：2008-02-20

Applicant: John W. Frost

Inventor： John W. Frost

IPC: C07D201/02 ,  C07D211/30 ,  C07D223/10 ,  C08G69/14

CPC classification number: C07D201/00 ,  C07D201/02 ,  C07D201/08 ,  Y02P20/52

Abstract: Catalytic processes for preparing caprolactam, pipecolinic acid, and their derivatives, from lysine or alpha-amino-epsilon-caprolactam starting materials, and products produced thereby. A process for preparing caprolactam or a derivative thereof, the process comprising contacting a reactant comprising lysine or alpha aminocaprolactam with a catalyst and a gas comprising hydrogen gas, in the presence of a solvent. The catalyst may be provided on a support material, such as a transition metal.

Abstract translation: 从赖氨酸或α-氨基-ε-己内酰胺起始原料制备己内酰胺，哌可啶酸及其衍生物的催化方法，以及由此产生的产物。 一种制备己内酰胺或其衍生物的方法，该方法包括在溶剂存在下使包含赖氨酸或α-氨基己内酰胺的反应物与催化剂和包含氢气的气体接触。 催化剂可以设置在载体材料如过渡金属上。