摘要:
The invention relates to a process for the preparation of the dyestuff Direct Yellow 11 directly in the form of stable concentrated solutions, in which caustic soda in aqueous solution is reacted, at a temperature from 40.degree. to 90.degree. C., with a solution containing 4-nitro-toluene-2-sulfonic acid, one or more alkanolamines, one or more alcohols containing an etheroxide function or a second alcohol function, then the caustic soda is neutralized by addition of sulfuric acid and the sodium sulfate thus formed is separated by filtration. The solutions obtained by the process according to the invention are particularly suitable for dyeing cellulosic materials and leather.
摘要:
Salts of N-acylaminohydroxynaphthalenesulphonic acids which, in the form of the free acid, correspond to the formula ##STR1## wherein R denotes hydrogen or alkyl,X denotes the radical of a monovalent or divalent acyl group,m denotes 1 or 2 andn denotes 1 or 2,and wherein at least one of the sulphonic acid groups contains, as a cation, a cation of the formula ##STR2## wherein R.sub.1 and R.sub.2 independently of one another denote C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl or R.sub.3, orR.sub.1 and R.sub.2, together with the nitrogen atom, denote piperidinyl, morpholinyl or pyrrolinyl,R.sub.3 denotes the group ##STR3## R.sub.4 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl or the group ##STR4## R.sub.5 and R.sub.6 denote hydrogen, methyl or ethyl and p represents an integer between 1 and 10,a process for their preparation and their use as coupling components for the preparation of azo dyestuffs or concentrated solutions thereof.
摘要:
This invention relates to a process for the preparation of a very pure copper phthalocyanine pigment of the .alpha.-modification which comprises dissolving crude copper phthalocyanine in a 80 to 86% sulfuric acid isolating the copper phthalocyanine sulfate formed, hydrolizing the sulfate and grinding the copper phthalocyanine thus obtained in an aqueous-organic medium.
摘要:
Dyestuff solutions ofCuPc-(3)(SO.sub.3.sup..crclbar. M.sup..sym.).sub.min whichCuPc denotes copper phthalocyanine,m denotes a number from 1.8 to 2.5 andM.sup..sym. denotes a mixture of A.sub.n.sup..sym. and an amine of the formula ##STR1## in which n represents a number 0.8 to 1.5,A.sub.n.sup..sym. represents an alkali metal ion or NH.sub.4 ion,R.sub.1 and R.sub.2 represent hydrogen, C.sub.1 -C.sub.4 -alkyl or (CH.sub.2 --CH.sub.2 --O).sub.p -H andR.sub.3 represents --(CH.sub.2 --CH.sub.2 --O).sub.p -H, whereinp denotes an integer from 1 to 6,are suitable for dyeing paper in turquoise-colored shades.
摘要:
Phosphorus acid substituted chromophores are reactively linked to cellulose fibers by means of a phosphorus ester link produced in the presence of a carbodiimide such as cyanamide.
摘要:
Stable, concentrated solutions of anionic dyestuffs are prepared by reacting the alkali metal or ammonium salts of anionic dyestuffs and brighteners, which are usually obtained from the industrial preparation process, in water-soluble organic solvents, optionally in the presence of water, with salts of nitrogen bases which impart hydrophilic properties, in accordance with the reaction equationMe.sub.n F + nB.multidot.A.fwdarw.Bn.multidot.F + nMeAin whichMe denotes an alkali metal or ammonium ion,B denotes a protonated or quaternized nitrogen base,A denotes the anion of an acid,N denotes an integer from 1 to 4 andF denotes the anion of a dyestuff acid,And separating the resulting solutions from the salt n.multidot.MeA, which is insoluble in the reaction mass.
摘要:
Dye solutions having excellent Kusters dye bath stability comprising, by weight,I. 10% to 20% of a dye of the formula ##STR1## wherein R is H or Cl, and X is a mixture of di- and tri-C.sub.1-4 alkanolammonium,Ii. 15% to 30% of n-butanol,Iii. 10% to 20% of ethyleneglycol,Iv. 10% to 20% of nonionic polyethylene oxide-polypropylene oxide copolymer surfactant,V. 5% to 10% of nonionic polyethoxylated aliphatic amine surfactant, andVi. 0 to 50% water.
摘要:
Concentrated, liquid preparations of metal-free direct azo dyes which contain in each instance 1 part by weight of dye, 1 to 8 parts by weight of water, and 0.5 to 5 or preferably 0.5 to 2 parts by weight of an amide are useful for dyeing paper in the stock and for dyeing paper sheet.
摘要:
Solution of a mixture of isomers of naphthylazophenylazonaphthyl dye containing two sulfonate substituents, the solution comprising said dye, water, triethanolamine, lithium base and urea. The dyes have good solubility and substantivity and are useful among other things, for dyeing cellulosic substrates.