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    Bleach Catalyst Compounds, Method For The Production Thereof And Use Thereof
    31.
    发明申请
    Bleach Catalyst Compounds, Method For The Production Thereof And Use Thereof 有权
    漂白催化剂化合物，其生产方法和用途

    公开(公告)号：US20120302490A1

    公开(公告)日：2012-11-29

    申请号：US13513729

    申请日：2010-11-30

    Applicant: Gerd Reinhardt ,  Michael Best

    Inventor： Gerd Reinhardt ,  Michael Best

    IPC: B01J31/22 ,  C11D3/30

    CPC classification number: C07F13/005 ,  C11D3/168 ,  C11D3/3932 ,  C11D17/0052 ,  C11D17/06 ,  C11D17/065 ,  D21C9/10 ,  D21C9/163

    Abstract: The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (I), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O22−, O2−, O2−, OH−, HO2−, SH−, S2−, SO, Cl−, N3−, SCN−, N3−, RCOO−, NH2− and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from −4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R′—C6H4—SO3Me, where R′ is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterised in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R′—C6H4—SO3Me is 1:0.5 to 1:5. The invention also describes a method for producing the compounds and to the use thereof as oxidation catalysts or bleach catalysts, in particular in detergents or cleaning agents.

    Abstract translation: 本发明涉及固体形式的化合物，其包含a）一种或多种通式（I）的锰络合物，其中M独立地选自III或IV氧化态的锰，X独立地为配位或桥接 选自H2O，O22-，O​​2-，O2-，OH-，HO2-，SH-，S2-，SO，Cl-，N3-，SCN-，N3-，RCOO-，NH2-和NR3的物质，其中R 是选自H，烷基和芳基的基团，L独立为有机配体，每个含有至少两个在锰上配位的氮原子，z为-4至+4的整数，Y为单价或多价计数器 其选自氯化物，硫酸盐，硫酸氢盐，硝酸盐和乙酸盐，其导致络合物的电荷中性，q是1至4的整数，b）一种或多种通式R'-C6H4- SO 3 Me，其中R'是CH 3或C 2 H 5，并且表示Me，Na，K，Ca或Mg，其特征在于锰络合物 通式（1）表示的化合物与通式R'-C6H4-SO3Me的盐为1:0.5至1:5。 本发明还描述了一种制备化合物的方法及其用作氧化催化剂或漂白催化剂的用途，特别是在洗涤剂或清洁剂中。

    Method For Isolating Concentrated Paraffin Sulfonic Acids
    32.
    发明申请
    Method For Isolating Concentrated Paraffin Sulfonic Acids 有权
    分离浓缩石蜡磺酸的方法

    公开(公告)号：US20100087674A1

    公开(公告)日：2010-04-08

    申请号：US12598229

    申请日：2008-04-29

    Applicant: Gerd Reinhardt ,  Peter Newmann ,  Lars Cuypers

    Inventor： Gerd Reinhardt ,  Peter Newmann ,  Lars Cuypers

    IPC: C07C309/00

    CPC classification number: C07C303/44 ,  C07C303/14 ,  C07C309/04

    Abstract: The invention relates to a method for isolating concentrated paraffin sulfonic acids from reaction mixtures that are produced during the sulfoxidation of n-paraffins, from which a major part of the sulfuric acid and the paraffin was removed by phase separation and which contain, in addition to the free paraffin sulfonic acids, n-paraffins, water and optionally minor amounts of sulfuric acids. The method according to the invention is characterized by removing paraffin and optionally residual water by vacuum distillation. The paraffin sulfonic acids obtained by distillation have a content of more than 85% by weight of the active substance. The material is pale, odorless and low in sulfuric acid and paraffin.

    Abstract translation: 本发明涉及一种从正链烷烃的亚磺氧化反应中产生的反应混合物中分离浓缩的链烷磺酸的方法，其中大部分硫酸和石蜡通过相分离从其中除去，除了含有 游离的链烷烃磺酸，正链烷烃，水和任选的少量硫酸。 根据本发明的方法的特征在于通过真空蒸馏除去石蜡和任选的残余水。 通过蒸馏获得的链烷磺酸含量大于活性物质的85重量％。 该材料为浅灰色，无臭，硫酸和石蜡含量低。

    Use Of Aminoacetones And Salts Thereof As Bleaching Boosters For Peroxygen Compounds
    33.
    发明申请
    Use Of Aminoacetones And Salts Thereof As Bleaching Boosters For Peroxygen Compounds 审中-公开
    使用氨基丙酮及其盐作为过氧化合物的漂白助剂

    公开(公告)号：US20090289221A1

    公开(公告)日：2009-11-26

    申请号：US12376423

    申请日：2007-07-31

    Applicant: Gerd Reinhardt ,  Georg Borchers ,  Michael Seebach

    Inventor： Gerd Reinhardt ,  Georg Borchers ,  Michael Seebach

    IPC: C11D3/395

    CPC classification number: C11D3/392 ,  C11D3/3917 ,  C11D3/3927 ,  C11D17/0034

    Abstract: The use is claimed of aminoacetones or salts thereof of the general formulae (I) and (II) in which R1 and R2 are each independently hydrogen, C1-C22-alkyl, C2-C22-alkenyl, phenyl or C5-C8-cycloalkyl, or R1 and R2, together with the nitrogen atom, form a 5-, 6- or 7-membered ring system, X′ is anion, for example chloride, bromide, iodide, toluenesulfonate, benzenesulfonate, cumenesulfonate, mesitylsulfonate, sulfate, hydrogensulfate, acetate, fatty acid anion or anion of polycarboxylates, as a bleaching booster for inorganic peroxygen compounds in the pH range from 7 to 9.

    Abstract translation: 要求使用通式（I）和（II）的氨基丙酮或其盐，其中R 1和R 2各自独立地为氢，C 1 -C 22 - 烷基，C 2 -C 22 - 烯基，苯基或C 5 -C 8 - 环烷基， 或R 1和R 2与氮原子一起形成5-，6-或7-元环体系，X'是阴离子，例如氯化物，溴化物，碘化物，甲苯磺酸盐，苯磺酸盐，磺酸盐，月桂基磺酸盐，硫酸盐，硫酸氢盐， 乙酸盐，脂肪酸阴离子或多羧酸盐阴离子，作为无机过氧化合物的漂白助剂，pH范围为7至9。

    Liquid bleaching composition components comprising amphiphilic polymers
    34.
    发明授权
    Liquid bleaching composition components comprising amphiphilic polymers 有权
    包含两亲聚合物的液体漂白组合物组分

    公开(公告)号：US07109155B2

    公开(公告)日：2006-09-19

    申请号：US10727770

    申请日：2003-12-04

    Applicant: Gerd Reinhardt ,  Irina Geiger ,  Matthias Loeffler ,  Roman Morschhaeuser

    Inventor： Gerd Reinhardt ,  Irina Geiger ,  Matthias Loeffler ,  Roman Morschhaeuser

    IPC: C11D17/08 ,  C11D9/42 ,  C11D3/37 ,  C11D3/395 ,  C11D7/54

    CPC classification number: C11D3/37 ,  C11D3/3719 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3947

    Abstract: Liquid bleaching composition components are claimed which comprise 1) amphiphilic copolymers which include structural units which are derived from a) acryloyldimethyltauric acid in free, partially neutralized or completely neutralized form with mono- or divalent inorganic or organic cations and b) at least one hydrophobic comonomer based on ethylenically unsaturated polyalkylene alkoxylates and optionally c) further at least monovinylically unsaturated comonomers different from a) and b), and 2) at least one bleach activator, bleach catalyst or oxygen transfer agent.

    Abstract translation: 要求保护液体漂白组合物组分，其包含1）两亲共聚物，其包括衍生自a）丙烯酰基二甲基牛磺酸的游离，部分中和或完全中和形式的单或二价无机或有机阳离子的结构单元，和b）至少一种疏水性共聚单体 基于烯键式不饱和聚亚烷基烷氧基化物和任选地c）至少一种不同于a）和b）的单乙烯基不饱和共聚单体，和2）至少一种漂白活化剂，漂白催化剂或氧转移剂。

    Ammonium nitriles and the use thereof as hydrophobic bleaching activators
    35.
    发明授权
    Ammonium nitriles and the use thereof as hydrophobic bleaching activators 失效
    腈类腈及其作为疏水性漂白活化剂的用途

    公开(公告)号：US07015185B2

    公开(公告)日：2006-03-21

    申请号：US10486939

    申请日：2003-03-12

    Applicant: Michael Seebach ,  Gerd Reinhardt

    Inventor： Michael Seebach ,  Gerd Reinhardt

    IPC: C11D1/00 ,  C11D3/26 ,  C11D3/395

    CPC classification number: C11D3/3925 ,  C07C255/25

    Abstract: The invention relates to ammonium nitriles of general formula (I), wherein the radicals R3, R4, R5 and X− have the meaning as cited in the description and R1 and R2 respectively represent individually a straight or branched chained C5–C24-alkyl, alkenyl or alkylether group. The inventive compounds are used as bleaching activators in washing, cleaning, and disinfective agents and in textile and paper bleaching.

    Abstract translation: 本发明涉及通式（I）的铵腈，其中R 3，R 4，R 5和X 5， - 具有在说明书中引用的含义，R 1和R 2分别独立地表示直链或支链的C 5 - -C 24 - 烷基，烯基或烷基醚基。 本发明化合物用作洗涤，清洁和消毒剂以及织物和纸张漂白中的漂白活化剂。

    Use of transition metal complexes as bleach catalysts in laundry detergents and cleaning compositions
    36.
    发明申请
    Use of transition metal complexes as bleach catalysts in laundry detergents and cleaning compositions 失效
    过渡金属配合物作为漂白催化剂在衣物洗涤剂和清洁组合物中的应用

    公开(公告)号：US20050209120A1

    公开(公告)日：2005-09-22

    申请号：US11041468

    申请日：2005-01-24

    Applicant: Gerd Reinhardt ,  Ekaterina Jonas

    Inventor： Gerd Reinhardt ,  Ekaterina Jonas

    IPC: C07D257/02 ,  C07F13/00 ,  C07F15/02 ,  C11D3/16 ,  C11D3/28 ,  C11D3/39 ,  C11D3/395 ,  C11D17/00

    CPC classification number: C11D3/168 ,  C11D3/3932

    Abstract: The use is claimed of transition metal complexes of the formula (I) [M(L)Yn]Xm   (I) where M is a metal atom from the group of Mn and Fe, L is a ligand of the general formula (II) or (III) where R1, R2, R3 and R4 are the same or different and are each H, C1-C8-alkyl or C6-C12-alkaryl; X and Y are each an uncharged or anionic ligand from the group of CH3CN, chloride, bromide, nitrate, perchlorate, sulfate, citrate, hexafluorophosphate, trifluoromethanesulfonate, tetrafluoroborate, tetraphenylborate or an anion of organic acids having C1-C22 carbon atoms, n and m are each a number from 0 to 4 as bleach catalysts in laundry detergents and cleaning compositions.

    Abstract translation: 要求使用式（I）的过渡金属络合物<？in-line-formula description =“In-line Formulas”end =“lead”？> [M（L）Y （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是来自Mn和Fe，L的金属原子 是通式（II）或（III）的配体，其中R 1，R 2，R 3和R 4相同或不同，并且各自为H，C 1 -C 8 > - 烷基或C 6 -C 12 - 烷芳基; X和Y各自是来自CH 3 N，CN，氯化物，溴化物，硝酸盐，高氯酸盐，硫酸盐，柠檬酸盐，六氟磷酸盐，三氟甲磺酸盐，四氟硼酸盐，四苯基硼酸盐或有机酸阴离子的不带电荷或阴离子配体 具有C 1 -C 22碳原子，n和m各自为0至4的数，作为洗衣洗涤剂和清洁组合物中的漂白催化剂。

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